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71.
72.
Ahmet Colak Ender Cekirge Serdar Karaböcek Aslıgül Küçükdumlu Nagihan Sağlam Ertunga Melek Col Rza Abbasoğlu 《Chemical Papers》2009,63(5):554-561
Nucleolytic activities of some new oxime-type ligand complexes were investigated by neutral agarose gel electrophoresis. Analysis
of the cleavage products in agarose gel indicated that all complexes used converted supercoiled pUC18 plasmid DNA to its nicked
or linear form. It was found that nucleolytic activities of the complexes depend on the complex concentration, reaction time
and the presence of a cooxidant (magnesium monoperoxyphthalate, MMPP) in the reaction mixture. However, the complexes cleaved
pUC18 plasmid DNA at all investigated pH values. Nucleolytic activities of complexes were investigated for different complex
concentrations (0.1–100 μmol L−1), pH values (6.0–10.0) and reaction times (0–60 min). Molecular modeling studies performed by the Hyperchem Software together
with DNA-binding studies showed that planar sites of the complexes intercalated into double stranded DNA. It can be concluded
that all oxime-type ligand complexes used can be evaluated as nuclease mimics. 相似文献
73.
Liquid–liquid equilibrium (LLE) data of the solubility (binodal) curves and tie-line end compositions were examined for mixtures of {(water (1) + levulinic acid (2) + dimethyl succinate or dimethyl glutarate or dimethyl adipate (3)} at 298.15 K and 101.3 ± 0.7 kPa. The reliability of the experimental tie-line data was confirmed by using the Othmer–Tobias correlation. The LLE data of the ternary systems were predicted by UNIFAC method. The LLE data were correlated fairly well with UNIQUAC and NRTL models, indicating the reliability of the UNIQUAC and NRTL equations for these ternary systems. The best results were achieved with the NRTL equation, using non-randomness parameter (α = 0.3) for the correlation. Distribution coefficients and separation factors were measured to evaluate the extracting capability of the solvents. 相似文献
74.
Many applications in science and engineering lead to models that require solving large‐scale fixed point problems, or equivalently, systems of nonlinear equations. Several successful techniques for handling such problems are based on quasi‐Newton methods that implicitly update the approximate Jacobian or inverse Jacobian to satisfy a certain secant condition. We present two classes of multisecant methods which allow to take into account a variable number of secant equations at each iteration. The first is the Broyden‐like class, of which Broyden's family is a subclass, and Anderson mixing is a particular member. The second class is that of the nonlinear Eirola–Nevanlinna‐type methods. This work was motivated by a problem in electronic structure calculations, whereby a fixed point iteration, known as the self‐consistent field (SCF) iteration, is accelerated by various strategies termed ‘mixing’. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
75.
Yousef Bisabr 《General Relativity and Gravitation》2010,42(5):1211-1219
We introduce a dynamical model to reduce a large cosmological constant to a sufficiently small value. The basic ingredient
in this model is a distinction which has been made between the two unit systems used in cosmology and particle physics. We
have used a conformal invariant gravitational model to define a particular conformal frame in terms of large scale properties
of the universe. It is then argued that the contributions of mass scales in particle physics to the vacuum energy density
should be considered in a different conformal frame. In this manner, a decaying mechanism is presented in which the conformal
factor appears as a dynamical field and plays a key role to relax a large effective cosmological constant. Moreover, we argue
that this model also provides a possible explanation for the coincidence problem. 相似文献
76.
The gold nanoparticles (AuNPs) are capable of enhancing the incident laser field in the form of scattered near field for even an off-resonance irradiation where the incident laser wavelength is far away from the localized surface plasmon resonance (LSPR). If the intensity of the pulse laser is large enough, this capability can be employed to generate a highly localized free electron (plasma) in the vicinity of the particles. The generated plasma can absorb more energy during the pulse, and this energy deposition can be considered as an energy source for structural mechanics calculations in the surrounding media to generate a photoacoustic (PA) signal. To show this, in this paper, we model plasma-mediated PA pressure wave propagation from a 100-nm AuNPs and the surrounding media irradiated by an ultrashort pulse laser. In this model, the AuNP is immersed in water and the laser pulse width is ranging from 70 fs to 2 ps at the wavelength of 800 nm (off-resonance). Our results qualitatively show the substantial impact of the energy deposition in plasma on the PA signal through boosting the pressure amplitudes up to ~1000 times compared to the conventional approach. 相似文献
77.
