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91.
Angular distributions of deuterons and tritons from the reactions52,53Cr(d,d),52,53Cr(d,d′),53,54Cr(d, t)52,53Cr have been measured at Ed=11.8 to 11.9 MeV. The elastic scattering data have been analyzed in terms of the optical model. The (d, d′) and (d, t) data have been compared with DWBA calculations. Deformation parameters and spectroscopic factors have been extracted. The results are qualitatively discussed in terms of different nuclear models. 相似文献
92.
The reactions48Ca(d, t)47Ca and48Ca(3He, α)47Ca have been measured at incident energies of 17 and 18 MeV, respectively and analysed by DWBA. Besides strong transitions to the groundstate and two unresolved states at aboutE x =2.60 MeV relatively strong transitions withl=2 are observed at higher excitation energies in the (3He, α) reaction. The observedl=1 and higherl=3 transitions are rather weak indicating that particle-hole components in the48Ca groundstate are relatively small. 相似文献
93.
Di Bella S Sortino S Conoci S Petralia S Casilli S Valli L 《Inorganic chemistry》2004,43(17):5368-5372
In this paper the preparation and characterization of Langmuir-Sch?fer (LS) films of a novel amphiphilic dipolar complex, [Ru(II)(NH(3))(5)(N-dodecyl-4,4'-bpy)](PF(6))(3) (1), are reported. Preparation of these films, otherwise precluded utilizing standard Langmuir procedures, is achieved by using a subphase at relatively high ionic strength, by addition of NH(4)PF(6). The morphology and the spectroscopic features of the floating films are investigated by Brewster angle microscopy and UV-vis reflection spectroscopy at the water-air interface, respectively, whereas LS films are characterized by absorption spectroscopy and atomic force microscopy. The overall results indicate the existence of aggregates of 1 and formation of homogeneous, densely packed layers. The presented approach could represent a general method to achieve Langmuir-Blodgett films of amphiphilic metal complexes having an "almost naked" multicharged headgroup. 相似文献
94.
C. S. Carvalho A. A. Martin A. M. E. Santo L. E. C. Andrade M. M. Pinheiro M. A. G. Cardoso L. Raniero 《Theoretical chemistry accounts》2011,130(4-6):1211-1220
Rheumatoid arthritis (RA) is characterized by chronic inflammation of the joints and can lead to a progressive destruction of articular cartilage and bone. In this study, the specificity and sensitivity of the RA diagnostic methods based on the receiver-operating characteristic curves for monitoring C-reactive protein (CRP) and rheumatoid factor (RF) were compared with the Raman spectroscopic diagnostic method developed in this work. Sera from 24 patients with rheumatoid arthritis and from 16 healthy individuals were analyzed to assess the biochemical composition and presence of inflammatory activity by the aforementioned methods. By comparing with the clinical results for specificity and sensitivity from the RF and CRP tests, we show that the overall results from the newly developed Raman method were significantly better, with a specificity of 96%, a sensitivity of 88%, and correctly identifying 92% of the RA and healthy individuals, while the RF test gave a specificity of 100% and a sensitivity of 54%, and the CRP test gave a specificity of 87% and a sensitivity of 58%, respectively. 相似文献
95.
Roman Denysiuk Lino Costa Isabel Espírito Santo 《Journal of Mathematical Modelling and Algorithms》2013,12(3):233-251
Hybridization of local search based algorithms with evolutionary algorithms is still an under-explored research area in multiobjective optimization. In this paper, we propose a new multiobjective algorithm based on a local search method. The main idea is to generate new non-dominated solutions by adding a linear combination of descent directions of the objective functions to a parent solution. Additionally, a strategy based on subpopulations is implemented to avoid the direct computation of descent directions for the entire population. The evaluation of the proposed algorithm is performed on a set of benchmark test problems allowing a comparison with the most representative state-of-the-art multiobjective algorithms. The results show that the proposed approach is highly competitive in terms of the quality of non-dominated solutions and robustness. 相似文献
96.
