Enantioselective Alternating Copolymerization of Propylene with Carbon Monoxide Using Cationic Palladium-Chiral Diphosphine Catalyst

Alternating copolymerization of (-olefins with carbon monoxide (CO) catalyzed by cationic palladium-chiral ligand complexes is of great interest due to the potential use of the resulting polymer as a new material1. Recently, enantioselective alternating copolymerization of CO with styrene has been reported by us using PdCl_2-CuCl2-chiral phosphine catalyst2. Here, we first report enantioselective alternating copolymerization of CO with propylene (P) using [(DDPPI)Pd(CH3CN)4](BF4)2 as …     

有限温度下Na4团簇的异构化

在紧密结合分子动力学模型基础上,对Ｎａ４的两种异构体Ｄ２ｈ和Ｃ２Ｖ和结构性质随温度的进行了系统性研究。发现在低温时,这两划构体具有明显有不同;在较高温度时,能够发现Ｃ２Ｖ和Ｄ２ｈ两种异构体之间的转变;在更高温度时,这两种异构体Ｃ２ｖ和Ｄ２ｈ都处于液态。     

壳聚糖希夫碱铜多相催化剂催化苯乙烯环丙烷化反应研究

壳聚糖希夫碱铜催化剂催化苯乙烯环丙烷化反应，得到了非常好的化学收率，同时还得到了17.1%ee和33.3:66.7的顺反比。此外，催化剂重复使用数次仍保持很高的活性。     

经典锥壳理论的新发展

本文在评述前人有关锥壳理论研究的基础上,介绍了我国学者近年来的一系列研究成果.