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991.
Kanitskaya L. V. Elokhina V. N. Fedorov S. V. Shulunova A. M. Nakhmanovich A. S. Turchaninov V. K. Lopyrev V. A. 《Russian Journal of General Chemistry》2002,72(5):778-784
Pyridine was reacted with propargyl bromide to obtain the dibromide [C5H5NCH = CHCH = CHCH = CHC5H5N]2
+ 2Br-. The effect of the vinyl group on its UV spectrum is qualitatively interpreted using the results of nonempirical quantum-chemical calculations (basis HF/6-31G*). 相似文献
992.
Tikhova V. D. Shakirov M. M. Fadeeva V. P. Dergacheva M. I. Samutenko L. V. Fedorova L. V. 《Russian Journal of Applied Chemistry》2002,75(5):829-833
Quantitative and qualitative changes in humic acids of meadow soddy soils, occurring under the action of various fertilizer systems, were studied by 13C and 31P NMR. 相似文献
993.
Rakhmankulov D. L. Shavshukova S. Yu. Latypova F. N. Zorin V. V. 《Russian Journal of Applied Chemistry》2002,75(9):1377-1383
The use of microwave techniques in scientific research is reviewed. Also some semicommercial-scale microwave units are examined. 相似文献
994.
V. A. Krylov O. Yu. Chernova Yu. M. Salganskii L. S. Malygina A. P. Kotkov 《Journal of Analytical Chemistry》2003,58(8):750-755
It is shown that the results of determining methane in high-purity arsine by reaction gas chromatography can be overestimated by more than two orders of magnitude. This overestimation is caused by the formation of methane as a side product of the reaction. Cryogenic preconcentration at the injection stage is proposed to improve the accuracy of determination of methane, and the cryofocusing of impurity hydrocarbons is proposed to improve separation. Detection limits of (3–10) × 10–6 vol % are achieved for C1–C5 hydrocarbons. 相似文献
995.
996.
Savos'kin M. V. Yaroshenko A. P. Mysyk R. D. Vaiman G. E. Vovchenko L. L. Popov A. F. 《Theoretical and Experimental Chemistry》2004,40(2):92-97
New thermally stable intercalation compounds of graphite were obtained by the further intercalation of a series of organic compounds into graphite nitrate. The stabilization is explained by the formation of hydrogen bonds between the protonated form of the modifying substance and neutral surrounding molecules. 相似文献
997.
998.
It was found experimentally that stacking defects formed in the mechanochemical activation of zinc ferrite enhanced the specific catalytic activity in the reaction of CO oxidation. The specific rate of CO oxidation was a linear function of defect concentration, which was determined using Mössbauer spectroscopy and X-ray diffraction. A conclusion was drawn that the same centers are responsible for an increase in the catalytic activity, the sorption capacity for hydrogen sulfide, and the reactivity of zinc ferrite in the interaction with hydrochloric acid. It was assumed that analogous factors caused an increase in the catalytic activity and reactivity of magnesium ferrite. 相似文献
999.
Abdrakhmanova L. A. Fakhrutdinova V. Kh. Khozin V. G. 《Russian Journal of Applied Chemistry》2003,76(11):1832-1834
The structural transformations of oligoglycol acrylates in the surface layers of polymethyl methacrylate were studied. 相似文献
1000.
Krylov I. O. Lugovskaya I. G. Anufrieva S. I. Krylova A. V. 《Russian Journal of Applied Chemistry》2003,76(8):1234-1237
The chemical composition, specific surface area, and pore structure of a schungite sorbent were studied as influenced by the conditions of thermal treatment. 相似文献