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901.
Akira Takahashi Ryu Yuzaki Yoshihito Ishida Atsushi Kameyama 《Journal of polymer science. Part A, Polymer chemistry》2019,57(24):2442-2449
Ring‐expansion polymerization (REP) of thiiranes was investigated using 3H‐benzothiazol‐2‐one (BT) as the cyclic aromatic thiourethane initiator in the presence of tetrabutylammonium chloride (TBAC) catalyst. The polymerization proceeded in a well‐controlled manner to afford cyclic polysulfides with one BT moiety per macrocycle, as confirmed by MALDI‐TOF MS spectroscopy. Differential scanning calorimetry (DSC) measurement of the obtained cyclic polysulfides revealed slight decrease in the glass‐transition temperature as the increase in the molecular weight, supporting the cyclic topology of the products. Postpolymerization of thiiranes using the BT‐initiated cyclic polysulfide as the macroinitiator afforded the ring‐expanded product while maintaining the narrow polydispersity and well‐defined cyclic structure, which enabled precise synthesis of cyclic block copolymer with different thiirane combination. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 2442–2449 相似文献
902.
903.
Alina Marieta Simion Takashi Arimura Akira Miyazawa G. K. Surya Prakash George A. Olah 《合成通讯》2013,43(16):2859-2865
Secondary and tertiary amines can be easily obtained from primary and secondary amines, respectively, in completely aqueous media, in the presence of a bicatalytic system formed of cheap commercial aluminum (Al) powder and 5% rhodium (Rh) or ruthenium (Ru) deposed on charcoal. 相似文献
904.
The measurement of soil reaction forces on a lug of a movable lug cage wheel was carried out in a soil bin. To elucidate the experimental results, a theoretical analysis of soil reaction forces on the lug of the movable lug cage wheel was made by using an analysis of the lug trajectory and a modified theory in soil–vehicle mechanics. The existing theory was modified and adjusted by considering the actual lug trajectory and the soil trench made by the preceding lug. The results showed that the theoretical analysis gave a good representation of the reaction forces measured experimentally. The higher pull and lift forces of the movable lug cage wheel compared with those of the fixed lug wheel was supported by the theoretical analysis. Although the theoretical representation of soil reaction forces should be improved by further works, it is sufficiently accurate to estimate the performance of the movable lug cage wheels by the proposed theory. 相似文献
905.
Wahyu Widada Nobuo Takeuchi Hiroaki Kuze Akira Tadaishi Shin Shimakura 《Optical Review》2000,7(1):95-100
Lidar return signals are studied for a micro-pulse lidar under sky conditions with multi-layer clouds. From theoretical considerations on the lidar signal-to-noise ratio, it is estimated that the maximum cloud optical thickness detectable is about 3.7. This result reasonably agrees with the actual multi-layer cloud data obtained from observations in Sukhothai, Thailand. Deviations from theoretical prediction, however, are found for a geometrically thin but dense cloud, and for a moderately concentrated but geometrically thick cloud. The effect of multiple scattering is also discussed. 相似文献
906.
Bikau Shukla Akira Miyoshi Mitsuo Koshi 《Journal of the American Society for Mass Spectrometry》2010,21(4):534-544
The role of methyl radicals in the networking of sp2 carbons has been explored through kinetic analysis of mass spectra of the gas-phase products of the pyrolysis of toluene
and toluene/acetone mixtures. Pyrolytic reactions were performed in a flow tube reactor at temperatures of 1140–1320 K and
a constant total pressure of 10.38 Torr with a residence time of 0.585 s. On addition of acetone, methyl substituted products
and their derivatives were enhanced. Mass peaks were observed in several sequences at an interval of 14 mass units; these
ions correspond to methyl substituted products formed as a result of hydrogen abstraction (−H) followed by methyl radical
addition (+CH3). Each major peak was usually preceded by a peak at two mass units lower, which was likely produced through dehydrogenation/dehydrocyclization
(−H2) of methyl substituted products. Detected species include a large number of alkyl, cyclotetrafused (CT), cyclopentafused
(CP) mono-, di-, and polycyclic aromatic hydrocarbons (PAHs) along with primary PAHs. The analysis showed that MAC (methyl
addition/cyclization) has a unique capacity to induce the sequential growth of hexagonal networks of sp2 carbons from all fusing sites [1] of a PAH. Moreover, MAC was found capable of answering an important question in PAH growth,
which is expansion of the CT → CP → hexagonal network for which other reported mechanisms are inefficient. 相似文献
907.
Hide-Ki Ishida Hiromune Ando Hiromi Ito Hideharu Ishida Makoto Kiso Akira Hasegawa 《Journal of carbohydrate chemistry》2013,32(4-5):413-428
Abstract A first total synthesis of gangliosides GD1c and GT1a containing Neu5Acα(2→8) Neu5Acα(2→3)Gal residue in their non-reducing terminal is described. Condensation of methyl O-[methyl 5-acetamido-8-O-(5-acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylono-11,9-lactone) -4,7- di-O-acetyl-3,5-dideoxy-D-glycero-α-D-galcto-2-nonulopyranosyranosylanate]-(2→3)-2,4,6-tri-O-benzoyl-1-thio-β-D-gala-ctopyranoside (1) with 2-(trimethylsilyl)ethyl O-(2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranosyl)- (1→4) -O -(2,3,6-tri-O-benzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (2) or 2-(trimethylsilyl)ethyl O-(2-acetamido-6-O-benzyl-2-deoxy-β-D-galactopyranosyl)-(1→4)-(9-[methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2→3)]-O-(2,6-di-O-benzyl-β-D-galactopyranosyl) - (1→4) - 2,3,6-tri-O-benzyl-β-D-glucopyranoside (3) in the presence of dimethyl(methylthio)sulfonium triflate (DMTST) gave the corresponding hexa-and heptasaccharide derivatives 4 and 5, respectively. These oligosaccharides were converted into the α-trichloroacetimidates 10 and 11 via reductive removal of the benzyl groups and/or benzylidene group, O-acetylation, selective removal of the 2-(trimethylsilyl)ethyl group and treatment with trichloroacetonitrile, which, on coupling with 2-azidosphingosine derivatives 12 or 13, gave the β-glycosides 14 and 15, respectively. Finally, 14 and 15 were transformed, via selective reduction of the azido group, coupling with octadecanoic acid and removal of all protecting groups, into the title gangliosides GD1c 18 and GT1a 19. 相似文献
908.
909.
An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with Si---Si bonds. Application of lithiosilanes for the synthesis of polysilane dendritic molecules is also described. 相似文献
910.