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21.
We prove that certain two-point Padé approximants occupying the diagonal of the Padé table form monotone sequences of lower and upper bounds uniformly converging to a Stieltjes function. The results can be applied to the theory of inhomogeneous media for the calculation of the bounds on the effective transport coefficients of heterogeneous materials. 相似文献
22.
23.
O. Yu. Rekhlova B. Tashkhodzhaev V. I. Andrianov A. I. Saidkhodzhaev G. V. Sagitdinova N. G. Furmanova 《Chemistry of Natural Compounds》1991,26(6):643-647
The spatial structure of the sesquiterpene humulane alcohol juniferol, which is represented in the crystal by two conformers, IA and IB, differing by the conformation of the C2...C9 section, has been established by the x-ray structural method. The strain energies of the conformers have been calculated by the method of molecular mechanics. The barrier to the interconversion of the conformers by rotation of the C2...C9 section has been calculated; it amounts to 7–8 kcal/mole. This value of the transformation barrier permits the assumption that the two conformers also exist in solution, their interconversion being hindered.Institute of Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Institute of Crystallography, Academy of Sciences of the USSR, Moscow. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 757–762, November–December, 1990. 相似文献
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25.
Summary By the metathetic reaction of sodium triethylsiloxide with titanium tetrachloride and with tin tetrachloride, tetrakis(triethylsiloxy)titanium and tetrakis(triethylsiloxy)tin were synthesized. 相似文献
26.
Journal of Structural Chemistry - Investigation of the potential surface of methyl 2,3-anhydro-2,3,4-trideoxy-β-D-lyxohexopyranoside has shown that the molecule has seven conformers with... 相似文献
27.
Berezin D. B. Zharnikova N. V. Andrianov V. G. Shatunov P. A. Semeikin A. S. 《Russian Journal of Coordination Chemistry》2002,28(5):325-332
The effect of peripheral substitution in the porphyrin macrocycle (2OEtP, H2TPP) of the nature of the N-substituent (X = Me, Ph) and of the anion in the salt solvate (A = –, NO3
–, –) on the complexation of the N-substituted porphyrins with zinc salts in DMSO is studied. The positions of the bands in the electronic absorption spectrum of the (A)M(N-X)P metal complex were found to depend only slightly on the nature of the A anion in the composition of the coordination sphere of the complex. An inhibition of coordination of the N-substituted 2TPP derivatives by zinc nitrate was discovered that is not typical of porphyrins proper. The type of hybridization of the substituted nitrogen atom in the porphyrin molecule is discussed. A mixed type of hybridization is suggested: the sp
2- and p
3-forms in the ligands and an almost complete transition to the p
3 form in the N-substituted metal complexes. 相似文献
28.
V. G. Andrianov V. G. Semenikhina A. V. Eremeev 《Chemistry of Heterocyclic Compounds》1991,27(1):102-104
The Z-oxime of the pentamethyleneamide of 4-aminofurazan-3-carboxylic acid isomerizes — rapidly in acid media, slowly in the absence of acid — to the E-oxime which at 120–140C undergoes alkali-catalyzed rearrangement to 4-piperidinofurazan-3-carboxyamidoxime.For Communication 1 see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 122–123, January, 1991. 相似文献
29.
A study is made of the catalytic condensation polymerization of polydialkylcyclosilazanes [RR'SiNH]n (n=3,4; R=CH3, C2H5; R'=C2H5, C4H9, C6H13, C9H19) in the presence of small amounts of nucleophilic reagents, to give compounds of the general type R5R6'Si6N3(NH)2 and oligomers. The reactivities of polydialkylsilazanes decrease with increase in aliphatic group chain length. 相似文献
30.
V. G. Andrianov 《Chemistry of Heterocyclic Compounds》1997,33(8):973-976
4-Amino-3-cyanofuroxan, obtained by the oxidation of aminocyanoglyoxime, reacts with hydrazine and hydroxylamine to form the amidrazone and amidoxime respectively of 4-aminofuroxan-3-carboxylic acid. The reaction of the amidoxime with triethyl orthoformate can lead to closure of both the pyrimidine and the 1,2,4-oxadiazole ring.Latvian Institute of Organic Synthesis, Riga. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1115–1119, August, 1997. 相似文献