全文获取类型
收费全文 | 168篇 |
免费 | 5篇 |
专业分类
化学 | 121篇 |
力学 | 10篇 |
数学 | 20篇 |
物理学 | 22篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2021年 | 11篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 10篇 |
2015年 | 7篇 |
2014年 | 4篇 |
2013年 | 9篇 |
2012年 | 10篇 |
2011年 | 10篇 |
2010年 | 5篇 |
2009年 | 6篇 |
2008年 | 3篇 |
2007年 | 3篇 |
2006年 | 5篇 |
2005年 | 4篇 |
2004年 | 6篇 |
2003年 | 1篇 |
2002年 | 1篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有173条查询结果,搜索用时 329 毫秒
91.
92.
Jacopo Dosso Tommaso Battisti Dr. Benjamin D. Ward Dr. Nicola Demitri Dr. Colan E. Hughes Dr. P. Andrew Williams Prof. Dr. Kenneth D. M. Harris Prof. Dr. Davide Bonifazi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6608-6621
In this work, a comprehensive account of the authors’ synthetic efforts to prepare borazino-doped hexabenzocoronenes by using the Friedel–Crafts-type electrophilic aromatic substitution is reported. Hexafluoro-functionalized aryl borazines, bearing an ortho fluoride leaving group on each of the N- and B-aryl rings, was shown to lead to cascade-type electrophilic aromatic substitution events in the stepwise C−C bond formation, giving higher yields of borazinocoronenes than those obtained with borazine precursors bearing fluoride leaving groups at the ortho positions of the B-aryl substituents. By using this pathway, an unprecedented boroxadizine-doped PAH featuring a gulf-type periphery could be isolated, and its structure proven by single-crystal X-ray diffraction analysis. Mechanistic studies on the stepwise Friedel–Crafts-type cyclization suggest that the mechanism of the planarization reaction proceeds through extension of the π system. To appraise the doping effect of the boroxadizine unit on the optoelectronic properties of topology-equivalent molecular graphenes, the all-carbon and pyrylium PAH analogues, all featuring a gulf-type periphery, were also prepared. As already shown for the borazino-doped hexabenzocoronene, the replacement of the central benzene ring by its B3N2O congener widens the HOMO–LUMO gap and dramatically enhances the fluorescence quantum yield. 相似文献
93.
Ab initio SCF MO LCAO calculations with the 4-31G basis set on the ten most stable complexes involving H2O, HF, HC1, F– and Cl– have been examined in order to verify whether there is some evidence supporting the hypothesis that water can act as a catalyst for some nucleophilic substitution reactions performed in inert solvents with hydrogen halides as nucleophile agents (e.g. the formation of halohydrins from epoxides). Energetic considerations and an analysis of the electrostatic contribution to the reactivity of the H2O-HX adduct seem to support this hypothesis. 相似文献
94.
Two possible pathways have been investigated for the cis—trans conversion in diimide N-oxide, viz. a rotation around the NN bond and an in-plane inversion. Calculations have been performed for the ground and lowest excited states by means of a Cl treatment including the configurations found to be the most important in large Cl calculations performed in a few points. It is shown that the rotational mechanism is favoured in the excited states and is probable also in the thermal reaction. Such investigation has been repeated in parallel by using other techniques of lower accuracy: (1) Cl limited to single excitations (EHP method); (2) rigid excitation to virtual orbitals; (3) the half electron methods. Deficiencies of such methods have been brought out and analyzed. In particular methods (2) and (3) lead to an erroneus interpretation of the actual mechanism of the photochemical conversion by rotation. 相似文献
95.
Dr. Amol P. Amrute Jacopo De Bellis Dr. Michael Felderhoff Prof. Dr. Ferdi Schüth 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(23):6819-6847
The mechanochemical synthesis of nanomaterials for catalytic applications is a growing research field due to its simplicity, scalability, and eco-friendliness. Besides, it provides materials with distinct features, such as nanocrystallinity, high defect concentration, and close interaction of the components in a system, which are, in most cases, unattainable by conventional routes. Consequently, this research field has recently become highly popular, particularly for the preparation of catalytic materials for various applications, ranging from chemical production over energy conversion catalysis to environmental protection. In this Review, recent studies on mechanochemistry for the synthesis of catalytic materials are discussed. Emphasis is placed on the straightforwardness of the mechanochemical route—in contrast to more conventional synthesis—in fabricating the materials, which otherwise often require harsh conditions. Distinct material properties achieved by mechanochemistry are related to their improved catalytic performance. 相似文献
96.
Patrizia N. Hanieh Jacopo Forte Chiara Di Meo Maria Grazia Ammendolia Elena Del Favero Laura Cant Federica Rinaldi Carlotta Marianecci Maria Carafa 《Molecules (Basel, Switzerland)》2021,26(11)
Hyaluronic acid (HA) is one of the most used biopolymers in the development of drug delivery systems, due to its biocompatibility, biodegradability, non-immunogenicity and intrinsic-targeting properties. HA specifically binds to CD44; this property combined to the EPR effect could provide an option for reinforced active tumor targeting by nanocarriers, improving drug uptake by the cancer cells via the HA-CD44 receptor-mediated endocytosis pathway. Moreover, HA can be easily chemically modified to tailor its physico-chemical properties in view of specific applications. The derivatization with cholesterol confers to HA an amphiphilic character, and then the ability of anchoring to niosomes. HA-Chol was then used to coat Span® or Tween® niosomes providing them with an intrinsic targeting shell. The nanocarrier physico-chemical properties were analyzed in terms of hydrodynamic diameter, ζ-potential, and bilayer structural features to evaluate the difference between naked and HA-coated niosomes. Niosomes stability was evaluated over time and in bovine serum. Moreover, interaction properties of HA-coated nanovesicles with model membranes, namely liposomes, were studied, to obtain insights on their interaction behavior with biological membranes in future experiments. The obtained coated systems showed good chemical physical features and represent a good opportunity to carry out active targeting strategies. 相似文献
97.
Scholes GD Curutchet C Mennucci B Cammi R Tomasi J 《The journal of physical chemistry. B》2007,111(25):6978-6982
The way that solvent (or host medium) modifies the rate of electronic energy transfer (EET) has eluded researchers for decades. By applying quantum chemical methods that account for the way solvent (in general any host medium including liquid, solid, or protein, etc.) responds to the interaction between transition densities, we quantify the solvent screening. We find that it attains a striking exponential attenuation at separations less than about 20 A, thus interpolating between the limits of no apparent screening and a significant attenuation of the EET rate. That observation reveals a previously unidentified contribution to the distance dependence of the EET rate. 相似文献
98.
99.
Christian Silvio Pomelli Jacopo Tomasi Maurizio Cossi Vincenzo Barone 《Journal of computational chemistry》1999,20(16):1693-1701
A new computational strategy for the building of molecular cavities (named DefPol) has been linked to the most recent implementation of the polarizable continuum model (PCM) for the representation of solvent effects on physicochemical properties of large molecules. Free energies, analytical gradients, and Hessians can be computed in this framework in the rigid cavity approximation. Coupling DefPol cavities with a number of other recent improvements of the standard algorithm (e.g., effective use of symmetry, iterative procedures with linear scaling) significantly enlarges the dimensions of systems amenable to refined computations and strongly reduces the gap between computations for isolated molecules and in solution. © 1999 John Wiley & Sons, Inc. J Comput Chem 20: 1693–1701, 1999 相似文献
100.