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131.
Bikash Kumar Sikder 《Journal of polymer science. Part A, Polymer chemistry》2019,57(7):783-791
The present article reports metal free acid‐mediated polymerization of 3,4‐alkylenedioxythiophenes in a solvent free medium and processability of insoluble polymers. It also describes structural variants and functional aqueous dispersions based on 3,4‐alkylenedioxythiophenes. Polymers were processed by dispersing the insoluble polymer powders in aqueous media using polymeric aromatic surfactant (polystyrenesulfonate, PSS) and aliphatic surfactant (sodiumdodecylsulfonate, SDS), respectively. The effect of surfactant on particle size, stability, and conductivity of the dispersions was investigated in detail. Polymer particles in SDS‐based dispersions tend to agglomerate which resulted enhanced conductivity of the thin films. Electrochemical studies revealed that the polymers are electroactive in nature and are transparent in oxidized state. The electrochromic contrast between the oxidized and reduced states of the polymers was in the range of 40–46%. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 783–791 相似文献
132.
Dinda Soumitra Sarkar Koushik Panda Bikash Kumar Pramanik Kausikisankar Ganguly Sanjib 《Transition Metal Chemistry》2022,47(1):31-38
Transition Metal Chemistry - By using a multifunctional diarylazooxime ligand LNOH 1, incorporating electron deficient azo chromophore in conjunction with a pendant π-electron-rich naphthyl... 相似文献
133.
We carry out density functional theory based investigation to understand the structural and electrical properties such as atomic structure, edge energy, band gap, and work function of zigzag ZnTe nanoribbons. It is found that the zigzag nanoribbons may be stabilized by passivating the edge atoms with Hydrogen, Oxygen or Fluorine atoms. Our study reflects that zigzag ZnTe nanoribbons with smaller width behave like semiconductor. However, they exhibit a transition from semiconducting phase to a metallic phase as width increases. A wide variation of band gap is obtained with respect to the choice of edge passivating elements. Work functions of all the nanoribbons are also estimated in order to assess the utility of these nanoribbons in various field emission devices. 相似文献
134.
135.
An efficient and eco-friendly method for the synthesis of spirooxindoles with fused tetrahydrochromenes has been demonstrated using basic nanocrystalline MgO catalyst in aqueous condition. The method has been applied for the synthesis of a range of compounds with variable functionalities in excellent yield and selectivity. 相似文献
136.
Ratiometric detection of Cr3+ and Hg2+ by a naphthalimide-rhodamine based fluorescent probe 总被引:1,自引:0,他引:1
Mahato P Saha S Suresh E Di Liddo R Parnigotto PP Conconi MT Kesharwani MK Ganguly B Das A 《Inorganic chemistry》2012,51(3):1769-1777
Newly synthesized rhodamine derivatives, L(1) and L(2), are found to bind specifically to Hg(2+) or Cr(3+) in presence of large excess of other competing ions with associated changes in their optical and fluorescence spectral behavior. These spectral changes are significant enough in the visible region of the spectrum and thus, allow the visual detection. For L(1), the detection limit is even lower than the permissible [Cr(3+)] or [Hg(2+)] in drinking water as per standard U.S. EPA norms; while the receptor, L2 could be used as a ratiometric sensor for detection of Cr(3+) and Hg(2+) based on the resonance energy transfer (RET) process involving the donor naphthalimide and the acceptor Cr(3+)/Hg(2+)-bound xanthene fragment. Studies reveal that these two reagents could be used for recognition and sensing of Hg(2+)/Cr(3+). Further, confocal laser microscopic studies confirmed that the reagent L(2) could also be used as an imaging probe for detection of uptake of these ions in A431 cells. 相似文献
137.
Saha S Chhatbar MU Mahato P Praveen L Siddhanta AK Das A 《Chemical communications (Cambridge, England)》2012,48(11):1659-1661
Effective extraction of Hg(2+) and Cr(3+) ions from aqueous media by novel rhodamine-alginate polymer-based highly fluorogenic, as well as colorimetric, chemosensor beads. 相似文献
138.
S Saha P Mahato M Baidya SK Ghosh A Das 《Chemical communications (Cambridge, England)》2012,48(74):9293-9295
A new coumarin-rhodamine conjugate constitutes a unique example of the interrupted PET coupled TBET response for developing an imaging reagent for determining the intracellular distribution of Hg(2+) in MCF7 cells exposed to [Hg(2+)] as low as 2 ppb. 相似文献
139.
Bikash Sahoo Sébastien Poncet 《Communications in Nonlinear Science & Numerical Simulation》2012,17(11):4181-4191
The steady flow arising due to the rotation of a non-Newtonian fluid at a larger distance from a stationary disk is extended to the case where the disk surface admits partial slip. The constitutive equation of the non-Newtonian fluid is modeled by that for a Reiner–Rivlin fluid. The momentum equation gives rise to a highly nonlinear boundary value problem. Numerical solution of the governing nonlinear equations are obtained over the entire range of the physical parameters. The effects of slip and non-Newtonian fluid characteristics on the momentum boundary layer are discussed in details. It is observed that slip has prominent effect on the velocity field, whereas a predominant influence of the non-Newtonian parameter is observed on the moment coefficient. 相似文献
140.
Mahato KK Rai SB 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2000,56(12):2333-2340
Tb3+-doped oxyfluoroborate glasses have been prepared for different concentrations of Tb. The absorption, fluorescence and photoacoustic spectra of these have been recorded and studied. It is marked that the fluorescence intensity of different fluorescence transitions decreases with the increase of Tb ion concentration in the glass. This quenching at higher concentration is due to the energy transfer among the excited and nearest neighbor unexcited Tb ions in the glass. The lifetime measurement confirms it, as the lifetime of a particular state was found to decrease with the increase of Tb ion concentration in the glass. The mechanism of the energy transfer process was determined to involve quadrupole quadrupole interaction. We have also studied the energy transfer from Tb3+-->Pr3+ when both the rare earths are doped together in the glass. A decrease in the lifetime of the 5D4 level of Tb3+ with the increase of Pr3+ concentration confirms this. 相似文献