Phase transformation in the system TlBi(Te1‐xSex)2

TlBiTe₂ and TlBiSe₂ ‐ that are ternary analogs of the IV‐VI semiconductors ‐, although they crystallize in the same space group R m (D⁵_3d), exhibit different behaviour during heating. The observed phase transformation depends on Se content (x) in the system TlBi(Te_1‐xSe_x)₂ and the transformation disappears by increasing Se content after a certain value (x = 0.25). This dependence is examined through the analysis of the DSC non‐isothermal measurements and an attempt for the explanation of the observed behaviour is undertaken through the consideration of off‐center atoms. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Ionizing radiation and its effects on pharmaceuticals

Journal of Radioanalytical and Nuclear Chemistry - In this work, a total of twenty samples selected for investigation originate from South Africa and Namibia uranium mines. The aim of this study...     

Liquid phase oxidation of benzyl alcohol to benzaldehyde over chromium borophosphate catalyst synthesized by solution combustion method using different types of fuel

In this paper, chromium borophosphates have been prepared by the solution combustion method using different types of fuel and enhanced as a catalyst for liquid-phase oxidation of benzyl alcohol to benzaldehyde for the first time. Carbohydrazide, citric acid, hexamethylenetetramine, oxalyldihydrazide and urea used as an organic fuel and the obtained chromium borophosphates were systematically characterized by infrared spectroscopy, X-ray powder diffraction, thermogravimetry, scanning electron microscopy, and surface analysis techniques. They are structurally identical and thermally stable up to 1000 °C. According to fuel, their surface properties differ from each other and the long and short rod-like particles, which have a surface area between 7 and 19 m² g^?1, are formed. The effects of solvent type, reaction temperature, reaction time, peroxide amount and catalyst amount were also examined for catalytic studies, and the reaction conditions were optimized. As compared with the other fuels, hexamethylenetetramine-assisted synthesized chromium borophosphate catalyst provides high benzaldehyde conversion (52.09%) and selectivity (100%) under the optimized condition and has potential as a heterogeneous catalyst for oxidation reactions.

     

Shock wave attenuation by grids and orifice plates

The interaction of weak shock waves with porous barriers of different geometries and porosities is examined. Installing a barrier inside the shock tube test section will cause the development of the following wave pattern upon a head-on collision between the incident shock wave and the barrier: a reflected shock from the barrier and a transmitted shock propagating towards the shock tube end wall. Once the transmitted shock wave reaches the end wall it is reflected back towards the barrier. This is the beginning of multiple reflections between the barrier and the end wall. This full cycle of shock reflections/interactions resulting from the incident shock wave collision with the barrier can be studied in a single shock tube test. A one-dimensional (1D), inviscid flow model was proposed for simulating the flow resulting from the initial collision of the incident shock wave with the barrier. Fairly good agreement is found between experimental findings and simulations based on a 1D flow model. Based on obtained numerical and experimental findings an optimal design procedure for shock wave attenuator is suggested. The suggested attenuator may ensure the safety of the shelter’s ventilation systems.     

Dynamics of stress wave propagation in a chain of photoelastic discs impacted by a planar shock wave; Part I, experimental investigation

The propagation of stress waves through a chain of discs has been studied experimentally. Optically transparent 20-mm diameter discs, made of epoxy, were loaded dynamically by head-on collision with an incident planar shock wave. The loading was done in a vertical shock tube. The head-on collision between the punch-plate, placed on top of the chain of discs, and the incident shock wave resulted in a head-on reflected shock wave inducing behind it a fairly uniform step-wise pressure pulse having duration of about 6 ms. The recorded fringe patterns of the stress field, in the discs-chain, show that the input pressure pulse was broken into several oscillating cycles. The back and forth bouncing of stress waves gave rise to two different modes of the contact stress oscillations, which continued until the overall stress reaches equilibrium with the input conditions. The registered propagation velocity of the stress wave was significantly lower than the appropriate speed of sound in the material from which the discs were made.      

A comparative analysis of Mindlin and Kirchhoff bending solutions for nonlinearly tapered annular plate with free edges

In this study, we consider the problem of nonlinearly tapered annular plate with a free edge. The supported edge may be simply supported, clamped or elastically restrained against rotation. Exact expressions of deflection, moment-resultants, and stresses are presented for nonuniform thickness. We compare the results of the Kirchhoff plate theory and the Mindlin plate theory. It is shown that the Kirchhoff plate theory and the Mindlin plate theory provide approximately the same results for the positive values of the thickness factor, but the difference between the deflections diverges as the thickness increases at the inner edge. We also propose that the Kirchhoff plate theory may be used in the region of −0.4 ≤ α < 1 and the Mindlin plate theory must be used for α < −0.4.     

Experimental and Theoretical Vibrational Spectra of Sideridiol Isolated from <Emphasis Type="Italic">Sideritis</Emphasis> Species

Sideridiol (ent-7α,18β-dihydroxykaur-15-ene) one of the ent-kaurene diterpenoid, is isolated from the genus Sideritis L. belongs to the family of Lamiaceae. The vibrational frequencies of sideridiol in the ground state have been calculated using the Density Functional Theory (DFT) method with the 6-31G(d) and 6 31+G(d,p) basis sets. The calculated vibrational frequencies have been compared with that of obtained experimental IR spectrum.     

Dynamics of stress wave propagation in a chain of photoelastic discs impacted by a planar shock wave: Part II, numerical investigation

The propagation of stress waves through a chain of discs has been studied experimentally in Part I (Glam et al. [1]) and is completed here with numerical investigation using the standard package ABAQUS. A fair agreement is found between experimental findings and their simulations. Based on this agreement, parametric study of wave propagation through disc-chains was conducted. Specifically, effects associated with changes in the disc diameter, material density, stiffness/rigidity and the number of discs in the chain on the stressed chain have been studied. It was found that the propagation velocity of the evolved waves increases with improving contacts between the chain’s discs by exposing the chain to a static load before its dynamic loading. The wave- propagation velocity decreases with increase in the discs material density and it increases when its diameter increases. In case of a chain composed of small diameter discs and/or small material density, the transmitted stress wave is first strengthened and only at discs further down the chain it starts decaying. When checking the influence of the dynamic-loading duration it was found that long dynamic-load duration dissolves quickly into short pulses. It was also found that there is a ‘characteristic’ wave for a given chain. This wave propagates with minimal dispersion. Dynamic loads having shorter time duration than the ‘characteristic’ one experiences significant attenuation.     

Shock wave interaction with cellular materials

The equations governing the head-on collision of a planar shock wave with a cellular material and a numerical scheme for solving the set of the governing equations were outlined. In addition, the condition for the transmitted compression waves to transform into a shock wave, inside the cellular material was introduced. It was proved analytically that a cellular material cannot be used as a means of reducing the pressure load acting on the end-wall of the shock tube. In subsequent papers, the interaction of planar shock waves with specific cellular materials, e.g., foams and honeycombs will be described in detail.This article was processed using Springer-Verlag T_EX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society.