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61.
表面辅助的金属有机纳米结构因其结构稳定性和潜在应用受到广泛关注。在金属有机纳米结构中,金属原子来源于外部沉积的金属或金属表面原子。外部沉积的金属原子种类多样,取决于目标纳米结构。然而,金属表面原子受限于表面科学常用的金、银和铜单晶金属表面。金属有机纳米结构大多包括Au配位或是Cu配位结构,而只有少量的用表面Ag原子构成。分子金属相互作用的进一步研究有助于预期纳米结构的精确控制形成。至于构建基元,有机分子通过M―C、M―N和M―O键与表面金属原子配位。末端炔反应或者乌尔曼耦合能够实现C―M―C节点的形成。Cu和Au原子能够与含有末端氰基或吡啶基官能团的分子配位形成N―M―N键。另外,表面Ag增原子能够通过Ag―N配位键与酞菁分子配位。然而,M―O配位键的相关研究较少。因此,我们计划使用末端羟基分子与Ag增原子配位形成金属有机配位纳米结构去研究O―Ag节点。我们通过扫描隧道显微镜利用4, 4’-二羟基-1, 1’: 3’, 1’’-三联苯分子(4, 4’-dihydroxy-1, 1’: 3’, 1’’-terphenyl,H3PH)和Ag增原子成功构筑了一系列二维有序纳米结构。在室温下,蒸镀的H3PH分子自组装形成由环氢键连接的密堆积结构。当退火温度提升到330 K,一种新的纳米结构出现了,该结构由O―Ag配位键和氢键共同作用形成。进一步地提升退火温度至420 K,蜂巢结构和共存的二重配位链出现,这两种结构中仅由O―Ag―O键构成。为分析金属分子反应路径和O―Ag―O键的能量势垒,我们对该体系进行密度泛函理论计算。计算结果显示,O―Ag键形成的能量势垒是1.41 eV,小于O―Ag―O节点1.85 eV的能量势垒。这也解释了分等级金属-有机纳米结构形成的原因。我们的实验结果提供了一种利用有机小分子和金属增原子来设计和构筑分等级二维纳米结构的有效方法。 相似文献
62.
In single-molecule junctions, anchoring groups that connect the central molecule to the electrodes have profound effects on the mechanical and electrical properties of devices. The mechanical strength of the anchoring groups affects the device stability, while their electronic coupling strength influences the junction conductance and the conduction polarity. To design and fabricate high-performance single-molecule devices with graphene electrodes, it is highly desirable to explore robust anchoring groups that bond the central molecule to the graphene electrodes. Condensation of ortho-phenylenediamine terminated molecules with ortho-quinone moieties at the edges of graphene generates graphene-conjugated pyrazine units that can be employed as anchoring groups for the construction of molecular junctions with graphene electrodes. In this study, we investigated the fabrication and electrical characterization of single-molecule field-effect transistors (FETs) with graphene as the electrodes, pyrazine as the anchoring groups, and a heavily doped silicon substrate as the back-gate electrode. Graphene nano-gaps were fabricated by a high-speed feedback-controlled electro-burning method, and their edges were fully oxidized; thus, there were many ortho-quinone moieties at the edges. After the deposition of phenazine molecules with ortho-phenylenediamine terminals at both ends, a large current increase was observed, indicating that molecular junctions were formed with covalent pyrazine anchoring groups. The yield of the single-molecule devices was as high as 26%, demonstrating the feasibility of pyrazine as an effective anchoring group for graphene electrodes. Our electrical measurements show that the ten fabricated devices exhibited a distinct gating effect when a back-gate voltage was applied. However, the gate dependence of the conductance varied considerably from device to device, and three types of different gate modulation behaviors, including p-type, ambipolar, and n-type conduction, were observed. Our observations can be understood using a modified single-level model that takes into account the linear dispersion of graphene near the Dirac point; the unique band structure of graphene and the coupling strength of pyrazine with the graphene electrode both crucially affect the conduction polarity of single-molecule FETs. When the coupling strength of pyrazine with the graphene electrode is weak, the highest occupied molecular orbital (HOMO) of the central molecule dominates charge transport. Depending on the gating efficiencies of the HOMO level and the graphene states, devices can exhibit p-type or ambipolar conduction. In contrast, when the coupling is strong, the redistribution of electrons around the central molecule and the graphene electrodes leads to a realignment of the molecular levels, resulting in the lowest unoccupied molecular orbital (LUMO)-dominated n-type conduction. The high yield and versatility of the pyrazine anchoring groups are beneficial for the construction of single-molecule devices with graphene electrodes. 相似文献
63.
有杆抽油系统动态特性的计算机仿真 总被引:1,自引:0,他引:1
本文建立了有杆抽油系统动态特性仿真的综合数学模型.即应用数值积分法建立转子运动规律的仿真模型和应用差分法建立抽油杆柱纵向振动的仿真模型。本文提出了一种叠代方法较好地解决了两子系统之间相互耦合的问题,给出了一种便于应用的井下边界条件的仿真方法。 相似文献
64.
