气相色谱-质谱联用法测定维生素C泡腾片中的甜蜜素

采用气相色谱-质谱(GC-MS)选择离子监测法(SIM),建立了准确可靠、灵敏度高、快速简便的测定维生素C泡腾片中甜蜜素含量的新方法.样品中的甜蜜素衍生后用有机试剂提取,在选择离子模式下进行测定,以保留时间和特征离子比例进行定性,单离子定量.甜蜜素的线性范围为0.05-10mg/L,检出限为0.6mg/kg,回收率为90.5%-96.9%,相对标准偏差小于4.4%.方法分析所用时间短,结果准确可靠,选择性好,适用于维生素C泡腾片中甜蜜素含量的检验.     

Buckling and free vibration analyses of stiffened plates using the FSDT mesh-free method

This paper presents a mesh-free Galerkin method for the free vibration and stability analyses of stiffened plates via the first-order shear deformable theory (FSDT). The model of a stiffened plate is formed by (1) regarding the plate and the stiffener separately, (2) imposing displacement compatible conditions between the plate and the stiffener so that displacement fields of the stiffener can be expressed in terms of the mid-surface displacement of the plate, and (3) superimposing the strain energy of plate and stiffener. Because there are no meshes used in this method, the stiffeners can be placed anywhere on the plate and need not be placed along the mesh lines. Several numerical examples are computed by this method to show its accuracy and convergence. The present results demonstrate good agreement with the existing solutions given by other researchers and the ANSYS. Influences of support size and order of the complete basis functions on the numerical accuracy are also investigated.     

基于专家动态权重的群组AHP交互式决策方法

为了能在群组决策中得到更为客观和准确的决策结果,在把专家权重划分为静态权重和动态权重的基础上,研究了在交互式决策中专家动态权重的确定方法,给出了共识度的一个定义.在此基础上,研究了群组AHP交互式决策方法中的一致性和相容性检验,给出了基于专家动态权重的群组AHP交互式决策方法流程,最后用一个示例说明了该方法的应用步骤.     

Response to high acidity and basicity at a platinum electrode in chronopotentiometry

A simple and rapid method is developed to determine the high acidity and the basicity of solutions by chronopotentiometry with a platinum working electrode. The acidity range from 5.0 mol/l H⁺ to 1.0 mol/l OH⁻ can be measured by the adjustment of deposition potential and time. The response mechanism to acidity and basicity has been explored. The transition potential plateau in chronopotentiograms is caused from the oxidation of hydrogen adsorbed on electrode surface.     

Measurement of small-signal and large-signal responses of packaged laser modules at high temperature

In this paper, the pulsed injection method is extended to measure the chip temperature of various packaged laser modules, such as the DFB laser modules, the FP laser modules, and the EML laser modules. An optimal injection condition is obtained by investigating the dependence of the lasing wavelength on the width and period of the injection pulse in a relatively wide temperature range. The small-signal frequency responses and large-signal performances of packaged laser modules at different chip temperature are measured. The adiabatic small-signal modulation characteristics of packaged LD are first extracted. In the large-signal measurement, the effects of chip temperature, bias current and driving signal on the performances of the laser modules are discussed. It has been found that the large-signal performances of the EML modules depend on the different red-shift speeds of the DFB and EAM sections as chip temperature varying, and the optimal characteristics may be achieved at higher temperature.     

Synthesis of TiO2–SiO2/polymer core–shell microspheres with a microphase‐inversion method

A novel microphase‐inversion method was proposed for the preparation of TiO₂–SiO₂/poly(methyl methacrylate) core–shell nanocomposite particles. The inorganic–polymer nanocomposites were first synthesized via a free‐radical copolymerization in a tetrahydrofuran solution, and the poor solvent was added slowly to induce the microphase separation of the nanocomposite and result in the formation of nanoparticles. The average particle sizes of the microspheres ranged from 70 to 1000 nm, depending on the reaction conditions. Transmission electron microscopy and scanning electron microscopy indicated a core–shell morphology for the obtained microspheres. Thermogravimetric analysis and X‐ray photoelectron spectroscopy measurements confirmed that the surface of the nanocomposite microspheres was polymer‐rich, and this was consistent with the core–shell morphology. The influence of the synthetic conditions, such as the inorganic composition and the content of the crosslinking monomer, on the particle properties was studied in detail. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3911–3920, 2006     

Effect of glass bead packing on the fibrillation of liquid‐crystalline polymer in polycarbonate

Polycarbonate (PC) was melt blended with small amount of liquid‐crystalline polymer (LCP) and various contents of glass beads (GB) having different diameters. The rheological measurements indicated that the GB addition increased the viscosity ratio and seemed unfavorable to the LCP fibrillation. However, the morphological observation showed that the LCP fibrillation was promoted by the GB addition and varied with the GB packing. With the increased GB packing by increasing the GB content and/or decreasing the GB diameter, LCP deformed from spheres and ellipsoids into stretched ellipsoids at lower shear rates and into long fibrils at higher shear rates. Although higher content of smaller GB jammed into the larger LCP droplets and inhibited the LCP fibrillation, very long LCP fibrils formed at higher shear rates at a high enough packing of GB. The relationship between GB packing and LCP fibrillation revealed two kinds of hydrodynamic effects of GB promoting the LCP fibrillation: at lower GB packing, the shear flow was enhanced by the high local shear between GB, in quantity; and for a high enough GB packing, the shear flow was changed, in quality, into elongational flow, which was more effective for the LCP fibrillation. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1020–1030, 2006     

Positive Steady States of a Prey-predator Model with Diffusion and Non-monotone Conversion Rate

In this paper, we study the positive steady states of a prey-predator model with diffusion throughout and a non-monotone conversion rate under the homogeneous Dirichlet boundary condition. We obtain some results of the existence and non-existence of positive steady states. The stability and uniqueness of positive steady states are also discussed.     

α-Fe_2O_3纳米微粒/硬脂酸交替L-B膜的结构表征

纳米微粒(NP)是一个新的物质层次,它具有一系列新异的物理、化学特性,涉及到大块样品中所忽略的,或根本不具有的基本物理、化学问题.用NP 制造新型的人工功能材料具有广泛的潜在应用.一个有意义的挑战是能否对NP 进行有序的组装.Zhao andFendler 等曾利用Fe_3O_4NP 进行有序组装的尝试.我们也在前期的初步研究中利用Langmuir-Blodgett(LB)技术对7nm 的α-Fe_2O_3 NP 进行了有序组装的探索,获得了α-Fe_2O_3 NP-硬脂酸交替LB 多层膜(FNSLF).然而这种交替膜的有序情况还不十分清楚.