2,2'-Bipyridinyl carboranes as B,N,N-ligands in cyclometallated complexes of platinum(II)

Novel B,N,N-cyclometallated Pt(II) complexes of 2,2'-bipyridin-6-yl carboranes exhibit absorption and emission similar to relative Pt(II) complexes of aromatic C,N,N-ligands: the same transitions but lower intensities. DFT calculations suggest the former emits from the (3)MLCT state while for the latter the mixed (3)ICT-MLCT transitions should be considered.     

Modeling of variations of the peak F2 layer electron density and total electron content during the recovery period after the magnetic storm of April 15–20, 2002

The results of numerical modeling by using the global upper atmosphere model of the Earth (UAM) for reproducing the peak F2 layer electron density (N _m F2) and total electron content (TEC) during recovery period after the magnetic storm of the April 15–20, 2002 are discussed. According to the simulations, the time it takes to reach a stationary regime of N _m F2 and TEC diurnal variations is 24 hours, much shorter then the plasmasphere refilling time. The results are compared with the predictions of the IRI-2007 empirical model and GPS data on the TEC and found in good quantitative agreement for the latitudinal variations of N _m F2 and TEC for daytime conditions in the southern hemisphere. The worst agreement occurs in the region of the main ionospheric trough.     

Dynamics of Inhomogeneous Chains of Coupled Quadratic Maps

A new effective local analysis method is elaborated for coupled map dynamics. In contrast to the previously suggested methods, it allows visually investigating the evolution of synchronization and complex-behavior domains for a distributed medium described by a set of maps. The efficiency of the method is demonstrated with examples of ring and flow models of diffusively coupled quadratic maps. An analysis of a ring chain in the presence of space defects reveals some new global-behavior phenomena.     

Etching of polyvinylidene fluoride with an alkaline solution of potassium permanganate

Kinetics of polyvinylidene fluoride etching with a permanganate alkaline solution used in manufacture of track membranes from hydrogen-containing fluoropolymers, and also products formed in the process, were studied in relation to temperature and relative content of mixture components.     

The vaporization of a metallic target by a microsecond pulsed TE-CO2 laser radiation

The analysis of some new experimental data has proved that the evaporation of a stainless steel target in vacuum under the action of powerful TE-CO₂ microsecond pulsed laser radiation is initiated on the initial spike or not at all. The minimum “tail” duration to get evaporation was deduced as a function of the temporal pulse shape characteristics and the metal thermophysical properties. The vaporisation process was accompanied by nonequilibrium heating of vapour clouds leading to the target surface shielding. Two self-regulated evolutions were recognised which were attributed to the intense vaporisation and the target evaporation by the UV plasma emitted radiation, respectively.     

Optical fibre-grating pulse compression

Numerical simulation is used to consider non-linear pulse propagation in fibres and subsequent pulse compression in a dispersive delay line. It is shown that for small initial pulse powers the conventional non-linear Schrödinger equation (NSE) is quite accurate to describe the process of pulse propagation in fibres. In this case initially symmetrical pulses undergo squaring and spectral broadening in fibres, and frequency chirp is linearized over most of the pulse, while shapes of the pulse, spectrum and frequency chirp remain symmetrical at the output of the fibre. There is a certain optimum fibre lengthZ _opt which is determined by the initial pulse parameters and fibre characteristics for pulse compression in the dispersive delay line. When the fibre lengthZ>Z _opt the optical wave breaking effect distorts the linearity of the frequency chirp and thus deteriorates the quality of the compressed pulse. The region of NSE approximation accuracy is determined. It is demonstrated that at increase of the initial pulse power (initial pulse width makes no difference) the NSE approximation becomes inaccurate. So the pulse dynamics in the fibre were described by the modified NSE derived in the higher-order approximation of the method of slowly varying amplitudes from Maxwell's equations. In this case the shock wave appears at the trailing edge of the pulse, which accelerates the wave breaking process. This results in a decrease of the optimum fibre length and deterioration of compressed pulse parameters, compared with the NSE case. Spectral windowing of the extreme Stokes components of the pulse spectrum permits significant improvement in the quality of the compressed pulse. The main features of the compression of pulses with asymmetrical initial shape are also considered.     

Elastic properties of ultrahard fullerites

The elastic properties of C₆₀ fullerite samples synthesized under pressure P=13.0 GPa at high temperatures were investigated using acoustic microscopy. The velocities of longitudinal (c _L=17–26 km/s) and transverse (c _T=7.2–9.6 km/s) elastic waves in the samples were measured. It was established that the longitudinal sound velocity of ultrahard fullerites is higher than that of any other known solid. The bulk modulus of these ultrahard samples is higher than that of diamond and reaches a value greater than 1 TPa. The high bulk modulus, the relatively large shear moduli, and the substantial Poisson ratio indicate that the structure of the ultrahard fullerites is fundamentally different from that of diamond. Zh. éksp. Teor. Fiz. 114, 1365–1374 (October 1998)     

A Laser Projection System for Displaying Dynamic Information

The possibility of reproducing computer and TV information on large screens is demonstrated. A good contrast in the image was attained with the use of different optical systems. A multichannel system making it possible to realize the transmission of a large body of information is considered.