Discrimination between ω-amino acids with chromogenic acyclic tripodal receptors functionalized with stilbazolium dyes

A tripodal receptor functionalized with a stilbazolium dye derivative has been designed, synthesized and has been used for the colorimetric discrimination between certain ω-amino acids in mixed DMSO-water 90:10 v/v solutions.     

Determination of sub‐ppb epichlorohydrin levels in water by on‐line solid‐phase extraction liquid chromatography/tandem mass spectrometry

A new sensitive and selective method based on on‐line solid‐phase extraction (SPE) coupled to liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI‐MS/MS) using a triple quadrupole mass spectrometer has been developed for the determination of epichlorohydrin (ECH) in different types of water samples. ECH is not easily determined directly by ESI‐MS as it is not readily ionized, and it has a low molecular mass and high polarity. Thus, prior derivatization of ECH was necessary, employing 3,5‐difluorobenzylamine as a derivatizing agent with Fe(III) as a catalyst. In order to achieve accurate quantification, correcting for matrix effects, losses in the derivatization process and instrumental deviations, isotope labelled ECH (ECH‐d₅) was added as an internal standard (IS) to the water samples. The method was validated based on European SANCO guidelines using drinking and other types of treated water spiked at two concentration levels (0.1 and 1.0 µg/L), the lower level having been established as the limit of quantification (LOQ) of the method. Satisfactory accuracy (recoveries between 70 and 103%), precision (RSD <20%) and linearity (from 0.05 to 50 µg/L, r >0.99) were obtained. The limit of detection (LOD) was set up at 0.03 µg/L. The method was applied to different water samples (drinking water and water samples collected from a municipal treatment water plant). In order to enhance confidence, five selected reaction monitoring (SRM) transitions were acquired, thus obtaining a simultaneous reliable quantification and identification of ECH in water, even at sub‐ppb levels. Copyright © 2009 John Wiley & Sons, Ltd.     

Impact of sideband harmonic pattern on losses in laminated non-oriented steel

Losses in laminated non-oriented steel under the effect of two high harmonic clusters, caused by voltage excitation typical of two-level pulse-with-modulated (PWM) DC-link and space-vector modulated (SVM) matrix converters, were analyzed. The predicting method proposed, which incorporates anisotropy of loss K_a and grain size g_s, describes the magnetizing process within the steel by the means of Poisson statistical distribution. Results are then compared to losses determined by Bertotti's model. The two methods confirmed that spreading of sideband harmonics in the kilohertz range can reduce harmonic losses by up to 40% at low power frequencies.     

Study of color and structural changes in silver painted medieval glasses

Silver was introduced into medieval glass by an ancient painting process using different clay minerals (ochre, illitic, montmorillonitic, and kaolinitic clays). The colorimetric properties, studied by UV-Vis spectroscopy, were dependent on the clay mineral as a result of different concentration of Ag ions diffused into the glass surface. TEM results showed the well known formation of silver nanoclusters which give the yellow coloration of the glass. The obtained results showed that clay properties such as specific surface area, pore volume and iron concentration (Fe₂O₃), are important factors that affect the yellow coloration. It is also observed that Fe₂O₃ acts as an oxidant agent for silver atoms providing the Ag₂O formation. This oxide cannot diffuse into the glass structure and avoid the ion-exchanged process. After Ag ion diffusion some structural changes occur in the glass as it has been shown by Raman spectroscopy. It is observed that the diffusion process leads to depolymerization of the glass network as it is determined by analyzing the Qⁿ components of Raman spectra. Two Raman bands at 148 and 244 cm⁻¹ assigned to Ag-O bonds can be associated to the presence of Ag₂O on the glass painted surface.     

Liaison addition and the structure of a Gorenstein liaison class

We study the concept of liaison addition for codimension two subschemes of an arithmetically Gorenstein projective scheme. We show how it relates to liaison and biliaison classes of subschemes and use it to investigate the structure of Gorenstein liaison equivalence classes, extending the known theory for complete intersection liaison of codimension two subschemes. In particular, we show that on the non-singular quadric threefold in projective 4-space, every non-licci ACM curve can be obtained from a single line by successive liaison additions with lines and CI-biliaisons.     

Delay in the alternating-offers model of bargaining

Alternating offers bargaining has been extensively used to model two-sided negotiations. The celebrated model of Rubinstein [Econometrica 50(1):97–109, 1982] has provided a formal justification for equitable payoff division. A typical assumption of these models under risk is that the termination event means a complete and irrevocable breakdown in negotiations. In this paper, the meaning of termination is reinterpreted as the imposition to finish negotiations immediately. Specifically, bargaining terminates when the last offer becomes definitive. While Rubinstein’s model predicts an immediate agreement with stationary strategies, we show that the same payoff allocation is attainable under non-stationary strategies. Moreover, the payoffs in delayed equilibria are potentially better for the proposer than those in which agreement is immediately reached.