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21.
22.
Kevin J. Quinn Kaylie E. GageCaroline M. Stanners Colin O. HayesKathleen E. Shanley Shalise M. Couvertier 《Tetrahedron letters》2014
Synthesis of the C2-symmetric, non-adjacent bis(tetrahydrofuran) core of cis-sylvaticin in seven steps and 24% overall yield from (2R,3S)-1,2-epoxy-4-penten-3-ol is reported. A strategy involving assembly of the central 1,4-diol unit by silicon-tethered ring-closing metathesis and subsequent two-directional functionalization, including establishment of the cis/threo stereochemical relationships of the tetrahydrofuran rings by Sharpless asymmetric dihydroxylation/SN2 cyclization, is employed. 相似文献
23.
Frontispiece: NMR Fingerprints of the Drug‐like Natural‐Product Space Identify Iotrochotazine A: A Chemical Probe to Study Parkinson’s Disease
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24.
Frank Quinn 《Transactions of the American Mathematical Society》2002,354(4):1373-1392
This paper concerns decompositions of smooth 4-manifolds as the union of two handlebodies, each with handles of index . In dimensions results of Smale (trivial ) and Wall (general ) describe analogous decompositions up to diffeomorphism in terms of homotopy type of skeleta or chain complexes. In dimension 4 we show the same data determines decompositions up to 2-deformation of their spines. In higher dimensions spine 2-deformation implies diffeomorphism, but in dimension 4 the fundamental group of the boundary is not determined. Sample results: (1.5) Two 2-complexes are (up to 2-deformation) spines of a dual decomposition of the 4-sphere if and only if they satisfy the conclusions of Alexander-Lefshetz duality ( and ). (3.3) If is 1-connected then there is a ``pseudo' handle decomposition without 1-handles, in the sense that there is a pseudo collar (a relative 2-handlebody with spine that 2-deforms to ) and is obtained from this by attaching handles of index .
25.
Akikawa H Ajimura S Chrien RE Eugenio PM Franklin GB Franz J Gang L Imai K Khaustov P May M Pile PH Quinn B Rusek A Sasao J Sawafta RI Schmitt H Tamura H Tang L Tanida K Yuan L Zhou SH Zhu LH Zhu XF 《Physical review letters》2002,88(8):082501
With a germanium detector array (Hyperball), we observed two gamma-ray peaks corresponding to the two transitions (5/2(+)-->1/2(+) and 3/2(+)-->1/2(+)) in the (9)(Lambda)Be hypernucleus which was produced by the 9Be(K-,pi(-)) reaction. The energies of the gamma rays are 3029 +/- 2 +/- 1 keV and 3060 +/- 2 +/- 1 keV. The energy difference was measured to be 31.4(+2.5)(-3.6) keV, which indicates a very small Lambda-spin-dependent spin-orbit force between a Lambda and a nucleon. This is the smallest level splitting by far ever measured in a hypernucleus. 相似文献
26.
Development of high resolution pyrolysis-gas chromatography for the identification of microorganisms 总被引:4,自引:0,他引:4
P A Quinn 《Journal of chromatographic science》1974,12(12):796-806
27.
Biancardo M Quinn AJ Floyd L Mendes PM Briggs SS Preece JA Bignozzi CA Redmond G 《The journal of physical chemistry. B》2005,109(18):8718-8722
We report on charge transport measurements through laterally contacted assemblies of Au nanoparticles capped with 11-mercaptoundecanoic acid ligands. Both alternating- and direct-current data indicate that although the nanoparticles behave as electrically isolated metallic islands, there is a significant influence from the nanoparticle environment, indicating the existence of a slow reorganization process linked to charge transport. On the basis of the observation of temperature-dependent hysteresis of charge tunneling, we propose that this process is due to proton transfer between the carboxylic acid tails of the ligands. 相似文献
28.
Ratynskaia S Khrapak S Zobnin A Thoma MH Kretschmer M Usachev A Yaroshenko V Quinn RA Morfill GE Petrov O Fortov V 《Physical review letters》2004,93(8):085001
The charge of dust particles is determined experimentally in a bulk dc discharge plasma in the pressure range 20-100 Pa. The charge is obtained by two independent methods: one based on an analysis of the particle motion in a stable particle flow and another on an analysis of the transition of the flow to an unstable regime. Molecular-dynamics simulations of the particle charging for conditions similar to those of the experiment are also performed. The results of both experimental methods and the simulations demonstrate good agreement. The charge obtained is several times smaller than predicted by the collisionless orbital motion theory, and thus the results serve as an experimental indication that ion-neutral collisions significantly affect particle charging. 相似文献
29.
Alavi-Harati A Alexopoulos T Arenton M Arisaka K Barbosa RF Barker AR Barrio M Bellantoni L Bellavance A Blucher E Bock GJ Bown C Bright S Cheu E Coleman R Corcoran MD Cox B Erwin AR Escobar CO Ford R Glazov A Golossanov A Gouffon P Graham J Hamm J Hanagaki K Hsiung YB Huang H Jejer V Jensen DA Kessler R Kobrak HG Kotera K LaDue J Lai N Ledovskoy A McBride PL Monnier E Nelson KS Nguyen H Prasad V Qi XR Quinn B Ramberg EJ Ray RE Santos E Senyo K Shanahan P Shields J Slater W Solomey N Swallow EC 《Physical review letters》2003,90(14):141801
The KTeV experiment at Fermilab has isolated a total of 132 events from the rare decay K(L)-->e+ e- mu+ mu-, with an estimated background of 0.8 events. The branching ratio of this mode is determined to be [2.69+/-0.24(stat)+/-0.12(syst)]x10(-9), with a radiative cutoff of M(2)(ee mu mu)/M(2)(K)>0.95. The first measurement using this mode of the parameter alpha from the D'Ambrosio-Isidori-Portolès (DIP) model of the K(L)gamma*gamma* vertex yields a result of -1.59+/-0.37, consistent with values obtained from other decay modes. Because of the limited statistics, no sensitivity is found to the DIP parameter beta. We use this decay mode to set limits on CP and lepton violation. 相似文献
30.
The problem of obtaining inner approximations to the set
of null controllability for linear systems is considered, and the geometry of certain sets arising in the approximation of
using linear feedback is explored. A two-dimensional example is worked in detail in order to delineate the limitations to the use of linear feedback. 相似文献