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51.
A novel calix[4]arene derivative with two ferrocenyl Schiff-base groups at the upper rim 3 has been synthesized from 5,17-diformyl-25,27-dipropoxy-26,28-dihydroxy calix[4]arene and 4-ferrocenylaniline via condensation reaction. Reduction of 3 with sodium borohydride led to calix[4]arene derivative 4 with two amino ferrocenyl groups at the upper rim. The ferrocenyl Schiff-base calix[4]arene and its corresponding reduced amine have been purified and characterized by elemental analysis,1H NMR, FTIR, Mass and UV-vis spectral data. Electrochemical properties of compounds 3 and 4 have been investigated. Cyclic voltammograms of 3 and 4 show reversible redox couples of ferrocene/ferrocinium at E1/2=0.401 V and 0.346 V, respectively. Electrochemical studies show these redox active compounds electrochemically recognize trivalent lanthanides La3+ and Ce3+ and divalent Pb2+ and Cu2+cations. With ferrocenyl Schiff-base calix[4]arene 3 an anodic shift as large as 130 mV is observed on addition of one equivalent of Ce3+ ion. Also extraction properties of compound 4 towards some metal cations have been described. It has been observed that compound 4 has a good selectivity for metal cations Fe3+, Cu2+, Pb2+ and Cd2+ against Ni2+ and Co2+. 相似文献
52.
Zohreh Derikvand Gholam Reza Talei Hossein Aghabozorg Marilyn M. Olmstead Azadeh Azadbakht Andya Nemati Jafar Attar Gharamaleki 《中国化学》2010,28(11):2167-2173
A mononuclear Cu(II) complex with mixed ligands, formulated as [Cu(hypydc)(dmp)]·H2O (hypydc=4‐hydroxypyridine‐2,6‐dicarboxylate, dmp=2,9‐dimethyl‐1,10‐phenanthroline), was synthesized and well characterized by single crystal X‐ray diffraction analysis, as well as spectroscopic (IR, UV‐Vis), and electrochemical methods. The Cu(II) atom exhibits a distorted square‐pyramidal geometry. Intermolecular O? H···O and C? H···O hydrogen bonds, π‐π stacking interactions and C? H···π interactions seem to be effective in the stabilization of the crystal structure. The complex was also evaluated for its antimicrobial activity using in vitro microdilution methods. Six standard bacteria and a strain of Candida albicans were used for the antimicrobial activities. There was a very strong activity against Candida albicans and significant activities against Enterococcus fecalis, Listeria monocytogenes, Bacillus cereus and Staphylococcus aureus, indicating important biological activities of the complex. 相似文献
53.
The one-pot synthesis of 2,3-dihydro-1,5-benzodiazepins-2-one bearing phosphanylidene (ylide) or phosphono-succinate substituent is described. In this four-component reaction, benzodiazepine derived from condensation of o-phenylenediamine and diketene is trapped with the trialkyl phosphite-dialkyl acetylenedicarboxylate zwitterion. In the presence of H2O, the ylide functional group is hydrolyzed to the corresponding phosphonate. The configuration of the products is selective and only one of the two possible rotamers or diastereomers is formed exclusively in high yield. 相似文献
54.
55.
Payman Hashemi Zohreh Rahmani Ali Kakanejadifard Esmaiil Niknam 《Analytical sciences》2005,21(11):1297-1301
Fast-flow spherical homogeneous agarose beads were prepared by an emulsification method, and were cross-linked and activated by repeated treatment with allylbromide and bromine/water, followed by alkali. Bis(2-aminopyridyl)dioxime (APD) was synthesized by the reaction of 2-aminopyridine, and dichloroglyoxime and characterized by melting-point as well as IR, 1HNMR, 13CNMR and MS spectroscopies. APD was chemically linked to activated agarose beads to be employed for the column preconcentration of metal ions. Capacity measurements for eight metal ions indicated a high selectivity of the adsorbent towards Cu2+ with a capacity of 25.7 micromol per ml packed adsorbent. A factorial design was used for optimization of the effects of 5 different variables on the recovery of Cu2+. Under the optimized conditions, Cu2+ was quantitatively accumulated on a 0.25 ml packed column of the adsorbent in the pH range of 4 to 6, and simply eluted with 2 ml of a 1 mol 1(-1) hydrochloric acid solution. The column could tolerate salt concentrations up to 0.5 mol 1(-1), sample flow rates up to 15 ml min(-1), and sample volumes beyond 1000 ml. Matrix ions of Na+, Mg2+ and Ca2+ and potentially interfering ions of Ni2+, Cd2+, Zn2+, Fe3+ and Co2+ with relatively high concentrations did not show any significant effect on the analyte's signal. Preconcentration factors up to 500 and a detection limit of 0.16 microg 1(-1) were obtained for the determination of the analyte by flame AAS. Application of the method to the determination of natural and spiked copper in river water and seawater samples resulted in quantitative recoveries. 相似文献
56.
