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11.
Claire Chainais‐Hillairet Marguerite Gisclon Ansgar Jüngel 《Numerical Methods for Partial Differential Equations》2011,27(6):1483-1510
A finite‐volume scheme for the stationary unipolar quantum drift‐diffusion equations for semiconductors in several space dimensions is analyzed. The model consists of a fourth‐order elliptic equation for the electron density, coupled to the Poisson equation for the electrostatic potential, with mixed Dirichlet‐Neumann boundary conditions. The numerical scheme is based on a Scharfetter‐Gummel type reformulation of the equations. The existence of a sequence of solutions to the discrete problem and its numerical convergence to a solution to the continuous model are shown. Moreover, some numerical examples in two space dimensions are presented. © 2010 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 27: 1483–1510, 2011 相似文献
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FLAIR will be the next-generation facility for physics with low-energy antiprotons, providing antiprotons at energies from tens of MeV down to rest. It will also offer unique possibilities for physics with highly charged ions at very low energies. The FLAIR facility will have two deceleration rings, the LSR which will decelerate antiprotons to 300 keV and the USR which will bring them down further to 20 keV. The LSR will consist of the present CRYRING at the Manne Siegbahn Laboratory. During the next few years, CRYRING will be modified with respect to injection and extraction, to allow injection of 30 MeV antiprotons and to provide it with both fast (single-turn) and slow (resonant) extraction at a variable energy. We here describe plans and preparations for the transfer of CRYRING to FLAIR, giving, in particular, an overview of new components for injection and extraction. 相似文献
14.
Christian-Robert Raddatz Maria Allers Ansgar T. Kirk Stefan Zimmermann 《International Journal for Ion Mobility Spectrometry》2018,21(3):49-53
Measuring a mixture of acetone and perdeuterated acetone (acetone-d6) with an ultra-high resolution drift time ion mobility spectrometer (resolving power of Rp?=?235) and ultraviolet ionization (10.6 eV) at ambient pressure reveals three separated peaks. Two of the peaks can easily be associated with acetone and perdeuterated acetone. In a former publication several findings indicated an exchange of a methyl group and the formation of a H3COCD3 related peak. In this work the formed ion species were analyzed with a high resolution drift time ion mobility time of flight mass spectrometer. The mass spectra clearly show the formation of three proton-bound dimer peaks whereas the peak between acetone and acetone-d6 is a proton-bound mixed dimer consisting of one acetone and one acetone-d6 molecule. 相似文献
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16.
Ansgar Jüngel José Luis López Jesús Montejo–Gámez 《Journal of statistical physics》2011,145(6):1661-1673
A quantum Navier–Stokes system for the particle, momentum, and energy densities is formally derived from the Wigner–Fokker–Planck
equation using a moment method. The viscosity term depends on the particle density with a shear viscosity coefficient which
equals the quantum diffusion coefficient of the Fokker–Planck collision operator. The main idea of the derivation is the use
of a so-called osmotic momentum operator, which is the sum of the phase-space momentum and the gradient operator. In this
way, a Chapman–Enskog expansion of the Wigner function, which typically leads to viscous approximations, is avoided. Moreover,
we show that the osmotic momentum emerges from local gauge theory. 相似文献
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18.
Biosensors and flow-through system for the determination of creatinine in hemodialysate 总被引:1,自引:0,他引:1
Biosensors for the determination of creatinine have been developed and integrated into a flow-through system. The sensors are based on a screen-printed three electrode transducer with a platinum working electrode. Applying the multi-enzyme sequence of creatininase (CA), creatinase (CI) and sarcosine oxidase (SO) hydrogen peroxide has been detected amperometrically. An optimal enzyme load was found to be 4.4 U/0.28 U/0.20 U (CA/CI/SO) and 0.28 U/0.20 U (CI/SO) per electrode for the creatinine sensor and for the creatine sensor, respectively. Among a variety of polymers Nafion has shown the highest efficiency to exclude interfering substances like ascorbic acid, acetaminophen and uric acid. First determinations of creatinine in dialysate samples obtained during hemodialysis treatments have shown a good correlation to the conventional methods, the Jaffé reaction (y=0.945x+ 2.8, R=0.9882, n=9) and the enzymatic photometric method (y=0.891x+3.5, R=0.9917, n=9). 相似文献
19.
Mark Eggink Maikel Wijtmans Ansgar Kretschmer Jeroen Kool Henk Lingeman Iwan J. P. de Esch Wilfried M. A. Niessen Hubertus Irth 《Analytical and bioanalytical chemistry》2010,397(2):665-675
Based on the template of a recently introduced derivatization reagent for aldehydes, 4-(2-(trimethylammonio)ethoxy)benzeneaminium
dibromide (4-APC), a new derivatization agent was designed with additional features for the analysis and screening of biomarkers
of lipid peroxidation. The new derivatization reagent, 4-(2-((4-bromophenethyl)dimethylammonio)ethoxy)benzenaminium dibromide
(4-APEBA) contains a bromophenethyl group to incorporate an isotopic signature to the derivatives and to add additional fragmentation
identifiers, collectively enhancing the abilities for detection and screening of unknown aldehydes. Derivatization can be
achieved under mild conditions (pH 5.7, 10 °C). By changing the secondary reagent (1-ethyl-3-(3-dimethylaminopropyl) carbodiimide
instead of sodium cyanoborohydride), 4-APEBA is also applicable to the selective derivatization of carboxylic acids. Synthesis
of the new label, exploration of the derivatization conditions, characterization of the fragmentation of the aldehyde and
carboxylic acid derivatives in MS/MS, and preliminary applications of the labeling strategy for the analysis of aldehydes
in urine and plasma are described. 相似文献
20.
Huang KY Siemer AB McDermott AE 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,208(1):122-127
We tested the performance of several (13)C homonuclear mixing sequences on perdeuterated microcrystalline ubiquitin. All sequences were applied without (1)H decoupling and at relatively low MAS frequencies. We found that RFDR gave the highest overall transfer efficiency and that DREAM performs surprisingly well under these conditions being twice as efficient in the aliphatic region of the spectrum than the other mixing sequences tested. 相似文献