Exergoeconomic analysis of a thermochemical copper–chlorine cycle for hydrogen production using specific exergy cost (SPECO) method

The manner is investigated in which exergy-related parameters can be used to minimize the cost of a copper–chlorine (Cu–Cl) thermochemical cycle for hydrogen production. The iterative optimization technique presented requires a minimum of available data and provides effective assistance in optimizing thermal systems, particularly in dealing with complex systems and/or cases where conventional optimization techniques cannot be applied. The principles of thermoeconomics, as embodied in the specific exergy cost (SPECO) method, are used here to determine changes in the design parameters of the cycle that improve the cost effectiveness of the overall system. The methodology provides a reasonable approach for improving the cost effectiveness of the Cu–Cl cycle, despite the fact that it is still in development. It is found that the cost rate of exergy destruction varies between $1 and $15 per kilogram of hydrogen and the exergoeconomic factor between 0.5 and 0.02 as the cost of hydrogen rises from $20 to $140 per GJ of hydrogen energy. The hydrogen cost is inversely related to the exergoeconomic factor, plant capacity and exergy efficiency. The results are expected to assist ongoing efforts to increase the economic viability and to reduce product costs of potential commercial versions of this process. The impact of the results are anticipated to be significant since thermochemical water splitting with a copper–chlorine cycle is a promising process that could be linked with nuclear reactors to produce hydrogen with no greenhouse gases emissions, and thereby help mitigate numerous energy and environment concerns.     

Cloud point extraction procedure for flame atomic absorption spectrometric determination of lead(II) in sediment and water samples

The conditions for cloud point extraction of lead(II) from aqueous solutions were investigated and optimized. The procedure is based on the separation of Pb(II) – brillant cresyl blue (BCB) complexes into the micellar media by adding the surfactant Triton X-114. After phase separation, the surfactant-rich phase was dissolved with 1 mol L⁻¹ HNO₃ in ethanol and diluted with 1 mol L⁻¹ HNO₃ solution before lead was determined by flame atomic absorption spectrometry. Optimization of the pH, ligand and surfactant quantities, incubation time, temperature, viscosity, sample volume, and interfering ions was performed. The effects of the matrix ions were also examined. The detection limits for three times the standard deviations of the blank for lead were 7.5 μg L⁻¹ for water samples and 0.33 μg g⁻¹ for sediment samples. The validity of cloud point extraction was checked by employing certified reference samples of Lake Sediment IAEA-SL-1 and Sewage Sludge BCR-CRM 144R. The procedure was applied to natural waters and sediment samples with satisfactory results (recoveries >95%, relative standard deviations <6.4%).     

Resonant non-linear waves—III. Elastic continuum with quadratic non-linearity

The paper derives the relevant non-linear integro-differential evolution equation by the method due to Collins expanding on a procedure by Keller. The quadratically non-linear case is not a trivial variation over the cubically non-linear case that was presented in preceding papers. As expected a different scaling and ordering of terms is needed and the first order perturbation solution provides no information on resonance. Nevertheless, although obtained by much longer calculations, the final equation for the present case is of identical form, with differences only in numerical coefficients, with the cubic case that was presented and solved earlier.     

Renal-related perinephric fluid collections: MRI findings

We retrospectively reviewed MR studies on 10 patients with renal-related perinephric fluid collections who underwent MRI in three institutions between January 2001 and August 2004. All patients underwent MRI of the abdomen and T1-weighted, T2-weighted and serial contrast-enhanced images, including delayed-phase contrast-enhanced images 10-12 min after contrast injection, were obtained. Perinephric fluid collections in 5 patients revealed MRI findings of simple fluid content (i.e., hypointense on T1-weighted images and hyperintense on T2-weighted images). In another 5 patients, a complex perinephric fluid content (i.e., mixed hyper/hypointense on T1-weighted images and mixed hypo/hyperintense on T2-weighted images compatible with blood breakdown products and pus) was observed. In 5 patients, contrast extravasation on late-phase images that was compatible with urine leak was demonstrated. Our results suggest that MRI may determine the content of perinephric fluid collections on noncontrast T1-weighted and T2-weighted images and that contrast extravasation on late-phase images is associated with urine extravasation from renal collecting systems.     

