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41.
Highly sulfated cyclosophoraoses (HS-Cys) were synthesized by the chemical modification of a family of neutral cyclosophoraoses isolated from Rhizobium leguminosarum bv. trifolii. The HS-Cys were then analytically characterized using Fourier transform-infrared spectroscopy and elemental analysis. These HS-Cys were successfully used as a novel chiral additive, in low-pH aqueous background electrolytes, for capillary electrophoretic separation of five basic chiral drugs such as arterenol, atenolol, isoproterenol, propranolol, and metoprolol. 相似文献
42.
In the reaction of paraoxon with alkali metal ethoxides, ion-paired EtO-M+ species are more reactive than the dissociated EtO- with the reactivity order EtO-Li+ EtO-Na+ > EtO-K+ > EtO-, while in the reaction of parathion, the reactivity follows the order EtO-K+ > EtO- > EtO-Na+ > EtO-Li+. 相似文献
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Jong-Moo Lee Yong-Soon Baek Kwang-Ryong Oh Hyung-Jong Lee Yong-Seok Kim 《Optics Communications》2007,270(2):189-194
We investigate on the variation of loss and temperature dependence of a polymeric arrayed waveguide grating (AWG) depending on its substrate, by fabricating 16-channel polymeric AWGs with various substrate conditions. Insertion loss for a polymeric AWG on a silicon substrate is measured as low as 3.1 dB. The temperature-dependent wavelength shift for a polymeric AWG detached from the substrate is maintained within 0.1 nm from 20 to 80 °C. But we observe a degradation of insertion loss and a little instability in wavelength characteristics both for the detached polymeric AWG and for a polymeric AWG on a polymer substrate. We investigate on those optical properties of the polymeric AWGs based on measured thermal expansion properties of the polymers. 相似文献
46.
Ki Wan Kim Seung Wook Baek 《Journal of Quantitative Spectroscopy & Radiative Transfer》2007,108(3):423-439
An inverse radiation problem was considered to estimate boundary conditions such as temperature distribution and emissivity in axisymmetric absorbing, emitting, and scattering medium, given the measured incident radiative heat fluxes. The finite-volume method was employed to solve a direct radiative transfer equation for a two-dimensional axisymmetric geometry. Various parameter estimators, such as conjugate-gradient method, hybrid genetic algorithm, and finite-difference Newton method, were employed to solve the inverse problems, while discussing their performances in terms of estimation accuracy and computational efficiency. Based on this, we proposed, as a best inverse analysis tool, a new combined method that adopted the hybrid genetic algorithm as an initial value selector and used the finite-difference Newton method as a parameter estimator. 相似文献
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Hyun‐Ji Kim Yun Jae Lee Seung Sang Hwang Dong Hoon Choi Hoichang Yang Kyung‐Youl Baek 《Journal of polymer science. Part A, Polymer chemistry》2011,49(19):4221-4226
Regioregular poly(3‐hexyl thiophene) (rr‐P3HT)‐based star polymers were synthesized by a crosslinking reaction of the linear rr‐P3HT macroinitiator and ethylene glycol dimethacrylate (EGDMA) crosslinker through Ru‐based atom transfer radical polymerization (ATRP), where the rr‐P3HT macroinitiator was prepared by Grignard metathesis method (GRIM) followed by end functionalization of the ATRP initiator with chlorophenylacetate (CPA) to the rr‐P3HT. Relatively high molecular weight of the star polymers were obtained (Mp = 8,988,000 g/mol), which consisted of large numbers of the rr‐P3HT arm chains radiating from the EGDMA‐based microgel core. The yield of the star polymers were strongly affected by the added amount of the EGDMA crosslinker. The crystalline structure of the rr‐P3HT by intermolecular π‐π stacking interaction gradually decreased as the star polymer formed, which was confirmed by differential scanning calorimeter (DSC), atomic force microscopy (AFM), and electro‐optical analyses. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
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Eun-Jung Lim Dae-Weon Park Jin-Gu Lee Chu-Hee Lee Yoe-Sik Bae Young-Chul Hwang Jae-Weon Jeong Byung-Rho Chin Suk-Hwan Baek 《Experimental & molecular medicine》2010,42(10):712-720
Synthetic oligodeoxynucleotides (ODN) with a CpG-motif are recognized by Toll-like receptor 9 (TLR9) and pleiotropic immune responses are elicited. Stimulation of macrophages with TLR9 agonist prevented apoptosis induced by serum deprivation through increased expression of FLICE-like inhibitory protein (FLIP). CpG ODN-mediated anti-apoptosis depended on the TLR9-Akt-FoxO3a signaling pathway. Inhibition of TLR9 by small interfering (si) RNA or an inhibitor suppressed CpG ODN-mediated anti-apoptosis. Analysis of signaling pathways revealed that the anti-apoptotic effect of CpG ODN required phosphorylation of FoxO3a and its translocation from the nucleus to the cytosol. Overexpression of FoxO3a increased apoptosis induced by serum deprivation and CpG ODN blocked these effects through FLIP expression. In contrast, siRNA knock-down of FoxO3a decreased apoptosis by serum deprivation. In addition, Akt activation was involved in CpG ODN-induced phosphorylation of FoxO3a, expression of FLIP, and anti-apoptosis. Taken together, these results demonstrate the involvement of Akt-FoxO3a in TLR9-mediated anti-apoptosis and indicate that FoxO3a is a distinct regulator for FLIP expression. 相似文献
50.
Seung Ki Baek 《Physica A》2008,387(14):3660-3668
We study human dynamics by analyzing Linux history files. The goodness-of-fit test shows that most of the collected datasets belong to the universality class suggested in the literature by a variable-length queuing process based on priority. In order to check the validity of this model, we design two tests based on mutual information between time intervals and a mathematical relationship known as the arcsine law. Since the previously suggested queuing process fails to pass these tests, the result suggests that the modelling of human dynamics should properly consider the statistical dependency in the temporal dimension. 相似文献