全文获取类型
收费全文 | 2666篇 |
免费 | 178篇 |
国内免费 | 37篇 |
专业分类
化学 | 1797篇 |
晶体学 | 24篇 |
力学 | 78篇 |
综合类 | 3篇 |
数学 | 254篇 |
物理学 | 725篇 |
出版年
2023年 | 13篇 |
2022年 | 25篇 |
2021年 | 54篇 |
2020年 | 42篇 |
2019年 | 44篇 |
2018年 | 38篇 |
2017年 | 29篇 |
2016年 | 74篇 |
2015年 | 72篇 |
2014年 | 107篇 |
2013年 | 130篇 |
2012年 | 192篇 |
2011年 | 217篇 |
2010年 | 123篇 |
2009年 | 130篇 |
2008年 | 185篇 |
2007年 | 182篇 |
2006年 | 134篇 |
2005年 | 137篇 |
2004年 | 96篇 |
2003年 | 75篇 |
2002年 | 79篇 |
2001年 | 68篇 |
2000年 | 64篇 |
1999年 | 23篇 |
1998年 | 15篇 |
1997年 | 20篇 |
1996年 | 18篇 |
1995年 | 29篇 |
1994年 | 28篇 |
1993年 | 49篇 |
1992年 | 27篇 |
1991年 | 25篇 |
1990年 | 21篇 |
1989年 | 14篇 |
1988年 | 17篇 |
1987年 | 13篇 |
1986年 | 14篇 |
1985年 | 29篇 |
1984年 | 18篇 |
1983年 | 13篇 |
1982年 | 20篇 |
1980年 | 20篇 |
1979年 | 16篇 |
1978年 | 19篇 |
1977年 | 14篇 |
1976年 | 18篇 |
1975年 | 14篇 |
1974年 | 12篇 |
1973年 | 12篇 |
排序方式: 共有2881条查询结果,搜索用时 15 毫秒
81.
After the earlier analysis of nine bisbenzylisoquinoline alkaloids with ion pair chromatography, seven other bisbenzylisoquinoline alkaloids were analyzed using gradient elution with an acetonitrile-phosphate buffer (pH 8.0) mixture, and UV detection. Four alkaloids were detected in the stem woods of a Lauraceous plant, Dehaasia triandra Merr. and their contents determined. LC-MS suggested that a major unknown compound in the plant was also a bisbenzylisoquinoline alkaloid. 相似文献
82.
Four new cyclopropyl-triterpenes, 27-nor-3beta-hydroxy-25-oxocycloartane (1), (22E)-25,26,27-trinor-3beta-hydroxycycloart-22-en-24-al (2), 3beta-acetoxy-15alpha-hydroxy-13,27-cyclours-11-ene (3), 3beta-acetoxy-12alpha-formyloxy-13,27-cycloursan-11alpha-ol (4), together with (23E)-27-nor-3beta-hydroxycycloart-23-en-25-one (5) were isolated from the aerial roots of Ficus microcarpa. Compounds 3 and 4 are rare 13,27-cycloursane-type triterpenes. Their structures were elucidated by spectroscopic and chemical methods. 相似文献
83.
Winghong Chan Suei Yee Lam-Leung Chingfai Ng Junqi Ding Shiping Xi 《Journal of polymer science. Part A, Polymer chemistry》1995,33(15):2525-2531
New diamino monomers IIa – IIg were synthesized in a two-step reaction sequence starting from p-acetamidobenzenesulfonyl chloride. Solution polymerization of these monomers in DMAC with terephthaloyl or isophthaloyl chloride resulted in the formation of a series of 14 poly(amide sulfonamide)s (PASAs) in excellent yield (> 95%). The polymers have in-trinsic viscosities of 0.32–1.11 dL g?1. Except for polymers IIIa ? p and IIId - p , all other PASAs were readily soluble in aprotic polar solvents including DMAC, DMF, and DMSO. Thermogravimetric analyses of the polymers showed moderate thermal stability with 10% weight loss being recorded in the range of 325–408°C. In addition, these polymers exhibit moderate chemical stabilities toward alkali, acidic, and chromic acid solution. © 1995 John Wiley & Sons, Inc. 相似文献
84.
LacTek tests are competitive enzyme-linked immunosorbent assays intended for rapid detection of antimicrobial residues in bovine milk. In this study, the LacTek test protocol was modified for use with extracts of bovine tissue to detect beta-lactam, tetracycline, and sulfamethazine residues. Test performance characteristics--precision, accuracy, ruggedness, practicability, and analytical specificity and sensitivity--were investigated. Results suggest that LacTek tests can be easily adapted to detect antimicrobial residues in extracts of lean ground beef. However, positive samples may not contain residues at violative concentrations (i.e., Canadian maximum residue limits), and therefore, additional analysis would be required for final confirmation and quantitation (e.g., chromatography). 相似文献
85.
