Transient and Persistent Room‐Temperature Mechanoluminescence from a White‐Light‐Emitting AIEgen with Tricolor Emission Switching Triggered by Light

Persistent luminescence from purely organic materials is basically triggered by light and electricity, which largely confines its practical applications. A purely organic AIEgen exhibits not only persistent photoluminescence, but also transient and persistent room‐temperature mechanoluminescence. By simply turning on and off a UV lamp, tricolor emission switching between blue, white, and yellow was achieved. The data from single‐crystal structure analysis and theoretical calculation suggest that mechanism of the observed persistent mechanoluminescence (pML) is correlated with the strong spin–orbit coupling of the bromine atom, as well as the formation of H‐aggregates and restriction of intramolecular motions in noncentrosymmetric crystal structure. These results outline a fundamental principle for the development of new pML materials, providing an important step forward in expanding the application scope of persistent luminescence.     

Improving Low-temperature Performance and Stability of Na2Ti6O13 Anodes by the Ti−O Spring Effect through Nb-doping

Na₂Ti₆O₁₃ (NTO) with high safety has been regarded as a promising anode candidate for sodium-ion batteries. In the present study, integrated modification of migration channels broadening, charge density re-distribution, and oxygen vacancies regulation are realized in case of Nb-doping and have obtained significantly enhanced cycling performance with 92 % reversible capacity retained after 3000 cycles at 3000 mA g⁻¹. Moreover, unexpected low-temperature performance with a high discharge capacity of 143 mAh g⁻¹ at 100 mA g⁻¹ under −15 °C is also achieved in the full cell. Theoretical investigation suggests that Nb preferentially replaces Ti3 sites, which effectively improves structural stability and lowers the diffusion energy barrier. What's more important, both the in situ X-ray diffraction (XRD) and in situ Raman furtherly confirm the robust spring effect of the Ti−O bond, making special charge compensation mechanism and respective regulation strategy to conquer the sluggish transport kinetics and low conductivity, which plays a key role in promoting electrochemical performance.     

Qualitative identification and quantitative comparison of Physochlainae Radix from different regions based on chemometric methods

Physochlainae Radix (PR) is an essential herbal medicine that has been generally applied for treating cough and asthma. In this study, a comprehensive strategy for quality evaluation of PR from different origins was established by integrating qualitative identification, quantitative analysis, and chemometric methods. A total of 58 chemical components were identified by ultra-high-performance liquid chromatography coupled with quadrupole time-of-flight tandem mass spectrometry (UHPLC-Q-TOF-MS/MS), and a sensitive and rapid UHPLC-QqQ-MS/MS method was established for the simultaneous determination of 12 compounds. In addition, multivariate statistical analysis was applied for discriminant analysis to compare the differences among 30 batches of PR samples. The results showed that the 30 batches of PR collected from four provinces could be clustered into three categories, in which scoparone, protocatechuic acid, tropic acid, and scopolin were important components to distinguish the primary and non-primary producing areas, as well as superior and inferior products of PR. Chemometric results were consistent and validated each other, and systematically explained the intrinsic quality characteristics of PR. This study first demonstrated that LC-MS combined with multivariate statistical analysis, provided a comprehensive and effective means for quality evaluation of PR.     

硅烷化活性炭的吸附性质

本工作测定了25℃和35℃时硅烷化活性炭自水溶液中吸附苯甲酸和苯甲醛的等温线;计算了吸附过程的ΔGⅲ,ΔHⅲ和ΔSⅲ;用Hill-deBoer方程处理了实验结果。所得结果表明:(1)随硅烷化时间延长,苯甲酸和苯甲醛的吸附量(mol.m^-^2)明显增加;-ΔGⅲ和-ΔHⅲ略有升高,ΔSⅲ为正值;(2)吸附分子之间的相互作用很弱,吸附分子与活性炭表面间的作用随硅烷化程度增加而加大;(3)芳香化合物可能是以苯环吸附在炭表面上的。     

混凝土箱梁相似模型结构噪声对比分析*

为探讨混凝土箱梁噪声的时变特性,以京沪高铁32 m混凝土简支箱梁为原型,制作了1:10的缩尺模型,通过模态试验的方法验证箱梁模型与原型的相似关系,通过声学试验验证箱梁声学计算模型的正确性。然后,建立了箱梁缩尺模型与原型两种计算模型,利用有限元和边界元法求出两种模型的瞬态结构噪声。研究发现,箱梁缩尺模型与箱梁原型的材料参数满足一定关系,模型试验的方法能够验证箱梁模型与箱梁原型之间符合相似关系,箱梁模型的振动噪声测试结果能真实反映原型振动噪声水平。两种模型的结构噪声在时域内声压级及对应场点的声压存在一定相似关系。该研究可为箱梁缩尺模型结构噪声反演至箱梁原型提供依据,所采用的方法和得到的结果对桥梁结构振动与声辐射实验研究具有参考作用。     

一种新的白光光纤传感系统波长解调方法

提出了一种新的白光非本征法布里-珀罗干涉（EFPI）光纤传感系统的干涉谱处理方法,在白光法布里-珀罗干涉光纤传感系统中,一个中心波长为850nm的发光二极管（LED）作为宽谱光源,HR2000高分辨力微型光谱仪用来测量返回的干涉光谱。通过跟踪干涉光谱中的特定谱峰点,法布里-珀罗干涉传感器的腔长值可以被解调出来。应用反向传播神经网络,解决了单峰测量方式的级次模糊问题。反向传播神经网络能够分辨出干涉谱中不同谱峰的干涉级次,因而可以进行多个谱峰的连续跟踪。从而实现了高精密度、大动态范围的测量。进行了基于这种干涉谱处理方法的白光法布里-珀罗干涉传感系统的应变测量实验。利用该传感系统实现了精密度达0．1με,500με范围的应变测量。     

具有聚集诱导发光效应的咔唑基三苯乙烯衍生物单体及聚合物

合成了一类新的咔唑基三苯乙烯衍生物单体及其聚合物.利用示差扫描量热法(DSC)、热重分析法(TGA)、紫外可见分光光度法和荧光分光光度法等对单体和聚合物的性能进行了初步的表征.实验结果表明,该单体和聚合物具有较高的玻璃化转变温度(Tg),分别为210℃和229℃;单体和聚合物均具有很高的热稳定性,热失重5%的温度分别为466℃和467℃;单体具有明显的聚集诱导发光性能(AIE),而聚合物则具有聚集诱导增强发光性能(AIEE);所合成的单体和聚合物有望在OLED器件以及化学传感器上得到应用.     

纺织品中pH值的测定能力验证

为了了解国内纺织品检测机构对纺织品中pH值测定领域的整体水平,识别和掌握实验室存在的差异,加强纺织品检测机构的实验室能力建设,中国国家认证认可监督管理委员会(CNCA)组织了纺织品中pH值的测定能力验证活动,有16个省、市、直辖市的69个实验室参加,测试结果满意的实验室占78.26%.     

Positive solutions for higher order nonlinear neutral dynamic equations on time scales

In this paper, we consider higher order nonlinear neutral dynamic equations on time scales. Some sufficient conditions are obtained for existence of positive solutions for the higher order equations by using the fixed point theory and defining the compressed map on a set.