全文获取类型
收费全文 | 200篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 186篇 |
力学 | 5篇 |
物理学 | 19篇 |
出版年
2024年 | 1篇 |
2022年 | 1篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 5篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 8篇 |
2012年 | 4篇 |
2011年 | 6篇 |
2010年 | 6篇 |
2009年 | 4篇 |
2008年 | 4篇 |
2007年 | 7篇 |
2006年 | 8篇 |
2005年 | 12篇 |
2004年 | 21篇 |
2003年 | 17篇 |
2002年 | 16篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1973年 | 2篇 |
1929年 | 1篇 |
1928年 | 1篇 |
排序方式: 共有210条查询结果,搜索用时 125 毫秒
31.
Akio Toshimitsu Toshiaki Aoai Hiroto Owada Sakae Uemura Masaya Okano 《Tetrahedron》1985,41(22):5301-5306
The reaction of phenylselenenyl chloride with olefins in aqueous acetonitrile affords β-hydroxyalkyl phenyl selenides in excellent yields, providing the most convenient method for hydroxyselenation of olefins so far reported. When the reaction was applied to conjugated dienes, monohydroxyselenated products were obtained in good to excellent yields. From non-conjugated dienes, on the other hand, cyclic ethers containing two phenylseleno groups were produced in good to excellent yields, the first step of this reaction being the hydroxyselenation of one double bond. 相似文献
32.
33.
34.
Oxidation of several linear conjugated dienes with tellurium (IV) oxide and lithium bromide in acetic acid affords an isomeric mixture of the corresponding diacetoxyalkenes (1,2- and 1,4-addition products), 1,4-isomer being highly selectively produced when the ratio of LiBr/TeO2, is 5–10. 相似文献
35.
Dutta S Abe H Aoyagi S Kibayashi C Gates KS 《Journal of the American Chemical Society》2005,127(43):15004-15005
Fasicularin is a structurally novel thiocyanate-containing alkaloid isolated from the ascidian Nephteis fasicularis. Early biological experiments suggested that this compound's cytotoxic properties may stem from its ability to damage cellular DNA. Sequence gel analysis reveals that treatment of a 5'-32P-labeled DNA duplex with fasicularin in pH 7.0 buffer causes strand cleavage selectively at guanine residues. Further experiments indicate that production of these base-labile lesions in DNA involves alkylation of guanine residues by a fasicularin-derived aziridinium ion. This work reveals fasicularin as the first natural product found to generate a DNA-alkylating aziridinium ion via a mechanism analogous to the clinically used anticancer drugs mechlorethamine, melphalan, and chlorambucil. 相似文献
36.
Treatment of several cyclic olefins, β-pinene, allylbenzene, and estragole with palladium(II) salt in acetic acid in the presence of t-butyl hydroperoxide and tellurium(IV) oxide afforded mainly the corresponding allylic acetates. The reaction proceeded catalytically with palladium(II) salt, t-BuOOH working as a reoxidizing agent. 相似文献
37.
38.
[reaction: see text] The reaction of heteroaromatic compounds with propargylic carboxylates in the presence of a catalytic amount of [RuCl(2)(CO)(3)](2) or PtCl(2) gives trienes in good yields. The key intermediate is an electrophilic (1-acetoxylvinyl)carbene complex generated from the activated propargylic acetates with transition metals. 相似文献
39.
Inagaki K Takatsu A Nakama A Eyama S Yarita T Okamoto K Chiba K 《Analytical and bioanalytical chemistry》2006,385(1):67-75
A method is described for determination of selenium in sediment by isotope-dilution inductively coupled plasma mass spectrometry
with an octapole reaction cell (ID–ICP–ORCMS). Sediment samples were digested with HNO3, HClO4, and HF, and the digestion included an elaborate evaporation process to remove bromine from the digested solution. Simple
strong cation-exchange disk filtration was used to remove rare earth elements (REE) from the digested solution, because REE2+ seriously interfere with Se isotopes (i.e. 156Gd2+ with 78Se+, 160Gd2+ with 80Se+). Addition of acetic acid to the filtrate was examined to improve the sensitivity of ICP–ORCMS measurement of Se+ by means of a carbon-enhancement effect. The interfering for selenium isotopes were almost eliminated by use of H2 as reaction gas. Interference from BrH+ formed in the reaction cell was negligible because the Br was removed in the evaporation process. Approximately 99.5% of
REE were removed by cation-exchange disk filtration yet more than 99% of Se remained in the filtrate solution. The intensity
for Se+ was enhanced approximately fourfold by addition of 5% (v/v) of acetic acid whereas that for was barely enhanced. Measured 80Se/78Se ratios in unspiked digested solutions of the sample were in good agreement with that for an Se standard solution. The analytical
results for Se in the certified reference materials MESS-3 and PACS-1 were in good agreement with their certified values,
with small uncertainties.
相似文献
40.