Design and analysis of multilayered structures with metal-dielectric gratings for reflection resonance and color generation

A multilayered structure incorporating a metal-dielectric subwavelength grating, with the characteristic of polarization separation for visible light and the capability of creating reflection resonance and distinctive polarization-dependent color effects, is proposed. Its reflection resonance and color for TE and TM polarizations are discussed, as well as the influence of its structural parameters on them. Moreover, a reflection filter with characteristics of red for TE-polarized light, green for TM-polarized light, and yellow for daylight is designed and fabricated by replacing its grating region with a sinusoidal grating, and its related characteristics also are verified. The structure and its properties can achieve practical applications in various fields, such as color security, image reproduction, color filtering, and polarization-based information hiding.     

1,4-双(4-吡啶基甲基苯基醚)(C18H18N2O2)与SCN^-形 成的超分子化合物[H2 (C18H18N2O2)](SCN)2的合成、结构 及其在溶液中的三阶非线性光学性质

超分子化合物[H2(C18H18N2O2)](SCN)由Fe(NO3)3·9H2O,KSCN和1,4-双(4-吡啶基甲基苯基醚)反应得到。通过X射线衍射仪测得该化合物是通过N┈H—N,S┈H—C(C5H5N)及S┈H—C(亚甲基CH2)三种氢键而形成的二维平面网状结构。用Z扫描法对该超分子在DMF溶液中的三阶非线性光学性质进行研究,发现它具有强的三阶非线性折射性能,三阶非线性超极化率X^(3)=6.27×10^-12esu.     

黏弹性体界面裂纹的冲击响应

研究两半无限大黏弹性体界面Griffith裂纹在反平面剪切突出载荷下,裂纹尖端动应力强度因子的时间响应,首先,运用积分变换方法将黏弹性混合黑社会问题化成变换域上的对偶积分方程,通过引入裂纹位错密度函数进一步化成Cauchy型奇异积分方程,运用分片连续函数法数值求解奇异积分方程,得到变换域内的动应力强度因子,再用Laplace积分变换数值反演方法,将变换域的解反演到时间域内,最终求得动应力强度因子的时间响应,并对黏弹性参数的影响进行分析。     

核反应实验数据库(EXFOR)

核反应实验数据库(EXFOR)及其检索系统提供了丰富的中低能核反应物理信息和数据,已经成为国际上最全面的核反应实验数据汇编.目前,由国际原子能机构核数据科(IAEA/NDS)协调管理,国际核反应数据中心协作网(NRDC)13个成员进行全球性合作,旨在协调国际范围内核反应实验数据的收集、编纂和传播.中国核数据中心(CND...     

非理想界面对三相复合材料应力场的影响

对非理想界面的三相复合材料,提出了计算弹性应力场的微观力学模型,在适当的简化假设下,对带界相的颗粒增强和纤维增强复合材料,得到了应力场的计算公式。以剪切载荷为例给出了数值例子。给出的数值结果表明非理想界面对三相复合材料应力场的影响。     

稠密气固两相湍流流动的实验和数值模拟

基于气固两相流动模型计算循环流化床内稠密气固两相流湍流动,颗粒动理学方法模拟颗粒相湍动能,ＳＧＳ模型模拟气相湍流,采用γ－射线密度计和非等速取样管测量局部颗粒浓度和流率,利用ＦＦＴ方法计算颗粒浓度功率谱密度。模拟计算得到上升管内气相和固相速度和浓度分布等。同时数值模拟与Ｔｓｕｊｉ等和Ｋｎｏｗｌｔｏｎ等试验结果进行了比较,结果表明数值模拟计算与实验结果相吻合。     

杂原子进入分子筛骨架结构的波谱学判据

概括了杂原子取代的分子筛内骨架杂原子的波谱学鉴定方法。根据杂原子进入骨架后所引起的晶体结构、表面酸性、电子跃迁规律、配位环境等微观性质的变化,重点讨论了XRD、FT-IR、DR UV-Vis、Raman、MAS-NMR、XAFS、ESR和XPS等波谱学方法在鉴别骨架杂原子时的应用原理和方法。     

电感耦合等离子体原子发射光谱法(ICP-AES)测定高效复合孕育剂中铝、钙、钡

通过硝酸、氢氟酸和盐酸分解试料,高氯酸冒烟驱走硅和氟,最后用盐酸溶解盐类,应用电感耦合等离子体原子发射光谱法(ICP-AES)对高效复合孕育剂中铝、钙、钡进行测定,方法能准确、快速地测定其含量,加标回收率在98.8%~103%,精密度、标准样品分析对照均取得了满意的结果。     

Simultaneous determination of cordycepin and its metabolite 3′-deoxyinosine in rat whole blood by ultra-high-performance liquid chromatography coupled with Q Exactive hybrid quadrupole orbitrap high-resolution accurate mass spectrometry and its application to accurate pharmacokinetic studies

Cordycepin from Cordyceps possesses excellent pharmacological properties, including anti-inflammation and anti-tumor effects, therefore representing a potential alternative medicine. However, doubts about the pharmacokinetic results of cordycepin had been raised in the previous study due to its rapid deamination. The organic solvent methanol was immediately added to terminate the degradation of cordycepin in anticoagulated blood samples and enable the accurate evaluation of pharmacokinetics in vivo. A sensitive and selective ultra-high-performance liquid chromatography coupled with Q Exactive hybrid quadrupole orbitrap high-resolution accurate mass spectrometry method was developed and validated to simultaneously determine cordycepin and its deamination metabolite 3′-deoxyinosine using 2-chloroadenosine as an internal standard in rat whole blood. The calibration curves of cordycepin and 3′-deoxyinosine showed excellent linearity within the concentration range of 1.05–10 000.00 ng/ml with acceptable accuracy, precision, selectivity, recovery, matrix effect, and stability. This method was successfully applied to the pharmacokinetic study of cordycepin and its metabolite in rat blood. The effect of the adenosine deaminase inhibitor erythro-9-(2-hydroxy-3-nonyl) adenine hydrochloride on the pharmacokinetics of cordycepin was investigated. In summary, the reliable pharmacokinetic parameters of cordycepin and its deamination metabolite 3′-deoxyinosine in rat blood were successfully elucidated. Erythro-9-(2-hydroxy-3-nonyl) adenine hydrochloride considerably prolonged the half-life of cordycepin in vivo.