全文获取类型
收费全文 | 1065篇 |
免费 | 38篇 |
国内免费 | 5篇 |
专业分类
化学 | 881篇 |
晶体学 | 8篇 |
力学 | 19篇 |
数学 | 63篇 |
物理学 | 137篇 |
出版年
2023年 | 8篇 |
2022年 | 5篇 |
2021年 | 14篇 |
2020年 | 17篇 |
2019年 | 21篇 |
2018年 | 16篇 |
2017年 | 16篇 |
2016年 | 27篇 |
2015年 | 24篇 |
2014年 | 30篇 |
2013年 | 55篇 |
2012年 | 68篇 |
2011年 | 84篇 |
2010年 | 36篇 |
2009年 | 33篇 |
2008年 | 70篇 |
2007年 | 88篇 |
2006年 | 79篇 |
2005年 | 69篇 |
2004年 | 59篇 |
2003年 | 53篇 |
2002年 | 50篇 |
2001年 | 19篇 |
2000年 | 10篇 |
1999年 | 11篇 |
1998年 | 12篇 |
1997年 | 8篇 |
1996年 | 9篇 |
1995年 | 12篇 |
1994年 | 9篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 11篇 |
1979年 | 7篇 |
1978年 | 3篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1956年 | 1篇 |
排序方式: 共有1108条查询结果,搜索用时 265 毫秒
71.
Tomohiro Seki Chi Feng Kentaro Kashiyama Shunichi Sakamoto Yuichi Takasaki Toshiyuki Sasaki Satoshi Takamizawa Hajime Ito 《Angewandte Chemie (International ed. in English)》2020,59(23):8839-8843
Ferroelasticity has been reported for several types of molecular crystals, which show mechanical‐stress‐induced shape change under twinning and/or spontaneous formation of strain. Aiming to create materials that exhibit both ferroelasticity and light‐emission characteristics, we discovered the first examples of ferroelastic luminescent organometallic crystals. Crystals of arylgold(I)(N‐heterocyclic carbene)(NHC) complexes bend upon exposure to anisotropic mechanical stress. X‐ray diffraction analyses and stress‐strain measurements on these ferroelastic crystals confirmed typical ferroelastic behavior, mechanical twinning, and the spontaneous build‐up of strain. A comparison with single‐crystal structures of related gold‐NHC complexes that do not show ferroelasticity shed light on the structural origins of the ferroelastic behavior. 相似文献
72.
73.
Inside Cover: Enhancement of Light Absorption Ability of Synthetic Chlorophyll Derivatives by Conjugation with a Difluoroboron Diketonate Group (Chem. Eur. J. 29/2016) 下载免费PDF全文
74.
75.
76.
Jiro Tsuji Yuichi Kobayashi Hideaki Kataoka Takashi Takahashi 《Tetrahedron letters》1980,21(35):3393-3394
2-Substituted 2-alkoxycarbonyl-3-vinylcyclopentanones (2), easily prepared by the palladium-catalyzed cyclization of 2-substituted 3-oxo-8-phenoxy-6-octenoates (1), are very suitable building blocks for CD rings of steroids, bearing particularly a functionalized 18-methyl group. 相似文献
77.
A simple Raman probe was realized using a single flexible hollow waveguide (HW). A HW coated with a silver film, which had reasonable transmission and little optical background noise, was used as a bidirectional transmission fiber for both the excitation and collection of Raman scattered light. The HW itself generated no Raman scattering or fluorescence noise during transmission. A complex filtering system at the end of the waveguide was thus unnecessary. In addition, the measured Raman spectra showed better signal-to-noise ratios than a conventional Raman fiber probe. The HW's suitability as a Raman fiber probe was also demonstrated. 相似文献
78.
79.
Itaka K Kanayama N Nishiyama N Jang WD Yamasaki Y Nakamura K Kawaguchi H Kataoka K 《Journal of the American Chemical Society》2004,126(42):13612-13613
An siRNA nanocarrier formed through self-assembly of PEG-based block catiomer possessing two distinct amino groups with different pKa values in a side chain was developed. This design provided the carrier with a sufficient siRNA complexation and an assumed buffering capacity in the endosomes, allowing it to exhibit remarkable gene knockdown abilities as well as sufficient serum tolerability. 相似文献
80.
Haraguchi K Shiina N Yoshimura Y Shimada H Hashimoto K Tanaka H 《Organic letters》2004,6(16):2645-2648
2'-Beta-methyl- and 2'-beta-hydroxymethyl-2'-deoxy-4'-thionucleosides have been synthesized through PhSeCl-mediated electrophilic glycosidation using 4-thiofuranoid glycals having carbon substituents at the C2-position as a glycosyl donor. Preparation of these glycals were carried out by means of the C2 lithiation of 1-chloro-4-thiofuranoid glycal with LTMP followed by the Birch reduction of the chlorine atom. [reaction: see text] 相似文献