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611.
Mukarakate C Mishchenko Y Brusse D Tao C Reid SA 《Physical chemistry chemical physics : PCCP》2006,8(37):4320-4326
The magnitude of the singlet-triplet gap in dichloromethylene (CCl(2)) has been a point of controversy in the recent literature. In this study, we report single vibronic level emission spectra of the A(1)B(1)-->X[combining tilde](1)A(1) system of the carbene C(35)Cl(2), which probes the vibrational structure of the X[combining tilde](1)A(1) state up to approximately 10,000 cm(-1) above the vibrationless level. By the careful selection of bands where complete isotope and K(a)' selectivity in excitation was possible, we measured K(a)'-sorted emission spectra in order to test the previously established hypothesis [M.-L. Liu, C.-L. Lee, A. Bezant, G. Tarczay, R. J. Clark, T. A. Miller and B.-C. Chang, Phys. Chem. Chem. Phys., 2003, 5, 1352] that unassigned lines lying above approximately 5,000 cm(-1) belong to levels of the ?(3)B(1) state. The K(a)'-sorting method discriminates between singlet and triplet levels via the (A'-B[combining macron]') rotational constant, which is significantly larger for pure triplet levels due to the larger equilibrium bond angle. In the region between 3,500 and 9,000 cm(-1) above the vibrationless level of the X[combining tilde](1)A(1) state, we find only a very modest increase in (A'-B[combining macron]'), and approximately 86% of the lines observed between 5,000 and 9,000 cm(-1) can be assigned to X[combining tilde](1)A(1) levels within 3 standard deviations of our Dunham expansion fit, which included more than 140 levels in total. A nearly complete set of Dunham parameters was determined for the C(35)Cl(2) isotopomer, and the X[combining tilde](1)A(1) state term energies up to 4,000 cm(-1) are in excellent agreement with recent variational calculations of Tarczay, et al. [G. Tarczay, T. A. Miller, G, Czakó and A. G. Császár, Phys. Chem. Chem. Phys., 2005, 7, 2881]. Finally, the implication of our results for the singlet-triplet gap in dichloromethylene is discussed. 相似文献
612.
Wasserfallen D Kastler M Pisula W Hofer WA Fogel Y Wang Z Müllen K 《Journal of the American Chemical Society》2006,128(4):1334-1339
With the approach presented herein, a large aromatic pi-system is synthesized, which shows extraordinarily high solubility and an effective suppression of aggregation. This was due to a distortion of the aromatic core by bulky tert-butyl groups and the solubilizing effects of alkyl chains in the corona of the aromatic core. Therefore not only the processing and cleaning of the materials with standard laboratory techniques became possible, but moreover the first structure-rich UV/vis and a resolved (1)H NMR spectra for an aromatic system two times larger than hexa-peri-hexabenzocoronene were recorded. The bulk properties in an extruded fiber as well as on the surface showed a columnar self-assembly including a phase in which a homeotropic alignment on a substrate was observed, which turns the material into an interesting candidate for future applications in electronic devices. 相似文献
613.
Sevryugina Y Rogachev AY Jackson EA Scott LT Petrukhina MA 《The Journal of organic chemistry》2006,71(17):6615-6618
The first X-ray structural characterization of an alkyl-substituted corannulene, namely, 1,3,5,7,9-penta-tert-butylcorannulene (C40H50), has been accomplished. The addition of bulky tert-butyl groups to the corannulene core flattens the bowl and affects the solid-state packing. The presence of two enantiomers, in addition to positional disorder of the C40H50 bowls in the solid-state structure, has prevented the acquisition of accurate geometric parameters of this open geodesic polyarene. Therefore, DFT calculations have been used to describe its molecular geometry and to access bond lengths, bond angles, and a bowl depth. 相似文献
614.
615.
In this paper we consider non-deterministic finite Rabin-Scott’s automata. We use a special structure to describe all the possible edges of non-deterministic finite automaton defining the given regular language. Such structure can be used for solving various problems of finite automata theory. One of these problems is edge-minimization of non-deterministic automata. As we have not touched this problem before, we obtain here two versions of the algorithm for solving this problem to continue previous series of articles. 相似文献
616.
Yulia E. Morozova Liubov S. Kuznetzova Asia R. Mustafina ELLA Kh Kazakova Vladimir I. Morozov ALBINA Yu Ziganshina Alexsandr I. Konovalov 《Journal of inclusion phenomena and macrocyclic chemistry》1999,35(1-2):397-407
On the basis of RCA, pH-potentiometry and EPR-spectroscopy data aminoalkylated derivatives were proved to bind metal ion complexes both in alkaline and in acidic media. Outer-sphere coordination is the only interaction mode in these host-guest complexes. 相似文献
617.
618.
Dr. Vyacheslav Sushev Dr. Yulia Panova Dr. Alexandra Khristolyubova Dr. Natalia Zolotareva Matvey Grishin Dr. Roman Rumyantcev Ekaterina Kozlova Prof. Dr. Georgy Fukin Prof. Dr. Alexander Kornev 《欧洲无机化学杂志》2023,26(23):e202300252
A number of two-deck dicationic 3a,6a-diaza-1,4-diphosphapentalenes (DDP)2X2 (X=halogen or complex ion) have been characterized. Interdeck distances P(1)⋅⋅⋅P(3) and P(2)⋅⋅⋅P(4) in crystal structures, as a rule, significantly exceed the sum of covalent radii, however they are still within the sum of van der Waals radii. The 31P NMR data indicate that phosphorus atoms are equivalent in solution even at low temperatures (233 K). Based on DFT calculations, the formation of two equivalent P−P covalent bonds (<2.4 Å) is energetically unfavorable, despite the absence of steric barriers. The total energy of the model dication as a function of the P⋅⋅⋅P separation has a minimum at the P−P distance of 2.85 Å. This distance corresponds to the highest aromaticity index in the interdeck space (NICS(1.0)=−20.72). The energy of interdeck interactions is estimated at 10–15 kcal/mol. 相似文献
619.
Thermal polymerization of 2-hydroxyethylmethacrylate (HEMA) and radical polymerization initiated by an acrylamid complex of cobalt nitrate in the presence of unmodified and surface treated silicas have been investigated. It has been found that the introduction of fillers, especially silicas with grafted silicon hydride groups, makes an essential effect on the rate and degree of the HEMA polymerization. 相似文献
620.