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41.
42.
Zdzisław Gałdecki Andrzej Fruziński Osman Achmatowicz Barbara Szechner Ewa Gałdecka 《Journal of chemical crystallography》1996,26(11):769-775
Methyl 6-(N-benzenesulfonylamino)-N,O-isopropylidene-2,3,6,8-tetradeoxy--d-erythrooct-2-enopyranos-4-uloside, C18H23N1O6S1, (3) crystallizes in the orthorhombic space groupP212121. The unit cell parameters are:a=7.839(2),b=10.111(2),c=24.217(5) Å. The dihydropyranone ring adopts a deformed sofa conformation with the O5 atom deviating 0.586(2) Å from the least-squares plane and the -face of the carbonyl group shielded by the terminal (C8) methyl group. 1,1-O,O-Ethylidene-3,4-dideoxy-d,l-hex-3-enoz-2-ulopyranos-5-ulose, C8H10O5, (6) crystallizes in the monoclinic space groupP21/n. The unit cell parameters are:a=6.310(1),b=18.656(3),c=7.604(1) Å, =106.01(1)°. The dihydropyranone ring adopts a deformed sofa conformation with O6 atom deviating 0.482(1) Å from the leastsquares plane and the hydroxy and dioxolanyl substituents are in pseudoaxial and pseudoequatorial positions, respectively. The average planes of six-membered and five-membered rings are approximately coplanar. 相似文献
43.
Zdzisłew Gałecki Paweł Grochulski Zdzisław Wawrzak Andrzej Szyczewski 《Journal of chemical crystallography》1990,20(2):179-185
The crystal structure of 4-thioethyl-4-cholesten-3-one, C29H48OS, has been determined by X-ray methods. The compound is orthorhombic:P212121,a=7.787(2),b=12.586(4),c=27.960(6) Å,V=2740(3) Å3,M
r
=444.8,Z=4,D
x
=1.08 Mg m–3, CuK radiation (=1.5418 Å),=11.2 cm–1,F(000)=984. FinalR=0.073 andR
w
=0.057 for 1562 reflections. A comparison with other 4-substituted 4-en-3-ore steroids suggests that theA ring conformation and its relative orientation can be influenced by the thioethyl substituent. The C4 side chain is turned under the steroid skeleton. The cholesterol side chain is fully extended, with atrans, +gauche conformation of the terminal C26 and C27 methyl groups. 相似文献
44.
Zdzisław Gałdecki Bernard Luciak Adam S. Redliński Krzysztof Kaczmarek Mirosław T. Leplawy 《Monatshefte für Chemie / Chemical Monthly》1991,122(1-2):37-42
Summary The synthesis and the crystal structure of N2-dibenzyl-N1-butoxycarbonyl hydrazine are reported. The compound was prepared from commercially availablet-butyl carbazate. It crystallizes in the triclinic space group P 1 witha=5.479(1) Å,b=9.559(1) Å,c=9.748(1) Å,a=63.81(1)°, =87.52(1)°, =74.07(1) Å,Z=1,D=1.18 g/cm3. The structure was solved by direct methods and refined toR=0.0329. 相似文献
45.
The initiating ability of 2-cyano-2-propyl hydroperoxide in the oxidation reaction of cumene by molecular oxygen has been investigated and compared with the initiating ability of cumene hydroperoxide.
Die Initiierungseigenschaften von 2-Cyano-2-propyl-hydroperoxid bei Oxydations-prozessen
Zusammenfassung Es wurde die Initiierungsfähigkeit des 2-Cyan-2-hydroperoxypropans in der Oxidation von Cumol mit molekularem Sauerstoff untersucht und mit der Initiierungsfähigkeit des Cumolhydroperoxids verglichen.相似文献
46.
Interaction energies of a proton and lithium cation with NH3, OH2, and HF axe computed at the SCF and Møller-Plesset levels. It is found that the basis set superposition errors at all levels with the 6-3 1G** basis set may be greatly reduced by including an additional diffuse sp shell on first-row atoms; the exponent of this shell has been optimized to 0.1. 相似文献
47.
Roman Joachimiak Zdzisław Paryzek 《Journal of inclusion phenomena and macrocyclic chemistry》2004,49(1-2):127-132
The synthesis and NMR spectra of steroid dimers being derivatives of cholic and lithocholic acid methyl esters, in which the steroid residues are linked by the terephthaloyl spacer, are described. The complexing ability of the dimers towards alkaline metal cations has been studied by the electrospray mass spectrometry. Cholic acid derivatives show affinity toward metal cations and anions. Binding of metal cations by methyl lithocholate dimer has not been detected. 相似文献
48.
A method for the photometric determination of platinum(IV), palladium(II) and osmium(VIII) with 5-mercapto-thiadiazolidine-thione-2 is described. The effects of an excess of reagent, of time, pH and of diverse ions were studied. The optimum concentration range for the method is 10 to 100 Μg of Pt(IV), Pd(II) and Os(VIII). 相似文献
49.
50.