A. Tumino C. Spitaleri A. Mukhamedzhanov S. Typel M. Aliotta V. Burjan M. Gimenez del Santo G. G. Kiss V. Kroha Z. Hons M. La Cognata L. Lamia J. Mrazek R. G. Pizzone S. Piskor G. G. Rapisarda S. Romano M. L. Sergi R. Spart�� 《Few-Body Systems》2011,50(1-4):323-325
The 2H(d,p)3H and 2H(d,n)3He reactions have been indirectly studied by means of the Trojan Horse Method applied to the quasi-free 2H(3He, p3H)1H?2H(3He, n3He)1H reaction at 18?MeV of beam energy. This is the first experiment where the spectator (here 1H) has been detected in coincidence with the charged participant, avoiding the limitations of standard neutron detectors. The d ? d relative energy has been measured from 1.5?MeV down to 2?keV, at center of mass angles from 40° to 170°. Indirect angular distributions are compared with the direct behaviour in the overlapping regions. 相似文献
97.
Nonlinear Dynamics - We propose a noise-assisted tumor-immune system based on the Wiener process. Stochastic sensitivity and chaos both are studied with the variations of noise strengths. The... 相似文献
98.
Favretto D Vogliardi S Stocchero G Nalesso A Tucci M Ferrara SD 《Journal of chromatography. A》2011,1218(38):6583-6595
A high performance liquid chromatography-high resolution mass spectrometry (HPLC-HRMS) method for simultaneous screening and quantification of 28 drugs was developed and validated for 2.5 mg hair samples. Target drugs and their metabolites included amphetamines, cocaine, opioids, benzodiazepines, antidepressants, and hallucinogens. After decontamination, hair samples were extracted with 200 μL of a mixture of water: acetonitrile:1 M trifluoroacetic acid (80:10:10, v/v) using a 5 min simultaneous pulverization/extraction step. The extracts were analysed by HPLC-HRMS in an Orbitrap at a nominal resolution of 60,000, with concomitant in source collisional experiments (in source CID). Gradient elution on an Atlantis T3 column resolved 28 target compounds and 5 internal standards. Total chromatographic run time was 26 min. Calibration was achieved by linear regression analysis utilizing six calibration points; R2 ranged from 0.9964 to 0.9999, the limits of quantification were 0.1 ng/mg for 8 compounds, 0.2 ng/mg for 16 compounds and 0.5 ng/mg for 4 compounds; mean relative errors from -21% to +23% were obtained; relative standard deviation, used to estimate repeatability and intermediate reproducibility at three concentrations, was always less than 20%. Process efficiency and recoveries for all analytes were better than 65 and 73%, respectively, at any concentration. The method was applied to hair samples from forensic investigations that contained a broad assortment of drugs of abuse and pharmaceuticals. The use of concomitant HRMS full scan and CID afforded the possibility of retrospective analysis for discovering untargeted drugs. 相似文献
99.
Consiglio G Failla S Finocchiaro P Oliveri IP Di Bella S 《Dalton transactions (Cambridge, England : 2003)》2012,41(2):387-395
The synthesis, characterization, (1)H NMR, optical absorption and fluorescent properties of a series of amphiphilic Schiff-base bis(salicylaldiminato)zinc(II) complexes are reported. Detailed (1)H NMR, DOSY NMR, optical absorption and fluorescence spectroscopy studies indicate the existence of aggregate species in solutions of non-coordinating solvents. The degree of aggregation is related to the nature of the bridging diamine. Chloroform solutions of complexes where the bridging diamine contains a naphthalene or the pyridine nucleus are always characterized by the presence of defined dimer aggregates, whereas oligomeric aggregates are likely formed by complexes where the bridging diamine contains a benzene ring. In coordinating solvents or in the presence of coordinating species, a complete deaggregation of the complexes occurs, because of the axial coordination to the Zn(II) ion, accompanied by considerable changes in the (1)H NMR and optical absorption spectra. The effect of the alkyl chains length seems to play a minor role in the aggregation properties, as noticed by (1)H NMR data, optical absorption and fluorescence spectra, which remain almost unaltered on changing the chain length. 相似文献
100.
Giacomo Berton Tommaso Lorenzetto Giuseppe Borsato Paolo Sgarbossa Claudio Santo Fabiano Visentin Fabrizio Fabris Alessandro Scarso 《Tetrahedron letters》2019,60(43):151202
C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations. 相似文献