全文获取类型
收费全文 | 99090篇 |
免费 | 5416篇 |
国内免费 | 4628篇 |
专业分类
化学 | 56268篇 |
晶体学 | 1331篇 |
力学 | 5582篇 |
综合类 | 322篇 |
数学 | 11832篇 |
物理学 | 33799篇 |
出版年
2023年 | 749篇 |
2022年 | 1709篇 |
2021年 | 2115篇 |
2020年 | 2310篇 |
2019年 | 2507篇 |
2018年 | 2892篇 |
2017年 | 2823篇 |
2016年 | 3486篇 |
2015年 | 2409篇 |
2014年 | 3477篇 |
2013年 | 4919篇 |
2012年 | 5055篇 |
2011年 | 5354篇 |
2010年 | 4249篇 |
2009年 | 4255篇 |
2008年 | 4453篇 |
2007年 | 4173篇 |
2006年 | 3804篇 |
2005年 | 3375篇 |
2004年 | 3036篇 |
2003年 | 2711篇 |
2002年 | 2828篇 |
2001年 | 2547篇 |
2000年 | 1987篇 |
1999年 | 1601篇 |
1998年 | 1534篇 |
1997年 | 1329篇 |
1996年 | 1295篇 |
1995年 | 1079篇 |
1994年 | 1159篇 |
1993年 | 1097篇 |
1992年 | 1063篇 |
1991年 | 1125篇 |
1990年 | 1118篇 |
1989年 | 1039篇 |
1988年 | 917篇 |
1987年 | 914篇 |
1986年 | 881篇 |
1985年 | 921篇 |
1984年 | 915篇 |
1983年 | 822篇 |
1982年 | 800篇 |
1979年 | 801篇 |
1978年 | 812篇 |
1977年 | 806篇 |
1976年 | 919篇 |
1975年 | 812篇 |
1974年 | 844篇 |
1973年 | 847篇 |
1972年 | 752篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
2.
The γcmc values of CTAB-SDS decrease from 63.67 mN/m at 10‡C to 36.38 mN/m at 90‡C, slightly lower than those of either CTAB or SDS.
Correspondingly, the CMC of CTAB-SDS decreases almost by half. The increase of surface activity of CTAB-SDS can be attributed
to the relatively weak electrostatic interaction at high temperature, which is supported by the increase of solubility of
CTAB-SDS with rise in temperature. Catalytic effect on oxidation of toluene derivatives with potassium permanganate follows
the order CTAB-SDS > SDS > CTAB. This is not caused by the dissociative effect of CTAB-SDS with low surface activity at low
temperature, as seen from the fact that almost all oxidative products can be retrieved for different toluene derivatives and
surfactants by mimicking the conditions of reaction. In the emulsifications of toluene derivatives at 90‡C, the time that
turbid water layers of surfactant solutions take to become clear is the same as that of the catalytic effect on oxidation
of toluene derivatives. Thus, it can be inferred that surfactants can improve the oxidation yields of toluene derivatives
by increasing the contact between two reacting phases. 相似文献
3.
The excitation of eigen surface waves by tubular electron beams in cylindrical discharge devices is studied. The influence of the wave‐field azimuthal structure on the excitation efficiency and nonlinear stage of the plasmabeam instability is investigated both numerically and analytically. Analytical expressions for the saturation amplitude and excitation efficiency of the wave under study are derived. They are found to agree well with results obtained by numerical modelling of the plasma‐beam interaction presented in this paper. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
4.
Xingxing Yu 《Journal of Graph Theory》2006,51(3):175-198
An infinite graph is 2‐indivisible if the deletion of any finite set of vertices from the graph results in exactly one infinite component. Let G be a 4‐connected, 2‐indivisible, infinite, plane graph. It is known that G contains a spanning 1‐way infinite path. In this paper, we prove a stronger result by showing that, for any vertex x and any edge e on a facial cycle of G, there is a spanning 1‐way infinite path in G from x and through e. Results will be used in two forthcoming papers to establish a conjecture of Nash‐Williams. © 2005 Wiley Periodicals, Inc. J Graph Theory 相似文献
5.
Yu. M. Dyukarev 《Mathematical Notes》2004,75(1-2):66-82
In this paper, we obtain criteria for the indeterminacy of the Stieltjes matrix moment problem. We obtain explicit formulas for Stieltjes parameters and study the multiplicative structure of the resolvent matrix. In the indeterminate case, we study the analytic properties of the resolvent matrix of the moment problem. We describe the set of all matrix functions associated with the indeterminate Stieltjes moment problem in terms of linear fractional transformations over Stieltjes pairs. 相似文献
6.
Yu. P. Kalmykov 《Radiophysics and Quantum Electronics》1989,32(9):826-835
Radio Engineering and Electronics Institute, Academy of Sciences of the USSR. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 32, No. 9, pp. 1113–1124, September, 1989. 相似文献
7.
A lithium(I) coordination polymer has been formed from LiClO4 and the 2,2′‐bipyrimidine (bpym) ligand in which each square pyramidal lithium(I) atom is coordinated in the basal plane by four nitrogen donor atoms derived from two bpym ligands and one water molecule at the apical position. These are connected into a layer structure via hydrogen‐bonding interactions involving the perchlorate anions. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
8.
Some possible errors in determining the gravity anomalies are discussed. Such errors may be caused by an inaccurate calibration of the gravimeter used in an airborne survey system. An approach based on wavelet decompositions is proposed for its additional calibration with the use of flight data obtained during repeated flights. 相似文献
9.
The aim of this study is to construct a quantitative characteristic for the degree of gaze stabilization on a visual target with consideration of physiological constraints. A quality criterion for visual tracking during optokinetic vestibulocervical nystagmus is proposed. The index of imaginary tracking during rotation in the dark allows one to speak of a difference in the image stabilization quality between a healthy person and a patient. Experimental nystagmus data are used to calculate the quality index of visual tracking and the index of imaginary tracking. 相似文献
10.
A. V. Ivanov M. Yu. Tsentalovich E. G. Kogan L. G. Tomilova N. S. Zefirov 《Russian Chemical Bulletin》2008,57(8):1676-1679
The chlorination of benzene, toluene, and o-xylene with molecular chlorine in the presence of the phthalocyanine complexes of different structures was studied. The transformations
of the catalysts during the reaction were investigated.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1644–1647, August, 2008. 相似文献