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121.
Jing Li Huayi Shi Runzhi Chen Xiaofeng Wu Jiayi Cheng Fenglin Dong Houyu Wang Yao He 《Chemical science》2021,12(3):896
Synthesis of programmable atom-like nanoparticles (PANs) with high valences and high yields remains a grand challenge. Here, a novel synthetic strategy of microfluidic galvanic displacement (μ-GD) coupled with microfluidic DNA nanoassembly is advanced for synthesis of single-stranded DNA encoder (SSE)-encoded PANs for reliable surface-enhanced Raman scattering (SERS) sensing. Notably, PANs with high valences (e.g., n-valence, n = 12) are synthesized with high yields (e.g., >80%) owing to the effective control of interfacial reactions sequentially occurring in the microfluidic system. On the basis of this, we present the first demonstration of a PAN-based automatic analytical platform, in which sensor construction, sample loading and on-line monitoring are carried out in the microfluidic system, thus guaranteeing reliable quantitative measurement. In the proof-of-concept demonstration, accurate determination of tetracycline (TET) in serum and milk samples with a high recovery close to 100% and a low relative standard deviation (RSD) less than 5.0% is achieved by using this integrated analytical platform.A novel synthetic strategy is presented for microfluidic preparation of programmable atom-like nanoparticles with high valences and high yields. 相似文献
122.
Cheng-Ting Zi Liu Yang Fa-Wu Dong Qing-Hua Kong Zhong-Tao Ding Jun Zhou 《Natural product research》2020,34(16):2301-2309
Abstract Two new compounds (9 and 10) having a camptothecin (CPT) analog conjugated to the 4β-azido-4-deoxypodophyllotixin analog by untilizing the copper-catalyzed azide-alkyne cycloadditon (CuAAC) reaction, and were evaluated for their cytotoxicity against a panel of five human cancer cell lines (HL-60, SMMC-7721, A-549, MCF-7 and SW480) using the MTT (3-(4,5-dimethyl-thiahiazo-2-yl)-2,5-diphenyltetrazolium bromide) assay. Two novel conjugates shown weak cytotoxicity, compound 10 showed highly potent against HL-60 cell line tested, with IC50 value 17.69?±?0.19?μM. This compound suggested its potential as anticancer agents for further development. 相似文献
123.
高效液相色谱分离与质谱稳定同位素稀释法联合测定地质样品中钐及钕 总被引:1,自引:0,他引:1
本文报道了用高效液相色谱分离,制取高纯度的Sm及Nd。再与质谱稳定同位素稀释法联合测定几种岩石矿物中的Sm与Nd。 相似文献
124.
In this text, we use inexpensive and natural amino acid, successfully obtained the asymmetric crystallization of three PTCs, [Tis(O~iPr)_(14)(μ_2-O)(μ_3-O)_2(D/L-pGlu)_2](D-PTC-53; L-PTC-53; H2 pGlu=pyroglutamic acid) and [Ti_6(O~iPr)_(14)(μ_2-O)(μ_3-O)_2(D-pGlu)_2][Ti_6(O~iPr)_(14)((μ_2-O)(μ_3-O)_2(L-pGlu)_2](D,L-PTC-53). Interestingly, in situ lactamide reaction starting from glutamic acid to pyroglutamic acid was observed. In addition,the chirality features of these PTCs have been thoroughly discussed.The two enantiomers crys tallize in chiral P21 space group.The optically pure pGlu ligands transform its chirality to the inorganic titanium oxo clusters. As a result, the stack of these inorganic clusters generates homochiral helical chains along the characteristic axial direction.Apart from the microscopic structural analysis, the macroscopic solid-state samples exhibit unusual strong circular dichroism(CD) signals,further verified the homochiral feature of the enantiomers. 相似文献
125.
Xin Yang Chuan Dong Jun Zhang Yan-sheng Wei Wei-Jun Jin Chang-song Liu 《Microchemical Journal》1997,57(3):294-304
Six polycyclic aromatic hydrocarbons (PAHs) are studied by chemical deoxygenation microemulsion-stabilized room temperature phosphorimetry with sodium sulfite as an oxygen scavenger and thallous nitrate as a heavy atom perturber in sodium dodecyl sulfate medium. Several factors influencing room temperature phosphorescence such as the concentration of sodium dodecyl sulfate, the heavy atom concentration, the pH, and the concentration of sodium sulfite are discussed and the quenching effect of NO2−on room temperature phosphorimetry of PAHs was compared in the microemulsion and micelle media. 相似文献
126.
Journal of Global Optimization - Improperly efficient solutions in the sense of Geoffrion in linear fractional vector optimization problems with unbounded constraint sets are studied systematically... 相似文献
127.
For a positive integerl divisible by 8 there is a (bosonic) holomorphic vertex operator algebra (VOA)
associated to the spin lattice
l
. For a broad class of finite groupsG of automorphisms of
we prove the existence and uniqueness of irreducibleg-twisted
-modules and establish the modular-invariance of the partition functionsZ(g, h, ) for commuting elements inG. In particular, for any finite group there are infinitely many holomorphic VOAs admittingG for which these properties hold. The proof is facilitated by a boson-fermion correspondence which gives a VOA isomorphism between
and a certain fermionic construction, and which extends work of Frenkel and others.Supported by NSA grant MDA904-92-H-3099.Supported by NSF grant DMS-9122030. 相似文献
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