Effective nonchain HF laser excited by a self-sustained discharge

Lasing and discharge in mixtures of SF₆ with hydrogen and hydrocarbons are investigated. If the chemical reaction is initiated by a self-sustained discharge (a generator with both an inductive and capacitive energy storage can be used), the maximum lasing efficiency is attained at high values of the ratio E/p (where E is the electric field intensity and p is the pressure in the mixture) if shaped electrodes and preionization of the discharge gap are employed. For the first time, the lasing efficiency obtained in a nonchain HF laser is as high as 10% of the energy deposit and 4.5% of the stored energy for a specific radiation energy of ≈140 J/(l atm). At high efficiencies, the emission spectrum of the nonchain HF laser significantly broadens and cascade lasing at P(3-2) → P(2-1) → P(1-0) vibrational transitions for several rotational lines is realized.     

Relaxor properties of Fe-doped TlInS<Subscript>2</Subscript>

The relaxor properties of Fe-doped TlInS₂ crystals are investigated. It is shown that Fe-doped TlInS₂ compounds exhibit all features inherent in relaxor ferroelectric materials. The temperature range of existence of the microdomain (relaxor) state and the temperature of the transition from this state to a macro-domain state are determined.     

Appearance of anomalous phase in <Superscript>4</Superscript>He crystal in the presence of small <Superscript>3</Superscript>He impurity

The kinetics of formation of an anomalous phase from a solution with a small ³He impurity was studied in the temperature range 0.2–0.7 K up to a supersaturation of ～30 mbar. The phase diagram was determined for normal and anomalous growths. It is found that, in the presence of impurities, the formation of a fast-growing state is retarded. This experimental fact indicates that the dissipative processes in fluids have an appreciable effect on the phase formation kinetics. The retardation is, possibly, caused by the direct interaction of an impurity with the crystal surface.     

Preparation of colloidal solutions of noble metals stabilized by polyoxometalates and supported catalysts based on these solutions

Conditions for the preparation of stable aqueous monometallic and bimetallic colloidal solutions (sols) of noble metals (Ru, Rh, Pd, Pt, Ir, Ag, and Au) in the presence of polyoxometalates containing W, Mo, V, and Nb were found. The stability of sols against coagulation at room temperature was studied. The metal/C samples prepared by metal adsorption from sols were studied by powder X-ray diffraction analysis and transmission electron microscopy. The following factors of importance for the preparation of a stable sol are discussed: (1) the formation of a sol of a metal polyhydroxo complex stabilized by a polyoxometalate (preliminary stage) and (2) the formation of polyoxometalate-metal clusters in the course of reduction of polyhydroxo complexes.Translated from Kinetika i Kataliz, Vol. 45, No. 6, 2004, pp. 921–929.Original Russian Text Copyright © 2004 by Maksimova, Chuvilin, Moroz, Likholobov, Matveev.     

The spline collocation method for parabolic boundary integral equations on smooth curves

Summary. We consider the spline collocation method for a class of parabolic pseudodifferential operators. We show optimal order convergence results in a large scale of anisotropic Sobolev spaces. The results cover the classical boundary integral equations for the heat equation in the general case where the spatial domain has a smooth boundary in the plane. Our proof is based on a localization technique for which we use our recent results proved for parabolic pseudodifferential operators. For the localization we need also some special spline approximation results in anisotropic Sobolev spaces. Received May 17, 2001 / Revised version received February 19, 2002 / Published online April 17, 2002     

Scaling laws for the spatial distributions of the plasma parameters in the positive column of a dc oxygen discharge

Comprehensive self-consistent simulations of the positive column plasma of a dc oxygen discharge are performed with the help of commercial CFDRC software (), which enables one to carry out computations in an arbitrary 3D geometry using fluid equations for heavy components and a kinetic equation for electrons. The main scaling laws for the spatial distributions of charged particles are determined. These scaling laws are found to be quite different in the parameter ranges that are dominated by different physical processes. At low pressures, both the electrons and negative ions in the inner discharge region obey a Boltzmann distribution; as a result, a flat profile of the electron density and a parabolic profile of the ion density are established there. In the ion balance, transport processes prevail, so that ion heating in an electric field dramatically affects the spatial distribution of the charged particles. At elevated pressures, the volume processes prevail in the balance of negative ions and the profiles of the charged particle densities in the inner region turn out to be similar to each other.     

Nonlinear vibrations of a charged drop in a third-order approximation in the amplitude of multimode initial deformation

A solution to the problem of nonlinear surface vibration of a charged ideal liquid drop is found in a third-order approximation in initial multimode deformation of the equilibrium spherical shape by the method of many scales. It is shown that the spectrum of modes that are responsible for the shape of the drop at an arbitrary time instant depends considerably on the spectrum of modes governing the initial deformation of the drop. The latter spectrum also has an effect on nonlinear corrections to the vibration frequencies and, consequently, on a nonlinear correction to the critical Rayleigh parameter, which specifies the stability of the drop against self-charge.     

On wave radiation induced by a fast shock wave in an oblique magnetic field

The corrugation stability of the flat surface of a fast magnetohydrodynamic shock wave in a perfect monoatomic gas with a constant heat capacity is studied with numerical techniques. The magnetic field makes an arbitrary angle with the plane of discontinuity. It is shown that the shock wave remains stable only if it is strictly perpendicular to the magnetic field. At any other angle between the fast shock wave and magnetic field, the former may spontaneously radiate outwardly propagating magnetohydrodynamic waves under certain conditions. Incoming flow characteristics at which these waves are induced are determined.     

Two scenarios for phase-transformation in disordered media

The reasons for the existence of various scenarios for structural transformations in disordered condensed media, such as liquids and amorphous substances, where both smeared transformations and sharp first-order transitions may occur, were analyzed. The ratio between the spatial scale of structural correlations and the size of the smallest possible region occupied by a new phase in the matrix of initial modification is the key parameter determining the scenario for equilibrium phase transformations in liquids. In amorphous substances, the experimentally observed transformations occur far from equilibrium, and the possible size of the region occupied by the new phase corresponds to the minimal nucleus size. For some amorphous solids, quantitative analysis of the transformation width was carried out and the main classes of covalent substances, in which the smeared or sharp transitions occur, were revealed. Specific features of the interparticle interactions determining various transformation scenarios are discussed.     

A new approach to unconditional security in relativistic quantum cryptography

A principally new approach ensuring secure key distribution via an open quantum communication channel is proposed. In contrast to the existing schemes, in which the security is based upon special properties of nonorthogonal states in the Hilbert space, the security of the proposed scheme relies on a spacetime structure of states and on certain constraints imposed by special relativity. Using these factors, it is possible to provide for secure key transmission using practically arbitrary quantum states.