非线性边值条件非线性方程的奇摄动问题

研究了三阶非线性边值条件的非线性方程奇摄动问题,先用合成展开法对形式近似解进行构造,再利用相关微分不等式理论给出所得解的存在性及一致有效性的证明.     

基于时反导波检测的管道缺陷圆周定位研究

用传递函数的观点,分析由缺陷这个被动的导波源产生的时间反转波场的传播方式.通过推导时间反转波幅值的表达式,在理论上论证了时间反转聚焦效应可用于管道导波缺陷的检测和定位.在分析影响缺陷定位的重要因素的同时,阐述了基于时间反转理论的管道单缺陷和双缺陷定位试验研究,进一步说明了在管道导波检测时,采用试验与有限元结合的方式实现缺陷的轴向和周向定位的方法是实际可行的,该方法同时还解决了管道轴向位置相同的双缺陷辨识问题.     

Hydrogen peroxide biosensor based on electrodeposition of zinc oxide nanoflowers onto carbon nanotubes film electrode

A new amperometric biosensor for hydrogen peroxide was developed based on adsorption of horseradish peroxidase at the glassy carbon electrode modified with zinc oxide nanoflowers produced by electrodeposition onto multi-walled carbon nanotubes （MWNTs） film. The morphology of the MWNTs/nano-ZnO electrode has been investigated by scanning electron microscopy （SEM）, and the electrochemical performance of the electrode has also been studied by amperometric method. The resulting electrode offered an excellent detection for hydrogen peroxide at -0.11 V with a linear response range of 9.9×10^-7 to 2.9×10^-3 mol/L with a correlation coefficient of 0.991, and response time 〈5 s. The biosensor displays rapid response and expanded linear response range, and excellent stability.     

Electrochemical oxidation behavior of hydroxypivalaldehyde in the ionic liquids

The similar electrochemical oxidation behaviors of hydroxypivalaldehyde in ionic liquids （ILs） medium, C4MIMPF6, C4MIMBF4 and CsMIMPF6, are investigated using classic electrochemical methods, respectively. Only the product, hydroxypivalic acid is detected by high performance liquid chromatography （HPLC）. It can be conferred that the electrochemical oxidation of hydroxypivalaldehyde consists of two successive one-electron irreversible reactions at glass carbon （GC） electrode and the possible reaction mechanism in the ILs is proposed firstly. The diffusion coefficients of hydroxypivalaldehyde are obtained according to the electrochemical characteristics of hydroxypivalaldehyde in C4MIMPF6, C4MIMBF4 and CsMIMPF6.     

Crystal Structure of Ethyl 4-benzoyl-1a,2,3,4-tetrahydro-3-methyl-1a-(4-methylphenyl)-1H-azirino〔1,2-a〕〔1,5〕 benzodiazepine-1-carboxylate(C_(28)H_(28)N_2O_3)

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Synthesis and Crystal Structure of a Mixed Cu - Cd Bim etallic Com plex ｛〔 Cu Cd(pba)( H_2 O)_3〕·2 H_2 O｝ _n

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苯酚在热氧化法制备的SnO2/Ti 电极上的电氧化研究

A SnO₂/Ti electrode prepared by thermal oxidation was used as the anode for galvanostatic electrolysis in acidic solution containing phenol, the time-dependances of phenol concentration,chemical oxygen demand in solution(COD)and instantaneous current efficiency were determined during electrolysis.The results show that with the SnO₂/Ti anode instead of Pt,the COD significantly decreases at the same charge passage, and average current efficiency of oxidation increases by three times The mechanism for phenol oxidation at two electrodes was discussed.     

周向超声导波对管道纵向缺陷检测的研究

在弹性动力学理论的基础上,研究了管道中周向超声导波的传播及其频散特性,并数值计算了周向导波的频散曲线。通过所建立的超声导波实验系统,在理论上与实验上研究了斜探头的入射角、频率及周向导波模态的关系,并在外径为88.8 mm、内径为80.8 mm的管道中激励出特定的单一模态周向导波;同时,利用单一模态周向导波对该管道表面上长25 mm、宽1 mm、深0.7 mm的人工缺陷进行了检测。结果表明,同在板中激励单一Lamb波模态类似,选用特定角度的斜探头与特定频率可在管道中激励出单一周向导波模态并有望应用于管道缺陷的检测。