Liping Meng Shimin WuFujun Ma Ai JiaJianying Hu 《Journal of chromatography. A》2010,1217(29):4873-4876
A simple, fast and sensitive liquid chromatography–electrospray tandem mass spectrometry method was established for trace levels of nine haloacetic acids (HAAs) in drinking water. Water samples were removed of residual chlorine by adding l-ascorbic acid, and directly injected after filtered by 0.22 μm membrane. Nine HAAs were separated by liquid chromatography in 7.5 min, and the limits of detection were generally between 0.16 and 0.99 μg/L except for chlorodibromoacetic acid (1.44 μg/L) and tribromoacetic acid (8.87 μg/L). The mean recoveries of nine target compounds in spiked drinking water samples were 80.1–108%, and no apparent signal suppression was observed. Finally, this method was applied to determine HAAs in the tap water samples collected from five waterworks in Shandong, China. Nine HAAs except for monochloroacetic acid, monobromoacetic acid, dibromochloroacetic acid and tribromoacetic acid were detected, and the total concentrations were 7.79–36.5 μg/L. The determination results well met the first stage of the Disinfectants/Disinfection By-Products (D/DBP) Rules established by U.S.EPA and Guidelines for Drinking-water Quality of WHO. 相似文献
65.
The fundamental measurement theory of an electrostatic probe and cross-correlation velocity measurement method are introduced in this paper. The effects of the probe's geometric parameters, including the length of the probe; the thickness, length and relative permittivity of the dielectric pipe; the radius of the screen on the dimensionless calibration coefficient (k), and the statistical error of the transit time (τm) of the correlation velocity measurement system using electrostatic probes were investigated theoretically. Finally the measurement system was applied in a 10 mm bore horizontal section of a dense-phase pneumatic conveying system under high pressure circulating pulverized coal over a superficial air velocity range of 0.5–7 m/s for a particle concentration 0.052–0.141 m3/m3. The experimental results that were obtained demonstrate that the system is capable of providing solid particle velocity measurements with repeatability better than 10% under the given experimental conditions. 相似文献
66.
The uniformly optimal graph problem with node failures consists of finding the most reliable graph in the class Ω(n,m) of all graphs with n nodes and m edges in which nodes fail independently and edges never fail. The graph G is called uniformly optimal in Ω(n,m) if, for all node-failure probabilities q∈(0,1), the graph G is the most reliable graph in the class of graphs Ω(n,m). This paper proves that the multipartite graphs K(b,b+1,…,b+1,b+2) are uniformly optimal in their classes Ω((k+2)(b+1),(k2+3k+2)(b+1)2/2−1), where k is the number of partite sets of size (b+1), while for i>2, the multipartite graphs K(b,b+1,…,b+1,b+i) are not uniformly optimal in their classes Ω((k+2)b+k+i,(k+2)(k+1)b2/2+(k+1)(k+i)b+k(k+2i−1)/2). 相似文献
67.
We report an effective method for bulk obtaining exfoliated graphene oxide (GO) solids from their aqueous solutions, which were prepared from nature graphite by an oxidation method. Tyndall effect proved that GO solution has a colloidal nature. Different flocculants were used to coagulate GO colloidal, and it was found that NaOH had the most obvious coagulation effect to GO. Transmission electron microscopy, X‐ray diffraction and atomic force microscopy analysis demonstrated that there were a large number of complete few‐layer GO sheets with thickness of about 0.8 nm, and the surfaces were very smooth, almost free of impurities. Liquid state 13C NMR and Fourier transformation infrared spectra showed the presence of abundant benzene carboxylic, hydroxyl and epoxide groups in the basal planes of GO. The graphene materials reduced from GO solids had good electrical conductivity. Our work explored a simple and effective route to extract GO from their solution, which is the most important to GO and graphene researches and applications. 相似文献
68.
69.
研究了7种取代查耳酮肟的电化学行为。用氢氧化钠底液热解石墨工作电极,取代查耳酮肟的电极过程为1e氧化不可逆吸附电极过程。它们的氧化电位随取代基吸电子能力的增强而增高,并与它们相应的Hammett常数呈线性关系。取代查耳酮肟的电化学氧化机理为先失去一个电子生成iminoxy自由基,然后由基对分子内烯键进行环化加成,脱氢后形成3,5-二聚代异恶唑。用控电位电解和紫外吸收光谱检测了部份电化学氧化产物,证 相似文献
70.
Wang Shimin Li Zuoyi Zhang Duanming Zhang Gangsheng Sun Junmei Zheng Ping 《Journal of Sol-Gel Science and Technology》2000,17(2):159-162
KTa0.65Nb0.35O3(KTN) thin films were prepared by sol-gel process on Pt(111)/Ti/MgO(100) substrates from KOAc, Ta(OC2H5)5 and Nb(OC2H5)5 in ethanol. The KTN thin films had a prefferred (100) orientation on Pt(111)/Ti/MgO(100) substrates and contained a small amount of pyrochlore structure phase. The 0.8-m-thick KTN film showed a room-temperature relative permittivity of 2160 and a room-temperature dielectric loss of 0.0098 at 1.0 kHz. The maximum relative permittivity of the KTN film was 4232 at 294 K and 1.0 kHz. The remanent polarization and coercive field of the KTN film were 2.8 C/cm2 and 5.0 kV/cm, respectively, at 263 K. 相似文献