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101.
在水热晶化合成一系列NASICON型化合物的基础上,应用固体高分辨31P和29Si MAS NMR,研究了几种NASICON化合物的结构,观察其骨架原子P和Si在结构中的状态及分布,并解释了由于在结构中发生取代作用而引起,Si或P的化学位移的变化. 相似文献
102.
一类Narcissistic反应过渡态的优化 总被引:1,自引:0,他引:1
我们对一类narcissistic 反应XCH_2-CH_2Y→[过渡态TS]→YCH_2—CH_2X (1)进行了研究,结果表明其过渡态能在对称性限制下由能量极小化方法较容易地给出. 采用IMSPAK分子轨道从头算程序,在IBM VM/370计算机系统上用STO—3G极小基组以平衡几何构型的能量梯度优化方法,在对称性限制下对反应(1)的几种反应体系的过渡态构型进行了优化,其结果列于表1. 相似文献
103.
This paper presents an analysis of a portfolio model which can be used to assist a property-liability insurance company in determining the optimal composition of the insurance and investment portfolios. By introducing insurer's threshold risk and relaxing some non-realistic assumptions made in traditional chance constraint insurance and investment portfolio models, we propose a method for an insurer to maximize his return threshold for a given threshold risk level. This proposed model can be used to optimize the composition of underwriting and investment portfolios regarding the insurer's threshold risk level, as well as to generate the efficient frontier by adjusting insurer's threshold risk levels. A numerical example is given based on the industry's aggregated data for a sixteen year period. 相似文献
104.
Determination of the arc-root position in a DC plasma torch 总被引:4,自引:0,他引:4
Seungho Paik P. C. Huang J. Heberleinand E. Pfender 《Plasma Chemistry and Plasma Processing》1993,13(3):379-397
The behavior of an arc operated in the nontransferred mode with a conical-shaped cathode and a nozzle-shaped anode is studied by applying general tyro-dimensional conservation equations and auxiliary relations for the simulation of arc channel flows. The position of the arc-root attachment at the anode surface is determined by using Steenbeck's minimum principle, which postulates a minimum arc voltage for a given current and certain given boundary conditions. The overall effects of the anode-arc root on the plasma flow are, studied by comparing the results with those of the transferred mode of operation. Specific arc-channel diameters are chosen in the simulation in order to verify flit, numerical model through comparisons with experimental results. The results show that Steenbeck's minimum principle is useful for determining the position of the arc-root attachment at the anode surface. Application of this method for control of the arc-anode attachment may be valuable in the design and operation of plasma spray torches to avoid jet instabilities. 相似文献
105.
Jing-song Huang 《Mathematische Annalen》1993,297(1):309-324
Supported in part by NSF Grant DMS-8610730 相似文献
106.
采用固源Si分子束外延,在较高的生长温度于Si(100)衬底上制备出Si1-xGex/Si量子阱发光材料。发光样品的质量和特性通过卢瑟福背散射、X射线双晶衍射及光致发光评估。背散射实验中观察到应变超晶格的反常沟道效应;X射线分析表明材料的生长是共度的、无应力释放的,结晶完整性好。低温光致发光主要是外延合金量子阱中带边激子的无声发射和横光学声子参与的激子复合。并讨论了生长温度对量于阱发光的影响。 相似文献
107.
Wang Dunhui Huang Songling Han Zhida Su Zhenghua Wang Yi Du Youwei 《Solid State Communications》2004,131(2):97-99
A series of Gd(1−x)Bx alloys have been prepared by arc melting method. After introducing small quantity of B atom in Gd, the Curie temperature of these alloys increase while the magnetic entropy changes are almost same as that of Gd. The refrigerant capacities of these alloys are also greater than that of Gd. These results suggest that Gd(1−x)Bx alloys may be utilized as refrigerant in household magnetic refrigeration. 相似文献
108.
J.S. Tsay H.W. Chang Y.L. Chiou K.T. Huang W.Y. Chan Y.D. Yao 《Journal of magnetism and magnetic materials》2006
Influences of oxygen exposure on the magnetic properties of Co/Ge(1 1 1) ultrathin films have been investigated by surface magneto-optic Kerr effect technique. As the oxygen exposure increases on Co/Ge(1 1 1) films, their magnetic properties could be modified. As an example for 15 ML Co/Ge(1 1 1) films, the coercivity increases from 730 to 920 Oe and the remanence Kerr intensity is reduced for 500 Langmuir (L) of oxygen exposure. Corresponding compositions analyzed by Auger electron spectroscopy measurement shows that the amount of oxygen on the surface layers increases with increasing the oxygen exposure time. Oxygen distributes on the topmost layers of the film. The adsorbed oxygen influences the electronic density of states of Co and results in the changes of the magnetic properties. Besides, the appearance of O/Co/Ge interface could modify the stress anisotropy, and as a result the coercivity of ultrathin Co/Ge(1 1 1) film is enhanced. 相似文献
109.
110.
Observation of spontaneous pattern with six-fold symmetry in disk-shaped ZnO complex microstructures
L.W. Yang Y.J. Gao X.L. Wu Y.M. Yang G.S. Huang Z.Y. Zhang P.K. Chu 《Applied Physics A: Materials Science & Processing》2007,89(1):173-176
Using a simple vapor phase transport technique, we have fabricated unique complex disk-shaped ZnO microstructures comprising
a small disk coaxially grown on a large one and observed spatially perfect six-fold symmetric patterns. The observed results
can be explained based on the spontaneous nanoindentation (NI) effect under the geometric constraints and the explanation
can be extended to fathom the growth mechanism of other highly symmetrical ZnO nanostructures. Our results indicate that NI
not only can elucidate the mechanical properties of surfaces and thin films but also is an effective approach to fabricate
ordered nanostructures with high precision on the location of the building blocks.
PACS 81.16.Rf; 81.07.-b; 81.05.Dz 相似文献