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151.
Structural transformations induced in gamma and alpha globulins under influence of gamma irradiation using doses of 2.5 and
24 kGy were studied by differential scanning calorimetry (DSC) and thermogravimetry (TG, DTG). Thermal decomposition of the
globulins irradiated in water suspensions occurs at higher temperatures, in comparison to the reference non-irradiated samples.
This was related to formation of covalent linkages in the irradiated proteins, apart to chemical changes induced in amino-acids.
Essential modification of thermal decomposition was detected already after irradiation with a dose of 2.5 kGy performed for
water suspensions. Irradiation of solid native proteins induces decrease in decomposition temperature and gives evidence of
proteins degradation. 相似文献
152.
153.
Density functional theory (DFT) calculations show that in vacuum such α-diketone as 1-(pyridin-2-yl)-4-(quinolin-2-yl)butane-2,3-dione
is much less stable than its enolimine–enaminone ((1Z,3Z)-3-hydroxy-4-(pyridin-2-yl)-1-(quinolin-2(1H)-ylidene)but-3-en-2-one) and dienaminone tautomers ((1Z,3Z)-1-(pyridin-2-yl)-4-(quinolin-2-yl)buta-1,3-diene-2,3-diol). Other its tautomers (multiple basic and acidic centers in their
molecules enable multiple proton transfer to take place) are even more labile. Strength of the intramolecular hydrogen bonds
and aromatic character of the (quasi)rings [proved by the Harmonic Oscillator Model of Aromaticity (HOMA) index] in their
molecules were found to be responsible for the observed tautomeric preferences. Polar and basic solvent disfavors and favors
the enolimine and enaminone tautomers, respectively. 相似文献
154.
Anna Śmiechowska Witold Przychodzeń Jarosław Chojnacki Piotr Bruździak Jacek Namieśnik Agnieszka Bartoszek 《Structural chemistry》2010,21(5):955-964
Adducts of natural allyl, phenethyl, and benzyl isothiocyanates and 2-amino-1-methylbenzimidazole were synthesized. After
optimization of the reaction conditions, the target 2-benzimidazolylthioureas were obtained in reasonable yields. The detailed
molecular and crystal structures of these compounds were characterized by spectroscopic and X-ray methods. Spectral analysis
demonstrated that N-(1-methylbenzimidazolyl)-N′-allylthiourea, N-(1-methylbenzimidazolyl)-N′-benzylthiourea, and N-(1-methylbenzimidazolyl)-N′-phenethylthiourea exist in solution in an unprecedented three tautomeric forms, whose structures were corroborated unambiguously. 相似文献
155.
DFT studies on tautomeric preferences. Part 3: Proton transfer in 2-(8-acylquinolin-2-yl)-1,3-diones
8-Acetyl- and 8-benzoyl-2-(quinolin-2-yl) derivatives of 1,3-diketones were studied from point of view of their tautomeric
preferences. Effective electron delocalization and strong hydrogen bonds were found to be responsible for high stability of
the enaminone form (the most stable tautomer). Density functional theory (DFT) calculations prove that enolimine and ketimine
species are less favored. Contribution of the zwitterionic resonance structures to the enaminone form is most significant
in 2-(quinolin-2(1H)-ylidene)-2H-indene-1,3-dione derivatives. Formation of the bifurcated hydrogen bonds was found to take place only in 8-acetyl derivatives.
One of these bonds is of the RAHB (Resonance Assisted Hydrogen Bond) type. There is a steric interaction of the pyridine β-hydrogen
and carbonyl oxygen atoms in the enaminone tautomers. 相似文献
156.
Agnieszka Zgoła-Grześkowiak 《Journal of chromatography. A》2010,1217(11):1761-1766
Dispersive liquid–liquid microextraction (DLLME) coupled with high-performance liquid chromatography with fluorescence detector was applied for the determination of alkylphenols and their short-chained ethoxylates in water samples. Development of DLLME procedure included optimisation of some important parameters such as kind and volume of extracting and dispersing solvents. Under optimised conditions 50 μL of trichloroethylene in 1.5 mL of acetone were rapidly injected into 5 mL of a water sample. After centrifuging the organic phase containing the analytes was taken for evaporation with a gentle nitrogen purge and reconstituted to 50 μL of acetonitrile. The aliquot of this solution was analysed with the use of HPLC. For octylphenol (OP) and octylphenol ethoxylates (OPEOs) linearity was satisfactory in the range 8–1000 μg L−1 and for nonylphenol (NP) and nonylphenol ethoxylates (NPEOs) linearity was in the range from 50 to about 3000 μg L−1. Limit of quantitation was 0.1 μg L−1 for OP and OPEOs and 0.3 μg L−1 for NP and NPEOs. Satisfactory recoveries between 66 and 79% were obtained for environmental samples. The results showed that DLLME is a simple, rapid and sensitive analytical method for the preconcentration of trace amounts of alkylphenols and their ethoxylates in environmental water samples. 相似文献
157.
Zofia?Krystyna?DrzazgaEmail author Karina?Maciejewska Katarzyna?Michalik Micha??Kaszuba Barbara?Nowińska 《Journal of fluorescence》2011,21(3):883-886
The influence of antiretroviral drug zidovudine treatment during pregnancy on mandible development in newborn rats was studied. The fluorescence of mandibles from 7-, 14-
and 28-days old individuals was measured by means of fiber-optical fluorescence analyzer with 407 nm laser excitation. Obtained
results revealed disturbing effect of maternal zidovudine administration on mandible fluorescence intensity which should decrease with bone development. Small changes in fluorescence
of porphyrin forms are maintaining in the first month of newborns life while the changes observed in 440–585 nm range disappear. 相似文献
158.
M. Wośko B. Paszkiewicz K. Tarnowski B. Ściana D. Radziewicz W. Salejda R. Paszkiewicz M. Tłaczała 《Opto-Electronics Review》2011,19(4):418-424
The paper presents the application of non-modulation reflectance method for composition profiling of epitaxial AlxGa−xAs/GaAs structures. This non-destructive method is based on spectral measurements and theoretical reflectance spectrum matching.
This is a very accurate and sensitive method of determining the Al composition in AlxGa1−xAs layers and structures with resolution down to 1 nm. In this work, the authors describe theoretic principles of this method
and present experimental results of characterization of different AlGaAs structures to prove the potential of the worked out
method. 相似文献
159.
160.
Anna Jaśkiewicz Janusz Matkowski Andrzej S. Nowak 《Annals of Operations Research》2014,220(1):263-278
This paper generalizes the classical discounted utility model introduced in Samuelson (Rev. Econ. Stud. 4:155–161, 1937) by replacing a constant discount rate with a function. The existence of recursive utilities and their constructions are based on Matkowski’s extension of the Banach Contraction Principle. The derived utilities go beyond the class of recursive utilities studied in the literature and enable a discussion on subtle issues concerning time preferences in the theory of finance, economics or psychology. Moreover, our main results are applied to the theory of optimal economic growth related with resource extraction models with unbounded utility function of consumption. 相似文献