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991.
The boxicity of a graph G = (V, E) is the least integer k for which there exist k interval graphs G i = (V, E i ), 1 ≤ i ≤ k, such that ${E = E_1 \cap \cdots \cap E_k}$ . Scheinerman proved in 1984 that outerplanar graphs have boxicity at most two and Thomassen proved in 1986 that planar graphs have boxicity at most three. In this note we prove that the boxicity of toroidal graphs is at most 7, and that the boxicity of graphs embeddable in a surface Σ of genus g is at most 5g + 3. This result yields improved bounds on the dimension of the adjacency poset of graphs on surfaces. 相似文献
992.
Vít Jelínek Eva Jelínková Jan Kratochvíl Bernard Lidický Marek Tesař Tomáš Vyskočil 《Graphs and Combinatorics》2013,29(4):981-1005
It is known that every planar graph has a planar embedding where edges are represented by non-crossing straight-line segments. We study the planar slope number, i.e., the minimum number of distinct edge-slopes in such a drawing of a planar graph with maximum degree Δ. We show that the planar slope number of every planar partial 3-tree and also every plane partial 3-tree is at most O(Δ 5). In particular, we answer the question of Dujmovi? et al. (Comput Geom 38(3):194–212, 2007) whether there is a function f such that plane maximal outerplanar graphs can be drawn using at most f(Δ) slopes. 相似文献
993.
994.
This paper reports the feasibility of nano-oxide precipitate formation in Fe–Cr alloy by ion implantation synthesis. High contents of Al+ and O+ ions were implanted into thin films of high purity Fe–10%Cr alloy at room temperature and were studied by transmission electron microscopy (TEM) and atom probe tomography (APT). In contrast, to the common two-stage implantation/annealing scheme of precipitate ensemble synthesis by ion beams, cluster formation took place at the implantation stage in our study, requiring no subsequent high-temperature annealing. The post-implantation microstructural examination revealed in the as-implanted thin foil an array of precipitates with diameters in the range of 3–30?nm. The precipitate number density distribution was found to depend on the foil thickness. The precipitate enrichment with both Al and O was confirmed by the energy-filtered TEM analysis. Judging from the electron diffraction pattern and high-resolution TEM analysis, the crystal lattice of precipitates corresponds to some cubic modification of aluminium-rich oxide or pure aluminium oxide. The precipitate lattice alignment with the host matrix was revealed for at least a part of precipitates. The analysis of APT data using cluster detection algorithm indicates the presence of local zones enriched in Al and O, even in those areas of as-implanted samples where no clusters were visible by TEM. 相似文献
995.
Ali Osman Ayaş Mustafa Akyol Selda Kılıç Çetin Melike Kaya İlker Dinçer Ahmet Ekicibil 《哲学杂志》2013,93(9):671-682
AbstractIn this work, we have studied on double-layered perovskite (Ruddlesden–Popper) manganite structure in Pr1.75Sr1.25Mn2O7 synthesised by sol–gel method. The crystal structure of the double-layered perovskite is found as tetragonal from the X-ray diffraction analysis with I4/mmm space group. A high Curie temperature, TC = 305 K is observed from the temperature dependence of magnetisation measurement. The isothermal magnetisation curves showed that magnetic phase transition is second order due to the positive slope of the Arrott plots. Maximum magnetic entropy change (ΔSM) and adiabatic temperature change (ΔTad) values are calculated as 3.99 J kg?1 K?1 and 2.1 K under external magnetic field of 70 kOe, respectively. Since our double-layered perovskite manganite sample has desired TC value and relatively high ΔSM, it can be a potential candidate as a magnetocaloric material for room temperature magnetic cooling systems. 相似文献
996.
The temperature dependence of capacitance–voltage (C–V) and conductance–voltage (G/w–V) characteristics of Al/HfO2/p-Si metal-oxide-semiconductor (MOS) device has been investigated by considering the effect of series resistance (Rs) and interface state density (Nss) over the temperature range of 300–400 K. The C–V and G/w–V characteristics confirm that the Nss and Rs of the diode are important parameters that strongly influence the electric parameters in MOS device. It is found that in the presence of series resistance, the forward bias C–V plots exhibits a peak, and its position shifts towards lower voltages with increasing temperature. The density of Nss, depending on the temperature, was determined from the (C–V) and (G/w–V) data using the Hill–Coleman Method. Also, the temperature dependence of dielectric properties at different fixed frequencies over the temperature range of 300–400 K was investigated. In addition, the electric modulus formalisms were employed to understand the relaxation mechanism of the Al/HfO2/p-Si structure. 相似文献
997.
