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131.
Franco L Mazzoni M Corvaja C Gubskaya VP Berezhnaya LSh Nuretdinov IA 《Chemical communications (Cambridge, England)》2005,(16):2128-2130
After pulsed photoexcitation of a new fullerene-linked bisnitroxide, a well resolved transient EPR spectrum is detected which is assigned to an excited quintet spin state generated by spin coupling of the nitroxides and the fullerene excited triplet. 相似文献
132.
Aresta M Tommasi I Quaranta E Fragale C Mascetti J Tranquille M Galan F Fouassier M 《Inorganic chemistry》1996,35(14):4254-4260
Extended labeling experiments have shown that formation of rhodium peroxocarbonate from CO(2) and [RhCl(eta(2)-O(2))(P)(3)] (P is PEt(2)Ph or PEtPh(2)) proceeds through O-O bond cleavage and CO(2) insertion. O-transfer to ancillary phosphine ligand to give R(3)P=O selectively (>85%) involves the Rh-linked O atom of the peroxo group of RhCl(CO(4))(P)(3). 相似文献
133.
Davide Carlo Demaria 《Milan Journal of Mathematics》1976,46(1):139-161
Given a metric compact spaceS and a finite graphG we show that:
Hence it follows that in each class of regularn-dimensional homotopy ofG can always be chosen as representative an almost constant path in respect of a suitable triangulation ofn-cubeI
n. 相似文献
a) | each regular function ofS inG is regularly homotopic to a strongly regular function; |
b) | each regular function ofS inG is regularly homotopic to an almost constant function in respect of an appropriate partition ofS. |
134.
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136.
Andrea Gambaro Ivo Moret Rossano Piazza Carlo Andreoli Eleonora Da Rin Gabriele Capodaglio 《International journal of environmental analytical chemistry》2013,93(6-7):401-412
The temporal evolution of concentrations of dimethylsulphide (DMS), its precursor dimethylsulphoniopropionate (DMSP) and chlorophyll a is surveyed weekly in the water column and in a landfast ice core at a coastal station of Gerlache Inlet (Terra Nova Bay, Antarctica) from 27 November 2000 to 14 February 2001. The DMS and DMSP profile concentrations in the water column are similar and show a clear temporal trend, with minimum values (<0.7?nM) at all depths occurring on 27 November 2000 and maximum values (4.8 × 102?nM for DMS and 1.8 × 102?nM for DMSP) in surface water on 27 December 2000 for DMS and on 19 December 2000 for DMSP. When the sea-ice cover is present, the temporal evolution of DMSP closely follows that of chlorophyll a in the water column, supporting the idea that DMSP, and therefore DMS, has a phytoplanktonic origin. However, when the ice cover breaks up during the late austral summer, a second phytoplankton bloom occurs, while the DMSP concentration in the sea-water column remains very low. In the ice core, the results show higher concentrations of DMSP than those of the underlying sea water, highlighting the important role of sea ice in the sulphur cycle of the Antarctic ecosystem. 相似文献
137.
Beaumont Jonathan S. Lee Tae Hoon Mayorov Mikhail Tintori Carlo Rogo Francesco Angelucci Bruno Corbo Matteo 《Journal of Radioanalytical and Nuclear Chemistry》2017,314(2):803-812
Journal of Radioanalytical and Nuclear Chemistry - The IAEA has developed a liquid scintillator-based system for the non-destructive assay of 235U in fresh fuel assemblies. The fast neutron... 相似文献
138.
Dr. Anil Reddy Marri Edoardo Marchini Dr. Valentin Diez Cabanes Dr. Roberto Argazzi Dr. Mariachiara Pastore Prof. Stefano Caramori Prof. Carlo Alberto Bignozzi Dr. Philippe C. Gros 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(65):16260-16269
A series of six new Fe(II)NHC-carboxylic sensitizers with their ancillary ligand decorated with functions of varied electronic properties have been designed with the aim to increase the metal-to- surface charge separation and light harvesting in iron-based dye-sensitized solar cells (DSSCs). ARM130 scored the highest efficiency ever reported for an iron-sensitized solar cell (1.83 %) using Mg2+ and NBu4I-based electrolyte and a thick 20 μm TiO2 anode. Computational modelling, transient absorption spectroscopy and electrochemical impedance spectroscopy (EIS) revealed that the electronic properties induced by the dimethoxyphenyl-substituted NHC ligand of ARM130 led to the best combination of electron injection yield and spectral sensitivity breadth. 相似文献
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140.
Carlo Rovelli 《Foundations of Physics》2013,43(1):8-20
Following the invitation of the editors of Foundations of Physics, I give here a personal assessment of string theory, from the point of view of an outsider, and I compare it with the theory, methods, and expectations of my own field. 相似文献