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91.
A domino reaction that is pericyclic in nature is thought to be triggered upon treatment of alkenynol 10 with arylsulfenyl chlorides. The process comprises an ordered sequence of sigmatropic rearrangements: a reversible [2,3]-allyl sulfenate to allyl sulfoxide shift, followed by a [2,3]-propargyl sulfenate to allenyl sulfoxide rearrangement, and last a stereodifferentiating [1,5]-sigmatropic hydrogen migration leading to polyene 13. The occurrence of the C7 to C11 hydrogen migration has been demonstrated by labeling experiments. The double diastereoselection of the [1,5]-sigmatropic hydrogen shift to afford a single isomer of the final polyene 13 is thought to arise from a combination of the electronic effect of the sulfoxide at one terminus, and the steric effect imparted by the bulky trimethylcyclohexenyl substituent at the other terminus. The overall process thus constitutes a stereoselective synthesis of an E,Z,Z-triene fragment from an alkenynol and, in particular, a retinoid with the 7E,9Z,11Z,13E configuration on the conjugated polyenic side chain. Application of this method to the synthesis of retinoids, including labeled analogues, is straightforward. 相似文献
92.
考虑碳排放税,建立双寡头制造商分别实施废品回收和绿色低碳广告投入策略的动态博弈模型。通过系统稳定域,分岔图,功率谱等分析了博弈模型纳什均衡解处的稳定性及参数对系统稳定域的影响,同时对系统的复杂性特征进行了研究。结果表明,消费者回收价格敏感性增加会使整个系统稳定域缩小,而绿色低碳广告投入水平增加只会使实施该策略的企业自身稳定域扩大;当制造商价格调整速度过快时,系统会进入混沌状态;混沌状态下,对比实施广告策略的制造商,实施废品回收策略的制造商价格调整行为对市场造成的震荡更大。最后使用反馈控制策略对系统混沌状态进行了有效的控制,研究结果对制造商低碳策略选择及价格决策有着较好的借鉴意义。 相似文献
93.
Calderbank AR; Cameron PJ; Kantor WM; Seidel JJ 《Proceedings London Mathematical Society》1997,75(2):436-480
When m is odd, spreads in an orthogonal vector space of type+(2m + 2,2) are related to binary Kerdock codes and extremalline-sets in 2m + 1 with prescribed angles. Spreads in a 2m-dimensionalbinary symplectic vector space are related to Kerdock codesover Z4 and extremal line-sets in with prescribed angles. These connections involve binary, realand complex geometry associated with extraspecial 2-groups.A geometric map from symplectic to orthogonal spreads is shownto induce the Gray map from a corresponding Z4-Kerdock codeto its binary image. These geometric considerations lead tothe construction, for any odd composite m, of large numbersof Z4-Kerdock codes. They also produce new Z4-linear Kerdockand Preparata codes. 1991 Mathematics Subject Classification:primary 94B60; secondary 51M15, 20C99. 相似文献
94.
95.
Solvent effects on the O NMR chemical shifts of 4-dimethylsulfoximide-1,1,1-trifluoro-3-alken-2-ones
Helio G. Bonacorso Sandra R.T. Bittencourt Adilson P. Sinhorin Nilo Zanatta Marcos A.P. Martins 《Journal of fluorine chemistry》2003,121(2):135-139
A multi-linear-regression analysis using the Kamlet-Abbout-Taft (KAT) solvatochromic parameters in order to elucidate and quantify the solvent effects on the chemical shifts of three 4-dimethylsulfoximide-1,1,1-trifluoro-3-buten-2-ones is reported. The predominant conformational structures of compounds has been determined by energy minimization calculations using the Austin Model (AM1) semi-empirical method, which has been used to explain the NMR chemical shifts for CO and SO groups. The chemical shifts of carbonyl and sulfoximide oxygen’s of molecules showed similar dependencies (in ppm) on the solvent polarity-polarizability and the solvent hydrogen-bond-donor (HBD) acidities. The influence of solvent hydrogen-bond-acceptor (HBA) basicities was little significant. 相似文献
96.
