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91.
Zhao Q Nellutla S Son WJ Vaughn SA Ye L Smith MD Caignaert V Lufaso M Pekarek TM Smirnov AI Whangbo MH zur Loye HC 《Inorganic chemistry》2011,50(20):10310-10318
Single crystals of a new iron-containing oxide, Ba(4)KFe(3)O(9), were grown from a hydroxide melt, and the crystal structure was determined by single-crystal X-ray diffraction. This ferrite represents the first complex oxide containing isolated 6-membered rings of corner-sharing FeO(4) tetrahedra. M?ssbauer measurements are indicative of two tetrahedral high-spin Fe(3+) coordination environments. The observed magnetic moment (~3.9 μ(B)) at 400 K is significantly lower than the calculated spin-only (~5.2 μ(B)) value, indicating the presence of strong antiferromagnetic interactions in the oxide. Our density functional theory calculations confirm the strong antiferromagnetic coupling between adjacent Fe(3+) sites within each 6-membered ring and estimate the nearest-neighbor spin-exchange integral as ~200 K; next-nearest-neighbor interactions are shown to be negligible. The lower than expected effective magnetic moment for Ba(4)KFe(3)O(9) calculated from χT data is explained as resulting from the occupation of lower-lying magnetic states in which more spins are paired. X-band (9.5 GHz) electron paramagnetic resonance (EPR) spectra of a powder sample consist of a single line at g ~ 2.01 that is characteristic of Fe(3+) ions in a tetrahedral environment, thus confirming the M?ssbauer results. Further analysis of the EPR line shape reveals the presence of two types of Fe(6) magnetic species with an intensity ratio of ~1:9. Both species have Lorentzian line shapes and indistinguishable g factors but differ in their peak-to-peak line widths (δB(pp)). The line-width ratio δB(pp)(major)/δB(pp)(minor) ~ 3.6 correlates well with the ratio of the Weiss constants, θ(minor)/θ(major) ~ 4. 相似文献
92.
93.
Kim SH Gwon SY Bae JS Son YA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(1):234-237
A new donor-π-acceptor (D-π-A) type isophorone dye was synthesized by the condensation reaction between 2-(3,5,5-trimethylcyclohex-2-enylidene)-malononitrile and indole-3-carboxaldehyde. The chemical structure of the dye was characterized by 1H NMR, EA and MS. A novel, chromogenic, fluorescent dye based on indol as donor unit and isophorone as acceptor unit displayed marked UV-visible absorption changes and highly selective fluorescence quenching in the presence of fluoride ion. The dye also exhibited sizeable colour changes when used as a pH-induced molecular switch and as a detector for volatile organic compounds. The absorption and fluorescent intensity of the dye can be reversibly selected by protonation/deprotonation of the amine moiety via control of intramolecular charge transfer (ICT), leading to a molecular switch with "on" and "off" states. 相似文献
94.
Choi J Jin J Jung IG Kim JM Kim HJ Son SU 《Chemical communications (Cambridge, England)》2011,47(18):5241-5243
Through a solution approach, SnSe(2) nanoplate-graphene composites were prepared and applied as anode materials in lithium ion batteries, showing promising storage performance superior to SnSe(2) nanoplates or graphene alone. 相似文献
95.
96.
S.-W. Son H. Jeong J. D. Noh 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,50(3):431-437
We propose a method to determine the community
structure of a complex network. In this method the ground state
problem of a ferromagnetic random field Ising model is considered
on the network with the magnetic field Bs = +∞, Bt =
-∞, and Bi≠s,t=0 for a node pair s and t. The
ground state problem is equivalent to the so-called maximum flow
problem, which can be solved exactly numerically with the help of
a combinatorial optimization algorithm. The community structure is
then identified from the ground state Ising spin domains for all
pairs of s and t. Our method provides a criterion for the
existence of the community structure, and is applicable equally
well to unweighted and weighted networks. We demonstrate the
performance of the method by applying it to the Barabási-Albert
network, Zachary karate club network, the scientific collaboration
network, and the stock price correlation network.
(Ising, Potts, etc.) 相似文献
97.
The orientation of E7 liquid crystal (LC) confined within 200 nm diameter cylindrical cavities of Anodisc membranes are investigated by FTIR dichroism techniques. The cavity walls of the confining pores were chemically modified with different length perfluorinated carboxylic acids (PCAs, C n F2n+1COOH, n = 3, 4, 5, 6) at 1, 3 and 5 mM concentrations. From the FTIR spectra of PCA-treated alumina Anodsic membranes, we found salt formation between the -COOH group of the PCAs and the Anodisc membranes. From the FTIR spectra of LC-filled Anodisc membranes, we found an abrupt alignment direction change, from parallel to perpendicular, of the LC molecules along the long axis of the cavities between n = 4 and n = 5 for the 1 mM concentration of PCA. However, for the 5 mM concentration of PCA, the parallel-to-perpendicular alignment direction of LC molecules changed between n = 3 and n = 4. These LC orientation changes for PCA-treated Anodisc membranes occurred at shorter length than for hydrocarbon carboxylic acid (HCA, C n H2n+1COOH)-treated Anodisc membranes. This change may be caused by the lower surface energy of the -(CF2) n CF3 chain of PCA than that of the -(CH2) n CH3 chain of HCA. 相似文献
98.
Sang Ick LeeSeung Uk Son Mi Ra ChoiYoung Keun Chung Sueg-Geun Lee 《Tetrahedron letters》2003,44(25):4705-4709
Cobalt on charcoal (Co/C) can be used as a catalyst in the tandem carbocycloaddition reaction of 1,6-diyne and carbon monoxide. The reaction product is dependent upon the reaction temperature, the position of the functional group, and the substrate itself. 相似文献
99.
The synthesis and optical properties of a series of benz[f]indenes as new building blocks for electronic and optoelectronic materials are described. 相似文献
100.