Cryogenic radiometer based absolute spectral power responsivity calibration of integrating sphere radiometer to be used in power measurements at optical fiber communication wavelengths

This paper covers the absolute spectral power responsivity calibration of spectralon-coated Integrating Sphere Radiometer (ISR) equipped with 3 mm diameter InGaAs photodiode to be used as a transfer standard in fiber optic power measurements against Electrical Substitution Cryogenic Radiometer (ESCR) in Optics Laboratory of National Metrology Institute (TUBITAK UME) of Turkey. The initial uncertainty arising from the use of the Electrically Calibrated Pyroelectric Radiometer (ECPR) as a transfer standard in radiometric scale is 0.5% (k=2), which particularly comes from irregularity in the surface homogeneity of ECPR. In order to eliminate the ECPR step as well as its initial uncertainty contribution in fiber optic power measurements, the calibration application herein was carried out. Moreover power stabilization measurements of DFB laser sources at both 1309.1 nm and 1549.0 nm, the beam size determinations, and spectral analyses of these laser sources as well as spatial and angular dependence of spectral responsivities of the ISR were presented in this paper. The total expanded uncertainties were calculated as 0.283% and 0.315% in the determination of absolute spectral power responsivities of the ISR for 1309.1 nm and 1549.0 nm wavelengths respectively (k=2).     

Characterization and determination of the thermodynamic and kinetic properties of p-CP adsorption onto organophilic bentonite from aqueous solution

The characterization of tetraethylammonium bentonite and the adsorption of p-chlorophenol (p-CP) onto organophilic bentonite (tetraethylammonium bentonite) was studied as a function of the solution concentration and temperature. The observed adsorption rates were found to fit first-order kinetics. The rate constants were calculated for temperatures ranging between 15.0 and 35.0 degrees C at constant concentration. The adsorption energy E and adsorption capacity q(m) for the phenolic compound adsorbing on organophilic bentonite were estimated using the Dubinin-Radushkevic equation. Thermodynamic parameters (Deltag(a), Deltah(a), Deltas(a)) were calculated by a new approximation from the isotherms of p-CP adsorption on organophilic bentonite. These isotherms were modeled according to Freundlich and Dubinin-Radushkevic adsorption isotherms. The amount of adsorption of p-chlorophenol on organophilic bentonite was found to be dependent on the relative energies of adsorbent-adsorbate, adsorbate-solvent, and adsorbate-adsorbate interactions.     

All-optical transistor action with bistable switching in a photonic crystal cross-waveguide geometry

We demonstrate all-optical switching action in a nonlinear photonic crystal cross-waveguide geometry with instantaneous Kerr nonlinearity, in which the transmission of a signal can be reversibly switched on and off by a control input. Our geometry accomplishes both spatial and spectral separation between the signal and the control in the nonlinear regime. The device occupies a small footprint of a few micrometers squared and requires only a few milliwatts of power at a 10-Gbit/s switching rate by use of Kerr nonlinearity in AlGaAs below half the electronic bandgap. We also show that the switching dynamics, as revealed by both coupled-mode theory and finite-difference time domain simulations, exhibits collective behavior that can be exploited to generate high-contrast logic levels and all-optical memory.     

Simulation of spray combustion in a lean-direct injection combustor

Large-eddy simulation (LES) of a liquid-fueled lean-direct injection (LDI) combustor is carried out by resolving the entire inlet flow path through the swirl vanes and the combustor. A localized dynamic subgrid closure is combined with a subgrid mixing and combustion model so that no adjustable parameters are required for both non-reacting and reacting LES. Time-averaged velocity predictions compare well with the measured data. The unsteady flow features that play a major role in spray dispersion, fuel–air mixing and flame stabilization are identified from the simulation data. It is shown that the vortex breakdown bubble (VBB) is smaller with more intense reverse flow when there is heat release. The swirling shear layer plays a major role in spray dispersion and the VBB provides an efficient flameholding mechanism to stabilize the flame.