Effect of the preparation method of the cathode material LiNi<Subscript>0.33</Subscript>Mn<Subscript>0.33</Subscript>Co<Subscript>0.33</Subscript>O<Subscript>2</Subscript> on the electrochemical characteristics of a lithium ion cell

Complex metal oxides with the composition LiNi_0.33Mn_0.33Co_0.33O₂ prepared by various methods: sol–gel method, solid-phase method, and thermal destruction of metal-containing compounds in oil were studied. The results of elemental analysis, TGA/DSC, powder X-ray diffraction, SEM, TEM, as well as the results of electrochemical testing of the cathodes based on the obtained materials are presented. The complex metal oxides LiNi_0.33Mn_0.33Co_0.33O₂ prepared by sol–gel processes and thermal destruction of metal-containing compounds in oil consist of primary nanosized crystallites with an average size of 90 nm covered by a nanometer carbon layer, which improves the electrochemical characteristics of lithium ion batteries.     

Structure and dynamics of the plasma armature of railgunmacroparticle accelerators

Results of the optical diagnostics of the plasma armature in railgun macroparticle accelerators are summarized. Determining the structure of the plasma armature and measuring its brightness and temperature at an initial stage of high-current discharge are the focus of attention. Experiments show that the plasma induced by the electric explosion of a copper foil undergoes complex variations that include plasma stratification. The plasma structure continuously changes, being of a complicated, irregular character. The lifetime of an individual stratum changes within 1 to 10 μs. In experiments on solid-body acceleration, the arc burns for a long time at the foil site, where a strong electrode erosion takes place. As the body passes through the railgun channel, the plasma armature continuously increases its length so that it gradually occupies the entire accelerator channel. the current is observed to redistribute itself from the front towards the end face of the plasma armature. The maximum brightness temperature measured in the experiments is 26000±2600 K. As is shown by the experiments, it is arguable that a magnetic-compressed discharge may be realized in a railgun solid-body accelerator with a plasma armature     

Synthesis of some polycyclic noncondensed pyrimidine structures

Methods for the synthesis of compounds containing two or more pyrimidine rings linked through aliphatic chains with different numbers of carbon atoms are described.Deceased.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 335–340, February, 1995     

Improvements in the Grinding of Gold-Bearing Geochemical Samples and Their Sampling for Fire Assay

The effect of fine grinding of gold-bearing geochemical samples on the representative sample size and the recovery of gold and silver in fire-assay fusion was studied experimentally. A method is proposed for the improvement of grinding and sampling procedures in fire assay.     

Studying the dependence of the representative weight of geological samples of gold-containing ores on their particle size

The dependence of the representative weight of a geological sample of quartz sulfide gold-containing ores on their particle size is studied. It is shown that the weight of the furrow samples selected in the chemical assay of gold-containing ores of the first group can be reduced two-to threefold.     

Magnetization dynamics of molecular magnets in a circular polarized electromagnetic wave of millimeter range

The appearance of magnetization in a crystal of molecular magnets under the action of a circular polarized electromagnetic wave of millimeter range is considered. The time dependence of magnetization is obtained for the case of resonance and for approximation of the single relaxation time.     

NAA for applied investigations at FLNP JINR: present and future

Experience in applying conventional and epithermal neutron activation analysis for some challenging areas of life sciences and material science is reviewed. For more than 30 years of its operation the radioanalytical complex REGATA at the IBR-2 reactor in Dubna has become a source of analytical data for the environmental studies, marine geology, biotechnology and medicine, technological process of diamond and boron nitride synthesis, archaeology, nanomaterials, etc. In spite of competing non-nuclear analytical techniques (AAS, ICP-ES, ICP-MS, etc.), the reactor neutron activation analysis (NAA) as a primary (ratio) method continues to be the most powerful multielement analytical technique providing quantification of trace elements at ultralow levels. Combined with modern statistical data treatment of large arrays of data, GIS (geographic information system) technologies, electron scanning microscopy, tomography, and others, NAA serves to obtain actual, practical results resumed in the review. The perspectives of using the upgraded reactor IBR-2M for analytical investigations are discussed.