镧掺杂水滑石材料的热分解过程研究

采用共沉淀法制备了系列La掺杂改性的含Cu类水滑石,高温焙烧得到其衍生混合氧化物材料,并用XRD,TG-DSC,FT-IR等对材料进行表征.结果表明,前驱物XRD图谱呈典型的水滑石衍射特征且颗粒结晶良好;经800℃焙烧后,掺杂La2O3含量为5.1%的样品仅有Mg1-xFexO晶相出现,说明La的掺杂提高了材料的高温稳定性,混合氧化物中的Cu离子呈高分散状态.     

强场作用下二能级原子双光子过程中辐射场的压缩效应

本文采用数值计算方法研究了强场作用下二能级原子双光子过程中辐射场的压缩效应.结果表明:辐射场主要处于压缩态,并周期性地出现短时的非压缩效应,随着值的不断增大,场与原子的非线性耦合越来越强,压缩的最大深度不断加深.     

Experimental investigation on large deflection response of a frame impacted by a moving body

This paper reports on the experimental investigation of the dynamic large deflection response of a portal frame impacted at its midspan by a body moving at a certain speed. Both the deflection and velocity vs. time curves of the midspan and the dynamic history of a number of desired locations were recorded during the process of response. On the basis of the test data, the momentum and kinetic energy conversion between the frame and the moving body in the impact process are realized, and the occurrence and expansion of plastic regions are described. Investigation results show that the initial collision is approximately ideally inelastic, and that the elastic deformation plays a considerable role in the response though the input energy is much larger than the maximum elastic energy capacity of the beam member; therefore, in a general impact, the energy ratio should not be regarded as a sufficient criterion for a rigid—plastic solution. The ratios of the impulse transferred to and the energy absorbed by the frame in the initial collision to that carried by the moving body before impact is only related to the ratiobetween the equivalent mass of the frame paticipating in the initial collision and the mass of the impacting body, having nothing to do with the impacting velocity to a certain extent.     

Comparative analysis of (p,d), (d,t) and (3He, α) reactions on13C nucleus

The angular distributions of the (p, d), (d, t) and(³He, ) reactions on¹³C have been analysed within the framework of DWBA in which additional information on nuclear vertex constants was introduced. Although all these reactions seem to be similar single nucleon transfer, their mechanism is shown to be quite different and so is the information extracted thereof. While from the (p, d) reactions spectroscopic factors may be extracted unambiguously, from the (d, t) reactions it is possible to obtain directly the values of vertex constants only, which in turn are consistent with those determined by extrapolation of the experimental cross sections of the (p, d) reactions to the pole.In the case of (³He, ) reactions, however, the analysis indicates inadequacy of the DWBA concerning the calculations of central partial amplitudes. For a more reliable extraction of structural information, besides the correct normalization of peripheral amplitudes, a contribution of more complex mechanisms must be taken into account.     

Multisites Cr3+ in GGG and GSGG garnets

The emission and excitation spectra of Cr³⁺ -doped Gd₃Ga₅O₁₂ (GGG) and Gd₃Sc₂Ga₃O₁₂ (GSGG) are explained in the light of multisite effects. The situation is particularly complicated in the case of GSGG, where the different sites have²E energy levels near each other which overlap with the⁴A₂ ⁴T₂ absorption bands. The spectra obtained under selective excitations are interpreted on the multisite assumption.     

Extension to R + n+1 of singular integrals and fractional integrals

In this paper, a natural R ₊ ⁿ⁺¹ extension of singular integrals, i.e.,T _κ:f→K*φ _t *t with K a standard C-Z kernel and ϕ usual one, is investigated. One of the main results is: Let (dμ, udx) ∈C₁ and u-Mw, w∈A_∞, then T_k is of type (L^p(udx), L^p(dμ)). As a related topic, a maximal operator is proved to be of type , where , provided (dμ, udx) ∈C₁ and u∈ A_∞. Supported by National Science Foundation of China     

Spectroscopic factors of9Be,10B and13C from (d,t) reactions

The differential cross sections of tritons from the (d, t) reaction on⁹Be,¹⁰B and¹³C targets have been measured in the angular range of 5° _LAB110° with relatively small errors, 5%. The experimental data were analysed in terms of the standard DWBA using both zero-range and exact finite-range approaches.     

Measurement ofD(\vec p,p)D elastic scattering at 10.0, 12.0, 14.1 and 16.5 MeV especially for small forward and extreme backward scattering angles

The elastic scattering was investigated especially in the Coulomb sensitive scattering regions. Angular distributions of the differential cross section and of the analyzing powerA _y, with emphasis on small scattering angles, were measured at 10.0 and 14.1 MeV. For extreme backward angles up toJ _c.m.=179° the differential cross section was measured at 12.0, 14.1 and 16.5 MeV. The data have been compared with recent Faddeev calculations based on the realistic meson-exchange Paris potential and including an approximate Coulomb correction. There are discrepancies between the data and the calculations especially for the analyzing power. This indicates that the approximate treatment of Coulomb effects and possibly also the purely nuclear part of the calculations need to be improved.     

在DBU存在下酞菁锰配合物的合成及溶剂影响

在强有机碱１，８－二氮杂双环［５，４，０］十一－７烯（简称ＤＢＵ）存在下，ＭｎＣｌ２与邻二氰基苯在某些二元醇溶剂中可高效合成Ｍｎ（Ⅱ）Ｐｃ（Ｐｃ表示酞菁），同时研究了不同溶剂对合成产物的物种及产率的影响和不同氧化态锰的酞菁配合物在一些醇溶剂中的互变现象     

A modified program for computation of formation constants of synergetic extraction complexes with two-phase titrations by using the Marquardt-Fletcher algorithm

A modified computer program SCTPT for the computation of formation constants of extraction complexes with two-phase pH titration data by using the Marquardt-Fletcher algorithm is described. It can be used to deal with extraction systems which consist of a metal, an acidic extractant and a neutral synergistic reagent with no need of new subroutine. It has been applied successfully to the Pb-PMBP(1-phenyl-3-methyl-4-benzoyl-pyrazolone-5)-TBP (tributyl phosphate) system. The results obtained are in agreement with those published in the literature.