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991.
Kurt Van Durme Bruno Van Mele Katrien V. Bernaerts Beatrice Verdonck Filip E. Du Prez 《Journal of Polymer Science.Polymer Physics》2006,44(2):461-469
A range of hydrophilic poly(methyl vinyl ether) (PMVE) polymers was synthesized by living cationic polymerization of methyl vinyl ether (MVE), having different hydrophilic or hydrophobic chain‐end functionalities. The dissimilar end‐groups were either introduced by end‐capping of the growing polymer chain with LiBH4, methanol, and water or by functional initiation with 2‐bromo‐(3,3‐diethoxy‐propyl)‐2‐methylpropanoate. The synthesized PMVEs were characterized by 1H NMR, size exclusion chromatography, and matrix‐assisted laser desorption ionization time of flight, displaying a narrow polydispersity. Modulated temperature DSC was applied to study the influence of the nature of the end‐groups on the solubility behavior of PMVE in water. Terminal‐modification with a hydroxyl function improves the solubility, whereas a Br‐containing end‐group causes the polymer to be insoluble in water at room temperature; however, the special type III lower critical solution temperature demixing behavior being maintained. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 461–469, 2006 相似文献
992.
993.
Donald C. Rogness Paul J. Riedel Jonathan R. Sommer Dwayne F. Reed Kurt N. Wiegel 《Liquid crystals》2006,33(5):567-572
A series of main chain liquid crystalline polymers were formed through intermolecular hydrogen bonding between a functionalized bisazopyridine phenol and aromatic bisacids. The behaviour of these complexes was studied through differential scanning calorimetry and thermal polarizing optical microscopy. The presence of the hydrogen bonds was confirmed through infrared spectroscopy. These complexes formed thermotropic mesophases. The phases were determined to be nematic in nature from the schlieren textures of the optical micrographs. As the length of flexible spacer groups separating the mesogenic portions increased, the clearing temperatures of the mesophases decreased. As the length of the rigid component increased, the clearing temperature increased. A new bisacid species based on 2-hydroxy-6-naphthoic acid was used to increase clearing temperatures while remaining within an acceptable temperature window. 相似文献
994.
Peadar Cremin Dervilla M. X. Donnelly Jean-Luc Wolfender Kurt Hostettmann 《Journal of chromatography. A》1995,710(2):273-285
Conventional HPLC analysis of the sesquiterpene aryl esters present in the crude extracts of the pathogenic basidiomycete Armillaria is complicated by difficulties in identification solely on the basis of retention time. On-line coupling of liquid chromatography with thermospray mass spectrometry (LC-TSP-MS) provides a means for their direct detection. Crude extracts of seven Armillaria species were analysed providing a semi-quantitative survey of sesquiterpene aryl ester production within the genus. The distribution of these metabolites and its significance with regard to species differentiation and pathogenicity are discussed. Unknown components were also detected by on-line LC-TSP-MS screening of extracts, facilitating a targeted isolation route. 相似文献
995.
Olivier Potterat Kurt Hostettmann Alexandra Hltzel GüNther Jung Peter-Allan Diehl Orlando Petrini 《Helvetica chimica acta》1997,80(7):2066-2072
Boophiline ( 1 ), a new sterol amide was isolated from the cattle tick Boophilus microplus (Ixodidae). The structure was assigned as N-[3-(sulfooxy)-25ξcholest-5-en-26-oyl]-L-isoleucine by detailed 2D NMR investigations in conjunction with FAB mass spectrometry and acidic hydrolyses. Complete assignment of the diastereotopic methylene protons of the ring system could be deduced from the NMR data. In agar dilution assays, 1 exhibited antifungal properties against Cladosporium cucumerinum and antibacterial activity against Bacillus subtilis and Escherichia coli. 相似文献
996.
Alain Hach Mohit Malik Marcus Diem Lasha Tkeshelashvili Kurt Busch 《Photonics and Nanostructures》2007,5(1):29-36
We show that the sensitivity to disorder of certain physical properties of periodic media depends on whether the disorder is truly random or not. This allows to utilize periodic media for testing sequences of random numbers and to quantify their departure from true randomness via simple transmission and/or reflection data analysis. This physics-based model shows promises for device applications to test random data. 相似文献
997.
Induced absorption spectra in the range 200–900 nm at 77 and 290 K for Li2B4O7 single crystals, isotopically Li and B enriched are presented after irradiation of these crystals by thermal neutrons with fluence 1.8×1016 cm−2. The dependence of induced absorption spectra on the isotope composition was revealed: for 6Li210B4O7 and 7Li210B4O7 crystals intensive band in the region of 280–294 nm was observed. Under substitution of 7Li isotope by 6Li in the lithium tetraborate lattice no changes in the absorption spectra were observed. The nuclear reaction 10B(n,)7Li is proposed to be the main mechanism of formation of the radiation defects. 相似文献
998.
Burak Ozbagci 《Topology and its Applications》2007,154(4):908-916
We describe explicit horizontal open books on some Seifert fibered 3-manifolds. We show that the contact structures compatible with these horizontal open books are Stein fillable and horizontal as well. Moreover we draw surgery diagrams for some of these contact structures. 相似文献
999.
1000.