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31.
Ewa Bulska Katarzyna Wróbel Adam Hulanicki 《Fresenius' Journal of Analytical Chemistry》1992,342(9):740-743
Summary The optimal conditions for the determination of aluminium and chromium in blood serum are proposed. Several sample pretreatment procedures for the purpose are compared. The best results are obtained by sample dilution with nitric acid (0.1 mol/l) and addition of Mg(NO3)2 as modifier with a magnesium concentration of 0.2 mg/ml. This procedure has been used for studying the intestinal intake of aluminium by patients after oral administration of aluminium compounds. 相似文献
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33.
Sandy AR Mochrie SG Zehner DM Grübel G Huang KG Gibbs D 《Physical review letters》1992,68(14):2192-2195
34.
The solid state structures of three nitroformate (NF) salts were determined using single crystal X‐ray crystallography. The NF anion was found to be a non‐planar moiety which adopts either the commonly observed C2v conformation or distorted propeller conformation (D3) in the case of the silver salts, or, a C2 conformation in the case of the potassium salt. This latter C2 conformation has been uniquely observed for potassium nitroformate. All structures exhibit cation‐anion interactions that influence the structure of the anion. The 13C and 14N NMR spectra of the NF anion show broad singlets, which indicates the equivalence of the nitro groups in solution within the NMR time‐scale. In addition, the vibrational and mass spectra of potassium nitroformate and silver nitroformate monohydrate were recorded. Furthermore, the gaseous decomposition products of potassium nitroformate at 25 °C were detected using IR spectroscopy and mass spectrometry. 相似文献
35.
Rancan F Wiehe A Nöbel M Senge MO Omari SA Böhm F John M Röder B 《Journal of photochemistry and photobiology. B, Biology》2005,78(1):17-28
The search for new efficient sensitizers for photodynamic therapy (PDT) points to improve photophysical properties like absorption in the red region and singlet oxygen quantum yield as well as to control the localization of the sensitizer within the tumour cell. Depending on their physicochemical properties and their uptake mechanism, sensitizers can reach different intracellular concentrations and localize in different subcellular compartments. Moreover, the preferential localization of a sensitizer in target organelles, like mitochondria or lysosomes, could determine the cell death mechanism after PDT. This study aimed to investigate the influence of substitutions on dihydroxychlorins with regard to intracellular uptake, subcellular localization and cell death pathway. Moreover, the effect of a liposome-based delivery system was tested. The intracellular uptake was found to be strictly dependent on the sensitizer molecular structure and the means of its delivery. The most polar sensitizer in this study (compound 3) had, depending on incubation time, an intracellular concentration 2-8 times higher than the unsubstituted chlorin 1. All investigated photosensitizers localize predominantly in lysosomes but after longer incubation times weak fluorescence intensity was also detected in mitochondria and Golgi apparatus. The cell death pathway was found to be influenced by the sensitizer intracellular concentration and the applied light doses. In general, the increasing amphiphilicity of the sensitizer molecules is correlated with an increased sensitizer uptake and an increased rate of necrotic cells after irradiation. 相似文献
36.
K. Hardt R. Kroth G. Mikus C. Günther M. Guttormsen H. Hübel J. Recht R. Tischler 《Zeitschrift für Physik A Hadrons and Nuclei》1982,305(1):1-7
The magnetic moment of the 11 ns, 15? isomer in204Po and the internal magnetic field of Po in Ni were determined in an in-beam recoil implantation experiment. Time-differential perturbed angular distributions of conversion electrons were measured in an iron-free orange spectrometer. The magnetic hyperfine field of ¦H(PoNi)¦=555(22) kOe is in agreement with the systematic trend for the 6p elements. Theg-factorg(15?) =0.41(2) is discussed, together with theB (E2, 15?→13?). within the shell model. 相似文献
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38.
Abstract Dielectric relaxation of water molecules in the lamellar, Lα, cubic and hexagonal, Hα, lyotropic structures of nonylphenoxy-poly(ethylenoxy)ethanol (Ark. 9) has been studied by dielectric time domain spectroscopy in the frequency range between 10 MHz and 10 GHz. The values of the relaxation times, obtained at room temperature, are the following: 41 ps for the Lα phase, 29 ps for the cubic phase and 22 ps for the Hα phase. As is seen, the relaxation time of bound water is distinctly higher than that of pure water, and it depends strongly on the phase structure. The relaxation times measured for the liquid-crystalline phases as well as for pure Ark. 9 obey the Arrhenius law, and the energy barriers obtained have the following values: (20 ± 2) kJ/mol for all the liquid-crystalline phases, and (30 ± 3) kJ/mol for pure Ark. 9. The former is in good agreement with the value found for bound water in lipid systems whereas the latter is characteristic of the isotropic phase of thermotropic liquid crystals. 相似文献
39.
Szymon Szufa Piotr Piersa ukasz Adrian Justyna Czerwiska Artur Lewandowski Wiktoria Lewandowska Jan Sielski Maria Dziku Marek Wrbel Marcin Jewiarz Adrian Knapczyk 《Molecules (Basel, Switzerland)》2021,26(4)
Miscanthus is resistant to dry, frosty winters in Poland and most European Union countries. Miscanthus gives higher yields compared to native species. Farmers can produce Miscanthus pellets after drying it for their own heating purposes. From the third year, the most efficient plant development begins, resulting in a yield of 25–30 tons of dry matter from an area of 1 hectare. Laboratory scale tests were carried out on the processes of drying, compacting, and torrefaction of this biomass type. The analysis of the drying process was conducted at three temperature levels of the drying agent (60, 100, and 140 °C). Compaction on a hydraulic press was carried out in the pressure range characteristic of a pressure agglomeration (130.8–457.8 MPa) at different moisture contents of the raw material (0.5% and 10%). The main interest in this part was to assess the influence of drying temperature, moisture content, and compaction pressure on the specific densities (DE) and the mechanical durability of the pellets (DU). In the next step, laboratory analyses of the torrefaction process were carried out, initially using the Thermogravimetric Analysis TGA and Differential Scaning Calorimeter DSC techniques (to assess activation energy (EA)), followed by a flow reactor operating at five temperature levels (225, 250, 275, 300, and 525 °C). A SEM analysis of Miscanthus after torrefaction processes at three different temperatures was performed. Both the parameters of biochar (proximate and ultimate analysis) and the quality of the torgas (volatile organic content (VOC)) were analyzed. The results show that both drying temperature and moisture level will affect the quality of the pellets. Analysis of the torrefaction process shows clearly that the optimum process temperature would be around 300–340 °C from a mass loss ratio and economical perspective. 相似文献
40.