Shivaji S. Kadam Lukáš Maier Tomáš Šolomek Marek Nečas Karel Šmejkal Jiří Dostál Vladimír Sklenář Radek Marek 《Journal of Physical Organic Chemistry》2013,26(10):814-821
We report a preparation of new 6‐substituted‐5,6‐dihydrobenzo[c]phenanthridines by the reaction of azoles with quaternary benzo[c]phenanthridine alkaloids sanguinarine and chelerythrine. The prepared compounds have been characterized by NMR spectroscopy, mass spectrometry, and single‐crystal X‐ray diffraction. Conformational behaviors of carbazole derivatives in solution have been investigated by low‐temperature NMR experiments. Barriers to rotation around newly formed C6–N bonds were determined to be 12–13 kcal/mol. Quantum chemical calculations have been used to reproduce the experimental observations. Large structural effects on several 1H NMR resonances were observed experimentally, analyzed by Density Functional Theory (DFT) calculations at B3LYP/6‐311+G(d,p)/PCM level, and interpreted by ring‐current effects of the benzo[c]phenanthridine and carbazole units. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
998.
Janne Weisell Jouko Vepsäläinen Mikael Peräkylä 《Journal of Physical Organic Chemistry》2013,26(4):360-366
Correct net charge and protonation pattern in the polyamine backbone is one of the major factors that define the interactions of this class of compounds. 1,12‐diamino‐3,6,9‐triazadodecane (SpmTrien) is a isosteric charge deficient analogue of naturally occurring spermine (Spm) with different biological features. The tautomeric populations of each SpmTrien charge state were estimated with computer simulations, molecular dynamics (MD) and quantum mechanical calculations, and cluster expansions separately. In the computer simulations, tautomeric populations of each charge state were obtained by constrained least‐squares fitting the theoretically calculated (GIAO B3LYP/6‐311 + G**) 15 N NMR chemical shieldings of SpmTrien tautomers to the experimentally measured chemical shifts. Theoretical chemical shieldings were calculated for water complexes of SpmTrien obtained from MD simulations in explicit water. Both methods gave highly similar realistic results. SpmTrien has many major populations of tautomers at biologically relevant charge states of three (+3) and four (+4) thus enabling a large variety of structures for specific ionic interactions. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
999.
Diana B. Muñiz-Márquez Guillermo C. Martínez-Ávila Jorge E. Wong-Paz Ruth Belmares-Cerda Raúl Rodríguez-Herrera Cristóbal N. Aguilar 《Ultrasonics sonochemistry》2013,20(5):1149-1154
Bay leaves (BL) (Laurus nobilis L., Family: Laureceae) are traditionally used to treat some symptoms of gastrointestinal problems, such as epigastric bloating, impaired digestion, eructing and flatulence. These biological properties are mainly attributed to its phenolic compounds. In this paper, ultrasound-assisted extraction of phenolic compounds from Laurus nobilis L. (Laureceae) was studied.Effects of several experimental factors, such as sonication time, solid/liquid ratio and concentration of solvent on extraction of phenolic compounds were evaluated through a randomized complete block design with factorial treatment arrangement (33). The best extraction conditions were: 1 g plant sample with 12 mL of 35% ethanol, for 40 min, obtaining a yield of phenolic compounds of 17.32 ± 1.52 mg g?1 of plant. In addition, free radical-scavenging potential of DPPH and lipid oxidation inhibition, by linoleic acid peroxidation of the selected extract was measured in order to evidence their antioxidant properties. Results indicated that high amounts of phenolic compounds can be extracted from L. nobilis by ultrasound-assisted extraction technology. 相似文献
1000.
Experimental results on dc and ac susceptibility, magnetization and magnetic relaxation, specific heat, electrical resistivity and magnetoresistivity up to 8?T are reported for the novel ternary uranium aluminide U3Co4.55Al11.45. The temperature dependence of the dc susceptibility shows a cusp at a characteristic temperature T f?=?8–10?K that depends weakly on the applied magnetic field. The observed pronounced difference between the ZFC and FC magnetizations, as well as the decay in the remanent, both give evidence that a highly irreversible, frozen state is formed below T f which is reminiscent of spin-glass behaviour. The real and imaginary parts of the ac susceptibility show that the corresponding T f peaks are only slightly dependent on frequency. Electrical resistivity measured at zero and in fields up to 8?T indicates that the Kondo-like state becomes dominant at temperatures above T f. 相似文献