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41.
42.
A simple, rapid and inexpensive solidified floating organic drop microextraction (SFODME) and flow injection flame atomic absorption spectrometric determination (FI-FAAS) method for copper were developed. 3-amino-7-dimethylamino-2-methylphenazine (Neutral red, NR) was used as the complexing agent. Several factors affecting the microextraction efficiency, such as, pH, NR and sodium dodecylbenzenesulfonate (SDBS) concentration, extraction time, stirring rate, and temperature were investigated and optimized. Under optimized experimental conditions an enrichment factor of 541 was obtained for 100 mL of sample solution. The calibration graph was linear in the range of 0.5–20.0 ng mL− 1 and the limit of detection (3 s) was 0.18 ng mL− 1, the limit of quantification (10 s) was 0.58 ng mL− 1. The relative standard deviation (RSD) for 10 replicate measurements of 10 ng mL− 1 copper was 2.7%. The developed method was successfully applied to the extraction and determination of copper in different certified reference materials (Estuarine water, Slew 3 and fortified water, TM 23.2) and real water samples and satisfactory results were obtained. 相似文献
43.
İsmail Aslan 《Mathematical Methods in the Applied Sciences》2011,34(8):990-995
In this paper, we present an application of some known generalizations of the Exp‐function method to the fifth‐order Burgers and to the seventh‐order Korteweg de Vries equations for the first time. The two examples show that the Exp‐function method can be an effective alternative tool for explicitly constructing rational and multi‐wave solutions with arbitrary parameters to higher order nonlinear evolution equations. Being straightforward and concise, as pointed out previously, this procedure does not require the bilinear representation of the equation considered. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
44.
It is shown that a Korovkin type theorem for a sequence of linear positive operators acting in weighted space L
p,w
(loc) does not hold in all this space and is satisfied only on some subspace. 相似文献
45.
İdris Dağ Alper Korkmaz Bülent Saka 《Numerical Methods for Partial Differential Equations》2010,26(3):544-560
The differential quadrature method based on cosine expansion is applied to obtain numerical solutions of the RLW equation. The propagation of single solitary wave is studied to validate the efficiency of the algorithm. Then, test problems including interaction of two and three solitary waves, undulation, and evolution of solitary waves are implemented. Solutions are compared with earlier results. Discrete conservation quantities are computed for test experiments. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2009 相似文献
46.
Incipient separation over wall irregularities in a steady two dimensional flow field of a perfect fluid which has transonic speed characteristics has been investigated considering viscous-inviscid interactions at high Reynolds number. The aim of this work is to investigate dependence of the critical hump height (when a well attached flow over rigid body surface turns into a separated one) on the Karman–Guderley parameter which characterizes of the local flow field. The analysis of the flow field starts with the so-called inspection analysis of the flow properties and then the interaction problem has been constructed using the asymptotic analysis of triple-deck structure of interaction region. Finally, a method based on a semi-direct solution of governing equations of the transonic interaction problem has been used to obtain the numerical solution of the problem. 相似文献
47.
48.
In this paper, we establish several inequalities for some differantiable mappings that are connected with the Riemann-Liouville fractional integrals. The analysis used in the proofs is fairly elementary. 相似文献
49.
İzzet Amour Morkan Ayşe Uztetik Morkan Çiğdem Tuç Engin Kendi 《Journal of chemical crystallography》2008,38(7):541-545
Abstract Pentacarbonyl(4-methylpyridine)chromium(0) complex was isolated from n-hexane solution as yellow plate-like crystals and characterized by using X-ray crystallography. It crystallizes in the orthorhombic
system with the space group Cmcm and Z = 4. The unit cell parameters are a = 11.737(1) ?, b = 12.857(2) ?, c = 8.465(1) ?. The single crystal X-ray structure of the complex shows that the coordination sphere around the chromium central
atom is slightly distorted octahedron, involving the 4-methylpyridine (4-mp), ligand as a monodentate N-donor ligand and five
carbonyl groups. The four equatorial CO groups in the complex, with the Cr–C2 distance of 1.886 Ǻ, are slightly bent away
from the 4-methylpyridine ligand with the N–Cr–C2 angle of 91.69°. The pyridine ring plane makes an angle of 135.17° with
the Cr–N–CO bond axis. The thermal analysis (differential thermal analysis and thermal gravimetry) and IR spectra of the complex
indicated that the compound undergoes complete decomposition to form the Cr2O3 as the final decomposition product.
Index Abstract The crystal structure of pentacarbonyl(4-methylpyridine)chromium(0) complex has been determined and its thermal behavior has
also been studied.
相似文献
50.
The epoxy resins containing imine bonding were prepared from hydroxyl substituted Schiff base monomers in two steps. At the first step, hydroxyl substituted Schiff base monomers were synthesized via condensation reaction. At the second step, epoxy resins were synthesized from the reaction between Schiff base monomers and epichlorohydrine (EPC). Then curing processes of epoxy resins were achieved by p-phenylenediamine compound. The structures of resulting compounds were confirmed by FT-IR, UV-Vis and 1H-NMR. TG-DTA and DSC measurements were performed for thermal characterizations of the compounds. Chemical resistances of the cured epoxy-amine systems were determined for coating applications in acidic, alkaline and organic solvents. HCl (10%, aqueous solution), NaOH (10%, aqueous solution), DMSO, DMF, N-methylpyrrolidone, ethanol, THF and acetone were used for corrosion tests. Chemical resistance data of the synthesized epoxy resins demonstrated that they have good chemical resistance against various acid, alkaline and common organic solvents. Surface morphologies of epoxy resin and the cured epoxy resin were determined with scanning electron microscopy (SEM) measurements. Also, optical band gap (Eg) values of Schiff base monomers and epoxy resins were calculated from UV-Vis measurements. 相似文献