Energy of planar defects in the Ni<Subscript>3</Subscript>Al phase: Theory and experiment

The Ni₃Al phase with an L1₂ surperstructure exhibits a clearly pronounced positive temperature dependence of the yield stress. The nature of this phenomenon is still not clearly understood. The temperature dependence of the yield stress under consideration is determined, in many respects, by the structure of glide superdislocations and planar defects of these superdislocations involved in the L1₂ superstructure. A critical analysis is made of the current state of the art in the solution of the problem regarding the energy of antiphase boundaries in planes of an octahedron and a cube, as well as the energy of stacking faults in the Ni₃Al phase.     

Description of mechanical properties of particulate-filled nanostructured polymer composites using fractal analysis

A number of the main mechanical characteristics (yield strength, impact toughness, microhardness) of particulate-filled polymer nanocomposites are quantitatively described using fractal analysis. The approach is used to study the main mechanical behavior features of these materials. The influence of the initial particle size of nanofiller and the degree of particle aggregation on the mechanical properties of nanocomposites is shown.     

Synthesis and Complexing Properties of Phosphorus-Substituted Pyridine-2-Carboxylic Acid Anilides

Abstract

Novel phosphorus-containing ligands have been synthesized by the condensation of 2-(thio)phosphorylated anilines with 2,6-dichloro- and 4-chloropyridine-2-carbonyl chlorides in the presence of Et₃N and unsubstituted pyridine-2-carboxylic acid using P(OPh)₃ as a coupling agent. The compounds derived readily form complexes with a range of transition metals (M=Re(I), Pd(II), and Cu(II)), serving as bi- or tridentate monoanionic ligands. The composition and structure of the resulting metallocycles depend both on the presence/amount of the Cl atoms in the pyridine ring and on the nature of the donor atom X in the P=X moiety. The novel compounds were characterized by multinuclear NMR and IR spectroscopy as well as X-ray crystallography.     

Synthesis and Electrochemical Properties of 2-(4-R 1 -Phenyl)-6-(4-R 2 -phenyl)-4-phenyl-3,4-dihydro1,2,4,5-tetrazin-1(2 H )-yls

A new methodology for creating electroactive components for organic batteries, based on the construction of a molecular platform including stable 3,4-dihydro-1,2,4,5-tetrazin-1(2H)-yl radicals was described. A series of 2-(4-R1-phenyl)-6-(4-R2-phenyl)-4-phenyl-3,4-dihydro-1,2,4,5-tetrazin-1(2H)-yls with substituents of various nature was obtained. It was shown that the substituents R1 in the aromatic ring at position 2 of the tetrazinyl fragment influence the value of the oxidation potential in the radical, but do not influence the value of the reduction potentials, while the substituent R2 of the aromatic ring at position 6 influence the values of the reduction potentials and practically do not influence oxidation potential values. Based on the obtained electrochemical data, a correlation structure–potential value was revealed for the cathodic and anodic process, with the help of which triarylsubstituted 3,4-dihydro-1,2,4,5-tetrazin-1(2H)-yl radicals with high values of the electrochemical gap were obtained.     

Explosive plasma-vortex optical radiation sources

The results of experimental study of explosive radiation sources based on pulsed injection of a cumulative plasma jet into atmospheric air are considered. The injection process is accompanied with intense vortex formation as well as the formation of a large-scale toroidal plasma vortex. High-power electromagnetic radiation in the optical range is generated due to shock-wave processes during deceleration of a plasma jet in air and plasma-chemical processes in the vortex. The temporal structure of a radiation pulse being generated contains components from the micro- and millisecond range. For a 20-g mass of the explosive charge, a peak radiation power of 300 kW/sr and an energy yield of 400–600 J/sr integrated over the emission spectrum are attained. The efficiency of conversion of the chemical energy of the explosive into radiation is 5.0–7.5%.     

Methane conversion in a multielectrode slipping surface discharge in the two-phase water-gas medium

The multielectrode slipping surface discharge in a two-phase water-gas (methane) medium is studied experimentally as a plasma-chemical converter of methane into various hydrocarbons, carbon, and hydrogen. The energy value of methane decomposition is on the order of 5 eV/molecule, which is close to record-high values attained in high-pressure discharges. The degree of conversion of methane is determined and the possibility of its substantial increase is considered.     

Modulation characteristics of resonance lines of Cs atoms in cells with antirelaxation coating

Modulation characteristics of absorption at the resonance D ₁ line of cesium atoms in a cell with antirelaxation coating are studied. It is experimentally shown that the minimum of the response to harmonic modulation in a certain frequency band coincides with Maxwellian velocity distribution maximum, despite the line profile distortion observed during linear frequency scanning [1]. The effect is theoretically explained.