首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   8989篇
  免费   1288篇
  国内免费   769篇
化学   6692篇
晶体学   118篇
力学   403篇
综合类   49篇
数学   841篇
物理学   2943篇
  2024年   19篇
  2023年   171篇
  2022年   167篇
  2021年   283篇
  2020年   353篇
  2019年   320篇
  2018年   248篇
  2017年   225篇
  2016年   425篇
  2015年   360篇
  2014年   444篇
  2013年   644篇
  2012年   839篇
  2011年   863篇
  2010年   520篇
  2009年   519篇
  2008年   603篇
  2007年   576篇
  2006年   497篇
  2005年   457篇
  2004年   300篇
  2003年   206篇
  2002年   224篇
  2001年   190篇
  2000年   182篇
  1999年   158篇
  1998年   145篇
  1997年   113篇
  1996年   108篇
  1995年   137篇
  1994年   121篇
  1993年   90篇
  1992年   79篇
  1991年   68篇
  1990年   64篇
  1989年   34篇
  1988年   46篇
  1987年   35篇
  1986年   35篇
  1985年   31篇
  1984年   23篇
  1983年   9篇
  1982年   20篇
  1981年   14篇
  1980年   7篇
  1979年   7篇
  1978年   10篇
  1977年   8篇
  1976年   7篇
  1975年   7篇
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
71.
In this paper an extension of the (r|X p )-medianoid on networks introduced by Hakimi (1983) is studied. In this extension the customer considers not only the distance but some characteristics of the facilities such as store size, quality of service and parking space. A new firm wants to establishr new facilities which have to compete with thep facilities that already exist in the market. The entry firm wants to find their locations and characteristics to maximize profits. Three different customer choice rules (binary, partially binary and proportional preferences) are considered. Some discretization results are obtained and a resolution procedure is proposed. The problem is solved combining a global search algorithm based on a branch and bound procedure with some combinatorial heuristics (greedy, interchange, and tabu search). Some computational experiences are presented. Partially supported by Ministerio de Ciencia y Tecnología (Spain) and FEDER, grant BFM2002-04525-C02-01.  相似文献   
72.
采用共沉淀法制备了系列La掺杂改性的含Cu类水滑石,高温焙烧得到其衍生混合氧化物材料,并用XRD,TG-DSC,FT-IR等对材料进行表征.结果表明,前驱物XRD图谱呈典型的水滑石衍射特征且颗粒结晶良好;经800℃焙烧后,掺杂La2O3含量为5.1%的样品仅有Mg1-xFexO晶相出现,说明La的掺杂提高了材料的高温稳定性,混合氧化物中的Cu离子呈高分散状态.  相似文献   
73.
The synthesis of three new series of chiral Schiff's bases containing benzilideneaniline and 2-hydroxybenzilideneaniline moieties as mesogenic cores is presented. Differential scanning calorimetry, optical polarizing microscopy and X-ray diffraction measurements were used to study the phase transition temperatures and behaviour. The results reveal that most of these materials show chiral smectic mesomorphism.  相似文献   
74.
Results from a systematic experiment on isolated perfused rat heart and isolated myocytes of adult rat showed that the mechanism of calcium influx during myocardial ischemia-reperfusion is due to the development of intracellular sodium overload during ischemic period; on reperfusion, the high intracellular Na+ content activated the reverse direction of Na(+)-Ca2+ exchange over myocardial sarcolemma (SL), thus a large quantity of extracellular Ca2+ fluxed over the SL to the intracellular space, forming a condition of intracellular Ca2+ overload, which leads to irreversible damage of the myocardium.  相似文献   
75.
常胜江  张文伟 《光学学报》1998,18(10):332-1335
提出了一种用于修正光学神经网络硬件系统误差的虚拟神经网络模型,光学实验结果表明该网络能够有效地消除硬件系统误差对实验结果的影响。  相似文献   
76.
We prove embedding results of weighted W1,p(RN) spaces of radially symmetric functions. The results then are used to obtain ground and bound state solutions of quasilinear equations with unbounded or decaying radial potentials.  相似文献   
77.
Three pyrrololactam alkaloids have been isolated from the marine sponge Phacellia fusca Schmidt collected from the South China Sea, and their structures were determined as 1–3 , on the grounds of spectral data. This is the first report of these compounds from this sponge. The structure of 1 was confirmed by X-ray analysis.  相似文献   
78.
We reported controllable synthesis of ZnS nanocrystal-polymer transparent hybrids by using polymethylmethacrylate (PMMA) as a polymer matrix. In a typical run, the appropriate amounts of zinc chloride (ZnCl2) and sodium sulfide (Na2S) in the presence of 2-mercaptoethanol (ME) as the organic ligand were well dispersed in H2O/dimethylformamide solution without any aggregation. In addition, the Mn-doped ZnS nanocrystals (NCs) were synthesized with similar method. Then, ZnS-PMMA hybrids were obtained via free radical polymerization in situ by using ZnS NCs functionalized with methacryloxypropyltrimethoxysilane (MPS). FT-IR characterization indicates the formation of robust bonding between ZnS NCs and the organic ligand. The TEM images show that ZnS NCs are well dispersed in PMMA matrix, and particle size of as-prepared ZnS NCs is about 2.6 nm, in agreement with the computing results of Brus’s model and Debye–Scherrer formula. The photoluminescence measurements present that ZnS NCs, Mn-doped ZnS NCs, and ZnS/PMMA hybrid show good optical properties.  相似文献   
79.
用光锥QCD求和规则研究D→Klv~l衰变过程,首先计算D→K跃迁形状因子,通过构造新的关联函数,消除了twist-3波函数的不确定性给计算结果所带来的影响,从而使计算结果更加精确. 计算得到的分支比与最近的实验数据相一致. 关键词: QCD光锥求和规则 D介子半轻衰变 分支比 形状因子  相似文献   
80.
Two series of novel fluorinated poly(ether imide)s (coded IIIA and IIIB ) were prepared from 2,6‐bis(3,4‐dicarboxyphenoxy)naphthalene dianhydride and 2,7‐bis(3,4‐dicarboxyphenoxy)naphthalene dianhydride, respectively, with various trifluoromethyl‐substituted aromatic bis(ether amine)s by a standard two‐step process with thermal or chemical imidization of the poly(amic acid) precursors. These fluorinated poly(ether imide)s showed good solubility in many organic solvents and could be solution‐cast into transparent, flexible, and tough films. These films were nearly colorless, with an ultraviolet–visible absorption edge of 364–386 nm. They also showed good thermal stability with glass‐transition temperatures of 221–298 °C, 10% weight loss temperatures in excess of 489 °C, and char yields at 800 °C in nitrogen greater than 50%. The 2,7‐substituted IIIB series also showed better solubility and higher transparency than the isomeric 2,6‐substituted IIIA series. In comparison with nonfluorinated poly (ether imide)s, the fluorinated IIIA and IIIB series showed better solubility, higher transparency, and lower dielectric constants and water absorption. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5909–5922, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号