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991.
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Romain Bénéteau Anne Boussonnière Jean‐Christophe Rouaud Prof. Dr. Jacques Lebreton Dr. Jérôme Graton Prof. Dr. Denis Jacquemin Dr. Muriel Sebban Prof. Dr. Hassan Oulyadi Ghanem Hamdoun Dr. Amber N. Hancock Prof. Dr. Carl H. Schiesser Dr. Fabrice Dénès 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(14):4809-4824
α‐Bromo aluminium acetals are suitable substrates for Ueno–Stork‐like radical cyclisations affording γ‐lactols and acid‐sensitive methylene‐γ‐lactols in high yields. The mechanistic study herein sets the scope and limitation of this reaction. The influence of the halide (or chalcogenide) atom X (X=Cl, Br, I, SPh, SePh) in the precursors α‐haloesters, as well as influence of the solvent and temperature was studied. The structure of the aluminium acetal intermediates resulting from the reduction of the corresponding α‐haloesters has been investigated by low‐temperature 13C‐INEPT diffusion‐ordered NMR spectroscopy (DOSY) experiments and quantum calculations, providing new insights into the structures of these thermally labile intermediates. Oxygen‐bridged dimeric structures with a planar Al2O2 ring are proposed for the least hindered aluminium acetals, while monomeric structures seem to prevail for the most hindered species. A comparison against the radical cyclisation of aluminium acetals derived from allyl and propargyl alcohols with the parent Ueno–Stork has been made at the BHandHLYP/6‐311++G(d,p) level of theory, highlighting mechanistic similarities and differences. 相似文献
995.
Dr. Julie Martin Dr. Mohammad Wehbi Dr. Cécile Echalier Dr. Sylvie Hunger Dr. Audrey Bethry Prof. Xavier Garric Dr. Coline Pinese Prof. Jean Martinez Dr. Lubomir Vezenkov Prof. Gilles Subra Prof. Ahmad Mehdi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(56):12839-12845
A simple and efficient way to synthesize peptide-containing silicone materials is described. Silicone oils containing a chosen ratio of bioactive peptide sequences were prepared by acid-catalyzed copolymerization of dichlorodimethylsilane, hybrid dichloromethyl peptidosilane, and Si(vinyl)- or SiH-functionalized monomers. Functionalized silicone oils were first obtained and then, after hydrosilylation cross-linking, bioactive polydimethylsiloxane (PDMS)-based materials were straightforwardly obtained. The introduction of an antibacterial peptide yielded PDMS materials showing activity against Staphylococcus aureus. PDMS containing RGD ligands showed improved cell-adhesion properties. This generic method was fully compatible with the stability of peptides and thus opened the way to the synthesis of a wide range of biologically active silicones. 相似文献
996.
997.
Iron complexes as photoinitiators for radical and cationic polymerization through photoredox catalysis processes 下载免费PDF全文
Jing Zhang Damien Campolo Frederic Dumur Pu Xiao Jean Pierre Fouassier Didier Gigmes Jacques Lalevée 《Journal of polymer science. Part A, Polymer chemistry》2015,53(1):42-49
Six iron complexes (FeCs) with various ligands have been designed and synthesized. In combination with additives (e.g., iodonium salt, N‐vinylcarbazole, amine, or chloro triazine), the FeC‐based systems are able to efficiently generate radicals, cations, and radical cations on a near UV or visible light‐emitting diode (LED) exposure. These systems are characterized by an unprecedented reactivity, that is, for very low content 0.02% FeC‐based systems is still highly efficient in photopolymerization contrary to the most famous reference systems (Bisacylphosphine oxide) illustrating the performance of the proposed catalytic approach. This work paves the way for polymerization in soft conditions (e.g., on LED irradiation). These FeC‐based systems exhibit photocatalytic properties, undergo the formation of radicals, radical cations, and cations and can operate through oxidation or/and reduction cycles. The photochemical mechanisms for the formation of the initiating species are studied using steady state photolysis, cyclic voltammetry, electron spin resonance spin trapping, and laser flash photolysis techniques. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 42–49 相似文献
998.
For a given multifunction, we provide proximal differentiability condition under which the equivalence between the interior sphere condition of each value of the multifunction and the interior sphere condition of its graph holds. 相似文献
999.
Naphthalic anhydride derivatives: Structural effects on their initiating abilities in radical and/or cationic photopolymerizations under visible light 下载免费PDF全文
Pu Xiao Frédéric Dumur Jing Zhang Bernadette Graff Fabrice Morlet‐Savary Jean Pierre Fouassier Didier Gigmes Jacques Lalevée 《Journal of polymer science. Part A, Polymer chemistry》2015,53(24):2860-2866
Only one naphthalic anhydride derivative has been reported as light sensitive photoinitiator, this prompted us to further explore the possibility to prepare a new family of photoinitiators based on this scaffold. Therefore, eight naphthalic Naphthalic anhydride derivatives (ANH1‐ANH8) have been prepared and combined with an iodonium salt (and optionally N‐vinylcarbazole) or an amine (and optionally 2,4,6‐tris(trichloromethyl)‐1,3,5‐triazine) to initiate the cationic polymerization of epoxides and the free radical polymerization of acrylates under different irradiation sources, that is, very soft halogen lamp (~ 12 mW cm?2), laser diode at 405 nm (~1.5 mW cm?2) or blue LED centered at 455 nm (80 mW cm?2). The ANH6 based photoinitiating systems are particularly efficient for the cationic and the radical photopolymerizations, and even better than that of the well‐known camphorquinone based systems. The photochemical mechanisms associated with the chemical structure/photopolymerization efficiency relationships are studied by steady state photolysis, fluorescence, cyclic voltammetry, laser flash photolysis, and electron spin resonance spin‐trapping techniques. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2860–2866 相似文献
1000.
Pier Alexandre Champagne Yasmine Benhassine Justine Desroches Jean‐Franois Paquin 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(50):14055-14059
A Friedel–Crafts benzylation of arenes with benzyl fluorides has been developed. The reaction produces 1,1‐diaryl alkanes in good yield under mild conditions without the need for a transition metal or a strong Lewis acid. A mechanism involving activation of the C F bond through hydrogen bonding is proposed. This mode of activation enables the selective reaction of benzylic C F bonds in the presence of other benzylic leaving groups. 相似文献