Adriana Chilin Giovanni Marzaro Samuele Zanatta Adriano Guiotto 《Tetrahedron letters》2007,48(18):3229-3231
A rapid and efficient microwave-assisted protocol is described that greatly improves a recent synthetic method developed for quinazoline synthesis. The synthetic protocol is based on the use of cycles of microwave irradiation. The optimization process is reported and the experimental results are compared with those of the conventional synthetic route. 相似文献
97.
Adriana Chilin Giovanni Marzaro Samuele Zanatta Vera Barbieri Giovanni Pastorini Paolo Manzini Adriano Guiotto 《Tetrahedron》2006,62(52):12351-12356
A new synthetic pathway to quinazolines is described. This new method uses hexamethylenetetramine in TFA and potassium ferricyanide in aqueous ethanolic KOH, starting from simple N-protected anilines. The method affords substituted quinazolines with high selectivities and good yields, reducing reaction-time and work-up operations. 相似文献
98.
Marcos A.P Martins Claudio M.P PereiraPaulo Beck Pablo MachadoSidnei Moura Marcos V.M TeixeiraHelio G Bonacorso Nilo Zanatta 《Tetrahedron letters》2003,44(35):6669-6672
A series of five 5-trichloromethyl-1-phenyl-1H-pyrazoles and six 5-trichloromethyl-1,2-dimethylpyrazolium chlorides have been synthesized in 80-98% yield by environmentally benign microwave induced techniques involving the cyclocondensation of 4-alkoxy-1,1,1-trichloro-3-alken-2-ones [Cl3C(O)C(R2)=C(R1)OR, where R2=H, Me; R1=H, alkyl, phenyl and R=Me, Et] with phenyl hydrazine and 1,2-dimethylhydrazine dihydrochloride, respectively, using toluene as solvent. The use of microwave and classical methods are comparable for making pyrazoles, but the formation of pyrazolium chlorides can be achieved in a significant shorter time, and in some cases better yield. 相似文献
99.
Marcos A. P. Martins Claudio M. P. Pereira Sidnei Moura Clarissa P. Frizzo Paulo Beck Nilo Zanatta Helio G. Bonacorso Alex F. C. Flores 《Journal of heterocyclic chemistry》2007,44(5):1195-1199
The regiospecific synthesis of a series of twelve 5‐trifluoromethyl‐4,5‐dihydropyrazoles and ‐pyrazoles from the cyclocondesation reaction of 4‐alkoxy‐1,1,1‐trifluoro‐3‐alken‐2‐ones [F3CC(O)CH=C(R1)OR, where R1 = Me, Et, Pr, iso‐Pr, Bu, iso‐Bu, Ph, H; and R = Me, Et] with phenylhydrazine in toluene by environmentally benign microwave induced techniques is reported. It is shown that under appropriated conditions, the variation of microwave irradiation power leads to 4,5‐dihydropyrazole or pyrazole derivatives. This paper also includes the use of montmorillonite K‐10 as a solid support for the synthesis of pyrazoles under solvent free conditions. 相似文献
100.
Helio G. Bonacorso Rogério V. Lourega Fernando J. Righi Everton D. Deon Nilo Zanatta Marcos A. P. Martins 《Journal of heterocyclic chemistry》2008,45(6):1679-1686
The synthesis of a novel series of the intermediates N2(N3)‐[1‐alkyl(aryl/heteroaryl)‐3‐oxo‐4,4,4‐trifluoroalk‐1‐en‐1‐yl]‐2‐aminopyridines [F3CC(O)CH?CR1(2? NH?C5H3N)] and 2,3‐diaminopyridines [F3CC(O)CH?CR1(2‐NH2‐3‐NH? C5H3N)], where R1 = H, Me, C6H5, 4‐FC6H4, 4‐CIC6H4, 4‐BrC6H4, 4‐CH3C6H4, 4‐OCH3C6H4, 4,4′‐biphenyl, 1‐naphthyl, 2‐thienyl, 2‐furyl, is reported. The corresponding series of 2‐aryl(heteroaryl)‐4‐trifluoromethyl‐3H‐pyrido[2,3‐b][1,4]diazepin‐4‐ols obtained from intramolecular cyclization reaction of the respective trifluoroacetyl enamines or from the direct cyclocondensation reaction of 4‐methoxy‐1,1,1‐trifluoroalk‐3‐en‐2‐ones with 2,3‐diaminopyridine, under mild conditions, is also reported. 相似文献