Numerical Investigation of the Natural Convection of Water in the Neighborhood of the Density Inversion Point For Grashof Numbers up to 106

The natural convection of fresh water in a square cell is considered at a temperature close to the density inversion temperature for Grashof numbers 2.9 · 10⁴ Gr 10⁶. As a result of the numerical investigation, one steady-state and three self-oscillating regimes are found in addition to the three steady-state flows previously detected earlier and described for low Grashof numbers ( 0 Gr 2 · 10⁵). The basic characteristics of the unsteady flows are analyzed by means of the Fourier method, the fundamental oscillation frequencies are found, and the flow evolution and the variation of the oscillation characteristics with increase in the Gr number are considered.     

Composition and reactivity of aminolysis products of phenyl glycidyl ether with benzylamine

Composition of aminolysis products of phenyl glycidyl ether with benzylamine in various conditions was studied. The ratio of 1-(benzylamino)-3-phenoxypropan-2-ol and 1,1'-(benzylazanediyl)bis(3-phenoxypropan-2-ol) does not considerably depend on the nature of the solvent and is basically determined by ratio of initial reagents. 2,6-Bis(phenoxymethyl)morpholine was obtained by dehydration of aminodiol in conditions of Mitsunobu reaction with subsequent reductive debenzylation.     

Determination of the shape of the shocks ahead of a transverse jet injected into a supersonic flow

The three-dimensional shape of the shock wave formed ahead of a sonic jet flowing out into a supersonic flow through the surface of a sharp cone is determined. The shape of the wave in the longitudinal and transverse cross-sections of the model is constructed using schlieren photographs taken for various angles of rotation and freestream Mach numbers M=1.75–3. Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 2, pp. 41–44, March–April, 1998. This research was carried out with financial support from the Russian Foundation for Basic Research (project No. 95-01-00709a).     

Synthesis, structure, and physicochemical properties of K[VO2(SeO4)(H2O)] and K[VO2(SeO4)(H2O)2] · H2O

The vanadium(V) complexes K[VO₂(SeO₄)(H₂O)] and K[VO₂(SeO₄)(H₂O)₂] · H₂O were synthesized using original procedures; their physicochemical properties were studied, and the crystal structure was determined on the basis of X-ray diffraction and neutron diffraction data. The structure of K[VO₂(SeO₄)(H₂O)₂] · H₂O is composed of VO₆ octahedra connected to form infinite chains by bridging SeO₄ tetrahedra. Each VO₆ tetrahedron has short terminal V-O bonds forming the bent dioxovanadium group VO₂⁺ The unit cell parameters of K[VO₂(SeO₄)(H₂O)₂] · H₂O are a = 6.4045(1) ?, b = 9.9721(2) ?, c = 6.6104(1) ?, β = 107.183(1)°, V = 403.34 ?³, Z = 2, monoclinic system, space group P2₁. The complex K[VO₂(SeO₄)(H₂O)] forms a two-dimensional layered structure composed of highly distorted VO₆ octahedra having two short terminal V-O bonds and SeO₄ groups coordinated simultaneously by three vanadium atoms. This compound crystallizes in the monoclinic system (space group P2₁/c): a = 7.3783(1) ?, b = 10.5550(2) ?, c = 10.3460(2) ?, β = 131.625(1)°, V = 602.894(5) ?³, Z= 4. The vibrational spectra of the studied compounds are fully consistent with their structural features.     

Supersonic Flow Past an Obstacle with a Clearance at the Base

The supersonic air flow structure and the pressure distribution in the vicinity of a vertical cylinder suspended over the surface of a plate with a turbulent boundary layer are studied experimentally. The effects of the free-stream Mach number and the width of the clearance between the cylinder base and the surface on the dimensions of the separated flow region and the pressure distribution in the latter are examined.     

Electronic structure and chemical bonding in Ba-Cu-O layer systems

The cluster method of discrete variation was used to study compounds containing chains of plane-coordinated copper ions separating oxygen-copper planes. We also examined real YBa₂Cu₃O₇ and hypothetical MBa₃Cu₄O₉ systems (M is a tetravalent metal ion). A study was carried out on the transformation of the valence band and structure of the molecular orbitals in the Fermi level in going from YBa₂Cu₃O₇ to MBa₃Cu₄O₉. The chemical bonding was analyzed and the role of the interchain interaction in the bonding of the copper and oxygen atoms in different crystallographic positions was determined.Institute of Chemistry, Urals Branch, Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 30, No. 5, pp. 17–20, September–October, 1989.     

Development of forced high-elastic deformations in polystyrene and its self-unloading capacity

The thermodynamic states of two systems of impact polystyrene based on polybutadiene-styrene rubbers are investigated, without introducing spectrography, in terms of the theory of linear viscoelasticity. The results are confirmed by the considerable difference in physicomechanical properties.Ukrainian Scientific-Research Institute of Plastics, Donetsk. Translated from Mekhanika Polimerov, Vol. 4, No. 4, pp. 595–597, July–August, 1968.