(Eu2+,Nd3+)∶CaAl2O4的长余辉发光及机理的研究

采用高温固相反应法制备了Eu^2 ∶CaAl2O4、（Eu^2 ,Nd^3 )∶CaAl2O4，等系列材料。测量了其激发、发射光谱及余辉衰减曲线。分析了掺杂稀土离子对长余辉发光的作用。并对其发光机理进行了深入地探讨。     

Polymers in Waveguide Packaging

Polymers were successfully used in the packaging of waveguide-based photonic components in the area of fiber-to-waveguide coupling, waveguide die attachment, strain relief, and waveguide encapsulation. The application results of these polymers were described in this paper.     

Synthesis of high-temperature resistant monolithic zirconia-based aerogel via facile water glass assisted sol–gel method

Zirconia aerogel monolith was prepared by a facile co-hydrolysis method, which adopts ZrOCl₂ as the precursor and water glass (Na₂SiO₃) as the gel initiator. ZrO₂ aerogel was formed by rational controlling of the hydrolysis rate of Zr⁴⁺ ions by Na₂SiO₃. The obtained aerogel consists of ZrO₂ nanoparticles surrounded by amorphous SiO₂ nano shell. The density and the surface area can be well tuned by adjusting the ratio of ZrOCl₂ to Na₂SiO₃. The in-situ introduced SiO₂ nano shell layer acts as the particle boundary reinforcement phase, which not only strengths the ZrO₂ particle connections to form monolith, but also significantly mitigates the sintering of ZrO₂ nanoparticles at high temperature. As a result, the zirconia aerogel prepared by such method could maintain its nanoporous microstructure up to 1000?°C.

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AN INVESTIGATION ON THE LOW TEMPERATURE RELAXATION OF POLYETHERETHERKETONE

The temperature spectra of internal friction of polyetheretherketone (PEEK) are investigated from 130K to 250K with a multi-function torsion pendulum in the frequency range of 0.1 Hz to 5 Hz. A relaxation process, γrelaxation, appears in the temperature range of the measurement. Its relaxation time distribution in terms of a Gaussian distribution, and the relation between molecular motion mechanism and the distribution characteristic are discussed. The element process of γrelaxation is found to be a disordering one.     

Molecular mechanics study on conformation of perylene-quinonoid photosensitizers

Using molecular mechanics method,values of the heat of formation (HF) of different conformations,of perylenequinonoid photosensitizes hypocrellin A (HA) and hypocrellin B (HB) were calculated and the variance of HF after phenolic protons' dissociation were calculated as well The following was found:(i) The HF values of lour conformational isomers of HA and HB are similar to each other,so the four isomcrs can transform to each other room temperature,(ii) There exists the difference between the ability of dissociation of phenolic protons of HA and that of HB,the former is higher than the latter (iii) There exist two intramolecular hydrogen bonds in HA and HB The bond energy is approximately 8 kJ/mol and the energy of conformation Ⅰ is lower than that of conformationⅡ The bond energy of HA is lower than that of HB.(iv) There exists a low energy snot when phenolic hydroxyl bond twists 180° from the position where hydrogen bond is formed,which suggests that this kind of conformation probably exists,(v) Th     

Catalytic Oxidation of Ethyl Lactate to Ethyl Pyruvate over Au-Based Catalyst Using Authentic Air as Oxidant

Highly dispersed Au nanoparticles supported on Ni–Al mixed metal oxides (Au/NiAl-MMO) were prepared by a facile method, which is significantly efficient for the aerobic oxidation of ethyl lactate using authentic air as the oxidant, achieving 72.6% ethyl lactate conversion and 88.3% selectivity to ethyl pyruvate at 240 °C in a continuous fixed-bed reactor. The catalyst retained its catalytic performance during a long-term stability test. Characterization and experimental studies on the kinetic dependence sequence of the reactants and elementary reaction steps confirmed that the Au/NiAl-MMO catalyst followed the Mars–van Krevelen mechanism, with the activation of O₂ as the elementary step. The quasi in situ X-ray photoelectron spectroscopy spectra demonstrated that the active sites in the Au/NiAl-MMO catalyst were Au nanoparticles. This work may provide a novel technique for developing more efficient supported metal catalysts for the aerobic oxidation of ethyl lactate using authentic air as the oxidant.

Graphical abstract

Highly dispersed Au nanoparticle catalyst was facilely prepared for the efficient catalytic oxidation of ethyl lactate with authentic air.

     

以二甲基硅二苯基硅共聚物引发苯乙烯光聚合的研究

本文研究了二甲基硅二苯基硅共聚物(P(DMS-co-DPS))作为光敏引发剂,引发苯乙烯进行光聚合的过程。结果表明,聚合为自由基引发的链式反应,聚合速率与P(DMS-co-DPS)浓度的0.37次方成正比;本体聚合活化能为30.6KJ/mol,氧气对聚合无明显影响。     

基于改进DeepLabv3+的无人车夜间红外图像语义分割

为了增强无人车对夜间场景的理解能力，针对无人车在夜间获取的红外图像，提出了一种基于改进DeepLabv3+网络的无人车夜间红外图像语义分割算法。由于自动驾驶场景中的对象往往显示出非常大的尺度变化，该算法在DeepLabv3+网络的基础上，通过引入密集连接的空洞卷积空间金字塔模块，使网络生成的多尺度特征能覆盖更大的尺度范围。此外，该算法将编码器模块的多层结果拼接在译码器模块中，以恢复更多在降采样过程中丢失的空间信息和低级特征。通过端到端的学习和训练，可直接用于对夜间红外图像的语义分割。实验结果表明，该算法在红外数据集上的分割精度优于原DeepLabv3+算法，平均交并比达到80.42，具有良好的实时性和准确性。     

Polymorph selection of magnesium under different pressures: A simulation study

Molecular dynamics simulations were used to investigate the influence of pressure on the structural properties and dynamics of magnesium(Mg)during rapid solidification.The dynamics analysis revealed that,with an increase in pressure,the dynamics of Mg melt slowed down sharply and the dynamical heterogeneities increased,leading to a denser structure.Atom-level structural analysis using the cluster-type index method suggested that the predominant structure transformed from hexagonal closed-packed to face-centered cubic with increasing pressure from 0 GPa to 5 GPa,and then transformed to the A15 complex crystal structure as the pressure increased above 10 GPa.In addition,the nature of polymorph selection was investigated by analyzing the phonon dispersion of Mg under different pressures.These findings provide a novel insight into polymorphic transitions of Mg under pressure and guide the selection of Mg polymorphs for practical applications.