Self-assembled tin-based bridged hybrid materials

Hybrid materials where layers of tin oxide alternate with layers of hydrophobic organic chains were prepared by the hydrolysis of distannylated compounds containing an organic chain alpha,omega-disubstituted by tripropynylstannyl groups. In the case of an aliphatic chain, hydrolysis under microemulsion conditions led to the organization of the corresponding hybrid. These hydrolysis conditions also induced a high surface area and a defined mesoporosity in the hybrid. When a mixed aromatic-aliphatic spacer was used, weak hydrophobic interactions between the spacers were sufficient to generate the same type of organization in the corresponding material.     

Mg2Ru2Cl10O·16H2O

Mg₂Ru₂Cl₁₀O·16H₂O {dimagnesium μ‐oxo‐bis­[penta­chloro­ruthenate(IV)] hexa­deca­hydrate} crystallizes in the monoclinic system (space group P2₁/c). The structure consists of layers of [Ru₂Cl₁₀O]⁴⁻ anions, [Mg(H₂O)₆]²⁺ cations and water mol­ecules stacked along the a axis. Only the O atom bonded to Ru occupies the 2a site with symmetry. All the other atoms occupy general 4e sites. The crystal structure is stabilized by O—H⋯O and O—H⋯Cl inter­actions.     

Solid-liquid equilibria of three binary systems: {1-Ethyl-3-methylimidazolium hexafluorophosphate + 2-phenylimidazole, or 4,5-diphenylimidazole or 2,4,5-triphenylimidazole}

The phase diagrams of binary mixtures formed by 1-ethyl-3-methylimidazolium hexafluorophosphate ([emim][PF₆]) and 2-phenylimidazole or 4,5-diphenylimidazole or 2,4,5-triphenylimidazole has been established using differential scanning calorimetry. Solutions containing 2,4,5-triphenylimidazole display phase splitting at high temperature range.     

A fracture criterion of rubber-like materials under plane stress conditions

In this work, we attempt to derive a fracture criterion for filled and unfilled elastomer vulcanizates and thermoplastics from a set of experimental data. Firstly, fracture criteria reported in the literature have been applied to experimental data obtained from tests including various loading modes (simple tension, equal biaxial tension and biaxial tension) and performed on four materials: a natural rubber (NR), a styrene butadiene rubber (SBR), a polyurethane (PU) and a thermoplastic elastomer (TPE).

Then, a new failure criterion based on an equivalent elongation concept is proposed. This equivalent elongation seems to be linearly dependent on a given biaxiality ratio n=(ln(λ_2b)/ln(λ_1b)), which leads to expressing the principal elongations at break as functions of both the biaxiality n and two experimental parameters. Quite good agreement is highlighted when comparing the failure experimental data with the proposed criterion for the tested elastomers.     

Mechanical properties of polyamide-12 layered silicate nanocomposites and their relations with structure

The mechanical properties of polyamide-12/Cloisite 30B (PA12/C30B) nanocomposites prepared by melt compounding were studied as a function of clay volume fraction φ under various processing conditions. All measured mechanical characteristics, Young's modulus, yield stress, strain at break and stress at break, exhibit a transition at φ_p1%, identified with a percolation threshold. Also, the linear and non-linear mechanical properties appeared to depend on the degree of exfoliation of the structure, which can be tuned by the processing conditions. The three-phase Ji's theoretical model was used to predict Young's modulus as a function of clay concentration, focusing on the influence of the degree of exfoliation. Experimental yield stress data were fitted to Pukanszky's model and discussed in terms of PA12/C30B interfacial adhesion.     

Thermal diagnostics of highly heated surfaces using water-spray cooling

Spray cooling of heated surfaces is common in many industrial applications, notably steelmaking, because of its high heat dissipating ability. Control of the surface heat flux rate contributes to better products; it is shown that the heat transfer rate depends on the mass fraction of liquid. Quantitative information regarding the parameters affecting spray cooling is relatively scarce. The rate of heat transfer from a plate due to impinging of an array of water jets was investigated numerically through the solution of heat conduction equation. The simulation is carried out for eight different sprayers, in the range of ejected fluid pressure between 1 bar and 3 bars. Experimental data are used to study the influence of the function g(x, y), of dispersed water, on heat transfer variations across the surface at the temperature of 600°C. Curves were generated showing time histories of the steel temperature for the removal of high heat fluxes of the order of 300 W/cm². It was also observed that for lower temperatures, the predicted local heat transfer coefficient increased significantly. In memory of H. Mzad’s father Mebrouk.