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51.
白洋淀内水体的流动特征研究 总被引:2,自引:0,他引:2
研究了风对白洋淀内水体循环流动的影响,研究指出:(1)风应力可看作是水体循环
的主要驱动力. (2)在风应力的作用下,水体表层的流动主方向与风的方向一致,下层水体
的流动方向与表层方向相逆或近似相逆. (3)表层以下水体流动复杂,次表层水平流动有明
显的双涡结构. (4)淀底地形对水体垂向流动影响很大,垂向速度变化复杂,垂向上有双涡
流动现象. 从动力学角度研究了淀内水体流动的情况. 相似文献
52.
Mass spectrometry (MS)-based studies of synthetic polymers often characterise detected polymer components using mass data alone. However when mass-based characterisations are ambiguous, tandem MS (MS/MS) offers a means by which additional analytical information may be collected. This review provides a synopsis of two particularly promising methods of dissociating polymer ions during MS/MS: electron-capture and electron-transfer dissociation (ECD and ETD, respectively). The article opens with a summary of the basic characteristics and operating principles of ECD and ETD, and relates these techniques to other methods of dissociating gas-phase ions, such as collision-induced dissociation (CID). Insights into ECD- and ETD-based MS/MS, gained from studies into proteins and peptides, are then discussed in relation to polymer chemistry. Finally, ECD- and ETD-based studies into various classes of polymer are summarised; for each polymer class, ECD- and ETD-derived data are compared to CID-derived data. These discussions identify ECD and ETD as powerful means by which unique and diagnostically useful polymer ion fragmentation data may be generated, and techniques worthy of increased utilisation by the polymer chemistry community. 相似文献
53.
How to make the Cassie wetting state stable? 总被引:1,自引:0,他引:1
Wetting of rough hydrophilic and hydrophobic surfaces is discussed. The stability of the Cassie state, with air trapped in relief details under the droplet, is necessary for the design of true superhydrophobic surfaces. The potential barrier separating the Cassie state and the Wenzel state, for which the substrate is completely wetted, is calculated for both hydrophobic and hydrophilic surfaces. When the surface is hydrophobic, the multiscaled roughness of pillars constituting the surface increases the potential barrier separating the Cassie and Wenzel states. When water fills the hydrophilic pore, the energy gain due to the wetting of the pore hydrophilic wall is overcompensated by the energy increase because of the growth of the high-energetic liquid-air interface. The potential barrier separating the Cassie and Wenzel states is calculated for various topographies of surfaces. Structural features of reliefs favoring enhanced hydrophobicity are elucidated. 相似文献
54.
The reaction of the thiocarbamoyl‐molybdenum complex [Mo(CO)2(η2‐SCNMe2)(PPh3)2Cl] 1 , with EtOCS2K and C4H8NCS2NH4 in dichloromethane at room temperature yielded the seven coordinated ethyldithiocarbonate thiocarbamoyl‐molybdenum complex [Mo(CO)2(η2‐S2COEt)(η2‐SCNMe2)(PPh3)] 2 , and the dithiocarbamate thiocarbamoyl‐molybdenum complex [Mo(CO)2(η2‐S2CNC4H8)(η2‐SCNMe2)(PPh3)] 3 . The geometry around the metal atom of compounds 2 and 3 are capped octahedrons as revealed by X‐ray diffraction analyses. The thiocarbamoyl and ethyldithiocarbonate or pyrrolidinyldithiocarbamate ligands coordinate to the molybdenum metal center through the carbon and sulfur and two sulfur atoms, respectively. Structure parameters, NMR, IR and Mass spectra are in agreement with the crystal chemistry of the two compounds. 相似文献
55.
Abstract The infrared spectrum of 3-bromo-1,3-dinitroazetidine was interpreted with the aid of normal coordinate calculations. A seventy-two parameter modified valence field was used in those calculations, and the observed wave numbers were fit with an average error of 2.5 cm?1. An assignment of the bands in terms of symmetry coordinates is given. Many of the force constants were transferred to 1-acetyl-3,3-dinitroazetidine to aid in normal coordinate calculations for that compound. 相似文献
56.
C.V.C. Prasad Stephen E. Mercer Gene M. Dubowchik John E. Macor 《Tetrahedron letters》2007,48(15):2661-2665
Enantioselective synthesis of constrained trans-aminobenzazepinone utilizing palladium-mediated Jeffery-Heck reaction and rhodium(II) catalyzed asymmetric hydrogenation as key steps are described. Diverse functional groups such as alkyl, aryl, basic or amino acid moieties were introduced with minimal racemization. 相似文献
57.
We give necessary and sufficient conditions on a row-finite graph E so that the Leavitt path algebra L(E) is purely infinite simple. This result provides the algebraic analog to the corresponding result for the Cuntz-Krieger C∗-algebra C∗(E) given in [T. Bates, D. Pask, I. Raeburn, W. Szymański, The C∗-algebras of row-finite graphs, New York J. Math. 6 (2000) 307-324]. 相似文献
58.
Summary The problem of generating the recurrence coefficients of orthogonal polynomials from the moments or from modified moments of the weight function is well understood for positive weight distributions. Here we extend this theory and the basic algorithms to the case of an indefinite weight function. While the generic indefinite case is formally not much different from the positive definite case, there exist nongeneric degenerate situations, and these require a different more complicated treatment. The understanding of these degenerate situations makes it possible to construct a stable approximate solution of an ill-conditioned problem.The application to adaptive iterative methods for linear systems of equations is anticipated.Dedicated to R.S. Varga on the occasion of his sixtieth birthdayG.H. Golub (USA, Canada), M.H. Gutknecht (other countries) 相似文献
59.
Gene Abrams 《Israel Journal of Mathematics》1997,99(1):343-347
We give examples of distinct integersi, j, and ringsT for which the matrix ringsM
i
(T) andM
j
(T) are isomorphic as rings, but for which the free modules
T
T
(i) and
T
T
(i) are non-isomorphic asT-modules. 相似文献
60.
Dale Newbury David Wollman Sae Woo Nam Gene Hilton Kent Irwin John Small John Martinis 《Mikrochimica acta》2002,138(3-4):265-274
Analytical X-ray spectrometry for electron beam instruments has advanced significantly with the development of the microcalorimeter
energy dispersive X-ray spectrometer (μcal EDS). The μcal EDS operates by measuring the temperature rise when a single photon
is absorbed in a metal target. A cryoelectronic circuit with electrothermal feedback and a superconducting transition edge
sensor serves as the thermometer. Spectral resolution approaching 4.5 eV for high energy photons (6000 eV) and 2 eV for low
energy photons below 2000 eV has been demonstrated in energy dispersive operation across a photon energy range from 250 eV
to 8 keV. Spectra of a variety of materials demonstrate the power of the μcal EDS to solve practical problems while operating
on a scanning electron microscope platform. 相似文献