Further studies on the bark of Taiwania cryptomerioides found four new podocarpane derivatives, 1beta,13-dihydroxy-8,11,13-podocarpatriene (1), 14,18-dihydroxy-13-methoxy-8,11,13-podocarpatriene (2), 1beta,14-dihydroxy-13-methoxy-8,11,13-podocarpatriene-2,7-dione (3), and 3beta,14-dihydroxy-13-methoxy-8,11,13-podocarpatrien-7-one (4), together with a known 1beta,13,14-trihydroxy-8,11,13-podocarpatrien-7-one (5). Those structures were elucidated principally from spectral evidence. 相似文献
86.
Hugh Y. Yee 《Microchemical Journal》1978,23(4):426-432
Five methods of acid digestion of amniotic fluid phospholipids for inorganic phosphate release were evaluated at a temperature of 225 °C and a heating time of 30 min. The methods used the following digestants: (A (perchloric acid), B (perchloric acid containing molybdate), C (sulfuric acid, 30% hydrogen peroxide, 5% urea), D (sulfuric-perchloric acids), and E (sulfuric-perchloric acids with vanadium pentoxide). After digestion and dilution with water, a hydrogen ion concentration of about 2.5 mol/ liter was obtained that permitted the use of stannous chloride-hydrazine sulfate as the reducing agent for phosphate color development. Recoveries of the different amniotic fluid phospholipids and aqueous phosphate standards were quantitative for all methods. A comparative study with amniotic fluids showed similar results for all methods. Since all methods were found to be equivalent under the specified conditions described, the choice was dependent upon the user's preference. 相似文献
87.
Yee NC Chottiner GS Scherson DA 《Langmuir : the ACS journal of surfaces and colloids》2005,21(23):10256-10259
Adsorption of small amounts of D(2)O (ca. 0.01 L exposure) on CO(sat)/Pt(100) surfaces in ultrahigh vacuum at 105 K was found to split the asymmetric peak at 2100 cm(-1) in the infrared reflection absorption spectra attributed to the stretching of CO adsorbed on atop sites into two clearly defined features: an intense component, which shifted toward lower energies due to surface hydration of adsorbed CO (originally at 2100 cm(-1), peak a), and a smaller peak centered at 2094 cm(-1) (peak b), which remained fixed in position even after closing the D(2)O dosing valve. The energies of peaks a and b, as determined by statistical analyses, correlated very well with those reported in the literature for CO adsorbed at high coverages on Pt(100) originally in the (5 x 20) or (hex) reconstruction, and on the unreconstructed Pt(100)-(1 x 1), respectively, at 90 K. On these bases, the asymmetry of the peak observed for CO(sat)/Pt(100) (no D(2)O dosing) is ascribed to the presence of CO linearly adsorbed on these two different sites on the surface, for which the rate of hydration is larger for the (5 x 20) compared to the (1 x 1) phases. 相似文献
88.
Four new lignans, 3',4'-O,O-demethylenehinokinin (1), chamalignolide (2), 8'beta-hydroxyhinokinin (3) and 7beta,8beta-epoxyzuonin A (4), as well as (-)-hinokinin (5), and (-)-zuonin A (6), were isolated from the heartwood of Chamaecyparis obtusa var. formosana. The structures of these lignans were unambiguously determined by spectroscopic methods. And the absolute configuration of 1 was elucidated with a circular dichroism (CD) spectrum. 相似文献
89.
The influence of the sizes of charged species on the stability of a colloidal dispersion is investigated theoretically. We consider the case where a particle comprises a rigid core and an amphoteric, charge-regulated membrane layer, which simulates biocolloids and particles covered by artificial membranes. A modified Poisson-Boltzmann equation, which takes the sizes of all the charged species into account, is adopted to describe the electrical field. The effects of other key parameters such as electrolyte concentration, pH, and the valence of counterions on the behavior of a dispersion are also examined. We show that the larger the effective size of the counterions, the greater the stability ratio, which is consistent with experimental observations in the literature. 相似文献
90.
Modified nucleosides in human serum. 总被引:1,自引:0,他引:1
E P Mitchell L Evans P Schultz R Madsen J W Yarbro C W Gehrke K Kuo 《Journal of chromatography. A》1992,581(1):31-40
Methylated purines and pyrimidines derived from the degradation of transfer ribonucleic acid have been shown to be excreted in abnormal amounts in the urine of patients with cancer. Recent technology developed by Gehrke and Kuo has allowed the separation and quantification of modified nucleosides in serum using reversed-phase high-performance liquid chromatography with diode-array measurement. Serum levels of ten modified nucleosides were measured in 37 normal healthy adults to establish normal values and to correlate activity with age and sex. In addition, serum levels of patients with several malignancies were measured to determine activity in these diseases. Levels of modified nucleosides in normal individuals were consistently reproducible and showed no significant variation among males versus females or with age. Patients with malignant diseases showed consistent elevations and these were highest in patients with more advanced disease. The evidence of no significant differences in the mean levels of modified nucleosides in serum with age or sex in normal adults and elevations in patients with malignancies demonstrate the potential value of modified nucleosides as cancer biomarkers. 相似文献