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51.
52.
Solutions for the fully compressible Navier–Stokes equations are presented for the flow and temperature fields in a cubic cavity with large horizontal temperature differences. The ideal-gas approximation for air is assumed and viscosity is computed using Sutherland's law. The three-dimensional case forms an extension of previous studies performed on a two-dimensional square cavity. The influence of imposed boundary conditions in the third dimension is investigated as a numerical experiment. Comparison is made between convergence rates in case of periodic and free-slip boundary conditions. Results with no-slip boundary conditions are presented as well. The effect of the Rayleigh number is studied. 相似文献
53.
Guido F. Smits Maarten C. Krol Pieter N. Van Kampen Cornelis Altona 《Journal of Molecular Structure》1986,139(3-4):247-253
Contrary to expectation, the gauche conformer of 1,2-difluoroethane is more stable than the trans conformer in the gas phase. In order to understand the underlying causes of the “gauche effect”, a complete geometry relaxation was performed for the gauche and trans conformers of 1,2-difluoroethane with the 4-21G, 4-31G and 4-31G** basis sets. The 4-31G** optimized geometry of the gauche conformer compares well with the experimental values obtained from a number of electron-diffraction studies. A correction for the correlation energy, calculated by means of second-order Møller—Plesset perturbation theory with the 6-31G** basis set, proves to be essential to obtain a correct estimate of the energy difference between the gauche and trans conformers 1,2-difluoroethane. 相似文献
54.
Yves Van Ingelgem Els Tourwé Orlin Blajiev Rik Pintelon Annick Hubin 《Electroanalysis》2009,21(6):730-739
Electrochemical impedance spectroscopy (EIS) is a powerful technique to study electrochemical processes and to perform screening tasks. Recently an integrated measuring and modeling methodology for EIS based on a multisine excitation signal was developed. A key issue in this methodology is the data analysis, allowing us to rapidly quantify the reliability of the measured data. In this paper, a comparison is made between classical single‐sine and the proposed multisine measurements on the same system. The fitting of the impedance data obtained by single‐or multisine excitation and using different weighting factors is also discussed. In addition to the advantages reported in earlier work, it is concluded that, of all investigated frequencies, the odd random phase multisine excitation yields the highest quality data in the shortest measurement time. 相似文献
55.
Bisphenol A polycarbonate degrades due to sunlight, humidity and oxygen. In this study two possible techniques to stabilize the polymer were compared, i.e. blending of UV-absorbers (UVAs) into the polymer or using block copolymers based on resorcinol polyarylates. Combination of different analysis techniques shows that the protection by UVAs is not as good as by the resorcinol polyarylate block copolymers. The block copolymer rearranges itself through a photo-Fries rearrangement within hours into a UV-absorbing top layer. Two different block compositions were studied, and the copolymer with the highest concentration of resorcinol polyarylate groups shows the best protection. 相似文献
56.
57.
Lees JP Poireau V Tisserand V Garra Tico J Grauges E Martinelli M Milanes DA Palano A Pappagallo M Eigen G Stugu B Brown DN Kerth LT Kolomensky YG Lynch G Koch H Schroeder T Asgeirsson DJ Hearty C Mattison TS McKenna JA So RY Khan A Blinov VE Buzykaev AR Druzhinin VP Golubev VB Kravchenko EA Onuchin AP Serednyakov SI Skovpen YI Solodov EP Todyshev KY Yushkov AN Bondioli M Kirkby D Lankford AJ Mandelkern M Stoker DP Atmacan H Gary JW Liu F Long O Vitug GM Campagnari C Hong TM Kovalskyi D 《Physical review letters》2011,107(22):221803
We search for hadronic decays of a light Higgs boson (A(0)) produced in radiative decays of an Υ(2S) or Υ(3S) meson, Υ→γA(0). The data have been recorded by the BABAR experiment at the Υ(3S) and Υ(2S) center-of-mass energies and include (121.3±1.2)×10(6) Υ(3S) and (98.3±0.9)×10(6) Υ(2S) mesons. No significant signal is observed. We set 90% confidence level upper limits on the product branching fractions B(Υ(nS)→γA(0))B(A(0)→hadrons) (n=2 or 3) that range from 1×10(-6) for an A(0) mass of 0.3 GeV/c(2) to 8×10(-5) at 7 GeV/c(2). 相似文献
58.
Sheetal Saxena Alexander Summa Dominik Elsässer Michael Rüger Karl Mannheim 《The European Physical Journal C - Particles and Fields》2011,71(11):1815
As the largest mass concentrations in the local Universe, nearby clusters of galaxies and their central galaxies are prime
targets in searching for indirect signatures of dark matter annihilation (DMA). We seek to constrain the dark matter annihilation
emission component from multi-frequency observations of the central galaxy of the Virgo cluster. The annihilation emission
component is modeled by the prompt and inverse-Compton gamma rays from the hadronization of annihilation products from generic
weakly interacting dark matter particles. This component is fitted to the excess of the observed data above the spectral energy
distribution (SED) of the jet in M87, described with a best-fit synchrotron-self-Compton (SSC) spectrum. While this result
is not sufficiently significant to claim a detection, we emphasize that a dark matter “double hump signature” can be used
to unambiguously discriminate the dark matter emission component from the variable jet-related emission of M87 in future,
more extended observation campaigns. 相似文献
59.
Nonlinear Elastic Wave Spectroscopy (NEWS) relies on the activation of defects by wave energy that propagates through the medium. In general, the response of activated defects will not scale linearly with the excitation amplitude, and the resulting nonlinear signatures can be identified and used for quality inspection. The efficiency of NEWS based inspection methods is therefore intrinsically linked to the locally deposited activation energy at the defect zone and the ability to generate nonlinear signatures that exceed the noise level of acquisition. Time Reversal techniques allow focusing of high levels of energy in small areas, and are consequently very useful for the local activation of defected zones. In this report, numerical simulations are reported showing the potential of a combination consisting of dual energy reciprocal Time Reversal and nonlinearity filtering using the Scaling Subtraction Method. The method is applied to the detection of planar near-surface defects parallel to the surface in a 2D domain. The results are evaluated for sweep excitation at different frequency ranges; for point-like receiver as well as extended transducers, and for in-plane as well as out-of-plane focusing. The observable nonlinear response at the surface is linked to an effective nonlinearity within the medium based on the defect geometry and the distribution of the local stresses. 相似文献
60.
Pieter Samyn Jürgen Van ErpsHugo Thienpont Gustaaf Schoukens 《Applied Surface Science》2011,257(13):5613-5625
Papers have a complex hierarchical structure and the end-user functionalities such as hydrophobicity are controlled by a finishing layer. The application of an organic nanoparticle coating and drying of the aqueous dispersion results in an unique surface morphology with microscale domains that are internally patterned with nanoparticles. Better understanding of the multi-scale surface roughness patterns is obtained by monitoring the topography with non-contact profilometry (NCP) and atomic force microscopy (AFM) at different sampling areas ranging from 2000 μm × 2000 μm to 0.5 μm × 0.5 μm. The statistical roughness parameters are uniquely related to each other over the different measuring techniques and sampling sizes, as they are purely statistically determined. However, they cannot be directly extrapolated over the different sampling areas as they represent transitions at the nano-, micro-to-nano and microscale level. Therefore, the spatial roughness parameters including the correlation length and the specific frequency bandwidth should be taken into account for each measurement, which both allow for direct correlation of roughness data at different sampling sizes. 相似文献