A convenient and rapid method for the electrophilic substitution reaction of indoles with carbonyl compounds has been developed by using deep eutectic solvent as green and reusable catalysts to afford the corresponding bis(indolyl) methanes in excellent yields at room temperature under mild reaction conditions. 相似文献
57.
Silas R. Beane Zohreh Davoudi Martin J. Savage 《The European Physical Journal A - Hadrons and Nuclei》2014,50(9):1-9
The level scheme above the proton threshold in 26Si is crucial for evaluating the 25Al(p, γ)26Si stellar reaction, which is important for understanding the astrophysical origin of the long-lived cosmic radioactivity 26Al(T 1/2 = 7.17 × 105 y) in the Galaxy. The excited states in 26Si have been studied using an in-beam γ-ray spectroscopy technique with the 24Mg(3He, nγ)26Si reaction. γ-rays with energies up to 4.6 MeV emitted from excited states in 26Si have been measured using large volume HPGe detectors. The spin-parity of one of the most important states reported recently at 5890.0keV has been assigned as 0+ by γ-γ angular correlation measurements in this work. 相似文献
58.
A novel, facile and inexpensive solid phase extraction (SPE) method using ethylene glycol bis-mercaptoacetate modified 3-(trimethoxysilyl)-1-propanethiol grafted Fe3O4 nanoparticles coupled with spectrofluorimetric detection was proposed for determination of aflatoxin M1 (AFM1) in liquid milk samples. The method uses the advantage fluorescence enhancement by β-cyclodexterin complexation of AFM1 in 12% (v/v) acetonitrile–water and the remarkable properties of Fe3O4 nanoparticles namely high surface area and strong magnetization were utilized to achieve high enrichment factor (57) and satisfactory extraction recoveries (91–102%) using only 100 mg of magnetic adsorbent. Furthermore, fast separation time of about 15 min avoids many time-consuming column-passing procedures of conventional SPE. The main factors affecting extraction efficiency including pH value, desorption conditions, extraction/desorption time, sample volume, and adsorbent amount were evaluated and optimized. Under the optimal conditions, a wide linear range of 0.04–8 ng mL−1 with a low detection limit of 0.015 ng mL−1 was obtained. The developed method was applied for extraction and preconcentration of AFM1 in three commercially available milk samples and the results were compared with the official AOAC method. 相似文献
59.
A novel mixed-ligand zinc(II) coordination polymer, {[Zn(μ-4,4'-bipy)(μ-3-bpdh)(H(2)O)(2)](ClO(4))(2)·(4,4'-bipy)(0.5)}(n) (1); 3-bpdh=2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene and 4,4'-bipy=4,4'-bipyridine, has been synthesized and characterized by IR, (1)HNMR and (13)CNMR spectroscopy. The single crystal X-ray data of compound 1 shows that this coordination polymer grows in two dimensions by two different bridging ligands, 4,4'-bipy and 3-bpdh. Also, nano-scale of compound 1 has been synthesized by sonochemical method and characterized by IR, X-ray diffraction (XRD) and scanning electron microscopy (SEM). Thermal stability of compound 1 in single crystalline and nano-scale form was carried out by thermal gravimetric (TG) and differential thermal analysis (DTA). The ZnO nanoparticles were obtained by calcination of compound 1 at 500°C under air atmosphere and by thermolyses in oleic acid at 200°C. The zinc(II) oxide nanoparticles were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). 相似文献
60.
Lia ZAHARANI Nader GHAFFARI KHALIGH Zohreh SHAHNAVAZ Mohd RAFIE JOHAN 《Turkish Journal of Chemistry》2020,44(2):535
In the current protocol, the arene diazonium saccharin derivatives were initially produced from various substituted aromatic amines; subsequently, these intermediates were treated with a greener organic iodide for the preparation of the aryl iodide. We tried to choose low-cost, commercially available, biodegradable, recoverable, ecofriendly, and safe reagents and solvents. The arene diazonium saccharin intermediates could be stored in the liquid phase into a refrigerator for a long time with no significant loss activity. The outstanding merits of the current protocol (a) included the partial recovering of saccharin and tetraethylammonium salt, (b) reduce the use of solvents and the reaction steps due to eliminating separation and purification of intermediates, (c) good yield of the sterically hindered substrates, and (d) avoid the generation of heavy metal or corrosive waste. 相似文献