Qaiser Rafiq Muhammad Tahir Khan Sikander Azam Amin ur Rahman Sardar Sikandar Hayat Yousef Mohammed Alanazi Syed Sheraz Ahmad 《International journal of quantum chemistry》2024,124(2):e27335
This study aimed to comprehensively investigate the optoelectronic and magnetic properties of Mo, Zn/LiNbO3 (1 1 1) material. The primary objectives were to understand the potential for manipulating the material's magnetism and to elucidate the origin of spin-polarized states and magnetic moments, particularly with respect to the unpaired d orbitals of Nb, Mo, and Zn atoms. To achieve these objectives, we employed the Pardew–Burke–Ernzerhof (PBE) method within the Generalized Gradient Approximation (GGA + U) framework. This computational approach allowed us to examine the optoelectronic and magnetic characteristics of the material in detail. Our research yielded several key findings that enhance our understanding of Mo, Zn/LiNbO3 (1 1 1) material. We observed a modest improvement in the material's absorption capacity within the visible spectrum, accompanied by a discernible red-shift. Notably, our study involved the calculation of the dielectric function and refractive constant of the material, revealing a strong correlation between absorption trends and the dielectric constant. Furthermore, our investigation uncovered that Mo, Zn/LiNbO3 (1 1 1) exhibits distinct conduction and valence bands, with p and d orbitals predominantly contributing to each, respectively. The energy gap of the material falls within a range of 0.30–1.04 eV. A particularly significant finding was the narrower band gap of Mo, Zn/LiNbO3 (1 1 1) material, which can be attributed to the superposition of Mo-d and Zn-p orbit energy levels with O-p orbit energy levels, ultimately forming a covalent bond. Importantly, our research demonstrated the material's heightened optical absorption within the visible spectrum, suggesting its suitability for various photonic and optoelectronic applications. Additionally, we calculated a wide range of optical characteristics, including the dielectric function, absorption coefficient, energy loss, reflectivity, refractive index, extinction coefficient, and optical conductivity, providing a comprehensive assessment of the material's optical properties. 相似文献
78.
Flexural,impact, rheological and physical characterizations of POM reinforced by carbon nanotubes and paraffin oil 下载免费PDF全文
The paraffin oil dispersion technique innovated in the recent years to synthesize bulk polymer nanocomposite materials has a uniform dispersion. This research work aims to study the effect of added carbon nanotubes (CNTs) on flexural, impact and rheology behaviors of polyoxymethylene (POM) reinforced by 0–0.03 wt% of CNT using paraffin oil dispersion technique. The wettability and lamellar thickness were measured and rheological performance investigated using a parallel plate rheometer. The flexural and impact mechanical properties were also evaluated. The fracture surfaces were then examined by microscopy. The results showed that the energy to break, flexural strength and modulus increased proportionally with the addition of the amount of CNT in the matrix. For the rheology behavior, the viscosity decreased at the low percentage of CNT and then increased with increase in the percentage weight ratio of CNT in the POM matrix. It was also noted that the water contact angle rose with the increase the CNT percentages. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
79.
The minimum variance lower bound (MVLB) represents the best achievable controller capability in the variance sense. Realization of MVLB for nonlinear systems confronts some difficulties. To realize the MVLB, in this paper, a nonlinear non-affine generalized minimum variance controller is designed. The situations in which the model is not in hand, accurate, or invertible are addressed. Moreover, in order to design minimum variance controller for nonlinear structures, inverse of the system is modeled; then, the controller parameters are tuned by a recursive optimization algorithm. The most classical recursive algorithms are gradient-based. In this paper, a relationship between gradient of the controller with that of the system model is derived by inverse lemma. Therefore, the recursive algorithm is free of any need for the gradient of the system model. Finally, an experimental test on four-tank benchmark processes is used to clarify the effectiveness of the proposed control scheme. 相似文献
80.
Iran Sheikhshoaie Tayebeh Shamspur S. Yousef Ebrahimipur 《Arabian Journal of Chemistry》2012,5(2):201-205
Manganese(II) complex of (E)-2-(hydroxyl-5-methoxybenzylideneamino) phenol was synthesized and used as a suitable Mn(II) – selective membrane in PVC matrix. The plasticized membrane sensor exhibits a nersian response for Mn(II) ions over a wide concentration range of 6 × 10?6–2 × 10?2 M with slope of 29 ± 1 mV per decade. It has a response time of <11 s and can be used for 2 months without any measurable divergence in potential. The response of the proposed sensor is independent of pH between 4 and 9.5. The proposed sensor shows a fairly good discriminating ability towards Mn(II) in comparison with some hard and soft metals. The electrode was used in the determination of Mn(II) in aqueous solutions and as an indicator electrode in potentiometer titration of manganese ions against EDTA. 相似文献