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61.
Katsumi Katoh Shunsuke Ito Yuji Ogata Jun-ichi Kasamatsu Hiroshi Miya Masaaki Yamamoto Yuji Wada 《Journal of Thermal Analysis and Calorimetry》2010,99(1):159-164
In order to prevent the spontaneous ignition of nitrocellulose (NC), NC is stabilized by washing with industrial water in
its synthesis process. However, there is a possibility that the components in industrial water contribute to the thermal stability
of NC. In this way, the purpose of this study is to clarify the effect of industrial water components on the thermal stability
of NC. In experiments, a heat flux calorimeter was used to observe the thermal behavior of NC with the residue of vaporized
industrial water. The induction period of heat release of NC with 2-mass% residues was approximately 2–5 h shorter than that
of NC alone whose induction period was observed at 7 h. Those results indicate that the residue destabilized NC. On the other
hand, when the additive amount of the residue was increased, the induction period gradually increased as well. Based upon
these results, we assume that inorganic salts contributing to stabilization and destabilization competitively coexist in the
industrial water components. The same thermal analysis was performed on NC with CaCO3, CaSO4, CaCl, ZnSO4, NaCl, and CuCl. Those salts are predicted to exist in the industrial water. In the results, the induction period of NC with
2-mass% CaCO3 was approximately 15-h longer than that of NC alone, while the induction period with the inorganic salts CaSO4, CaCl, ZnSO4, NaCl, and CuCl was 4–5-h shorter. Therefore, when the industrial water components accumulate in NC, the destabilization
by inorganic salts such as CaSO4, CaCl, ZnSO4, NaCl, and CuCl and the stabilization by compounds such as CaCO3 are thought to countervail against each other. 相似文献
62.
We present a new method of smoothing discrete breakup cross sections calculated by the continuum-discretized coupled-channels method based on the complex-scaling method. One of the advantages of this approach is to be applicable to many-body breakup reaction systems. In this work, we apply the new smoothing method to analyses of 12C(6He, nn 4He) and 208Pb(6He, nn 4He) reactions at 240 MeV/A. 相似文献
63.
Decomposition of Benzene in Air in a Plasma Reactor: Effect of Reactor Type and Operating Conditions 总被引:2,自引:0,他引:2
Ogata A. Miyamae K. Mizuno K. Kushiyama S. Tezuka M. 《Plasma Chemistry and Plasma Processing》2002,22(4):537-552
The decomposition of benzene was carried out in two types of plasma reactors packed with BaTiO3 pellets: one reactor had two stainless steel electrodes (SUS reactor), and the other reactor had a glass layer between two concentric electrodes (GL reactor). The decomposition efficiency and the suppression of formation of N2O and NOx were greater in the GL reactor than in the SUS reactor. In contrast, the suppression of O3 formation and the oxidation to COx in the SUS reactor were superior to those in the GL reactor. The effect of wa eform and frequency of applied ac power was in estigated for each reactor. 相似文献
64.
Nobuo Ogata Teruaki Yanagawa Koukichi Yoshida 《Journal of Polymer Science.Polymer Physics》1986,24(9):1917-1929
Fracture mechanics was used to investigate the environmental stress cracking (ESC) of low density polyethylene (LDPE). Annealed and quenched samples were prepared; a single edge notch was made and the samples were fractured under constant load in a liquid methanol environment. The relation between the stress intensity factor K and the crack speed ? has been investigated. There is a large difference between annealed and quenched samples in the variation of this relation with temperature and applied load. The cause of this difference is discussed in detail. We propose that thermally activated molecular motion is essential to ESC of the annealed LDPE while stress concentration contributes markedly to ESC of the quenched LDPE. 相似文献
65.
Teppei Yoshioka Md Zahangir Alam Tomonari Ogata Takamasa Nonaka Seiji Kurihara 《Liquid crystals》2004,31(9):1285-1291
Several chiral azobenzene compounds having different chiral substituents were synthesized. A cholesteric phase was induced by mixing each chiral azobenzene compound with a host non-chiral nematic liquid crystal (E44). The helical twisting power (HTP) as well as the change in HTP by trans-cis photoisomerization of the chiral azobenzene compound was dependent on the structure of the chiral substituents. A compensated nematic phase was induced by combination of E44, a chiral azobenzene compound and a non-photochromic chiral compound. Reversible switching between the compensated nematic phase and cholesteric phase was brought about by trans-cis photoisomerization of the chiral azobenzene compound in the liquid crystalline systems. An azobenzene compound substituted with a menthyl group showed the highest efficiency as the trigger for the switching; this efficiency was related to the compactness of the chiral group substituted within the azobenzene core moiety. 相似文献
66.
This note is a continuation of our recent paper [V. Jakšić Y. Ogata, and C.-A. Pillet, The Green-Kubo formula and Onsager reciprocity relations in quantum statistical mechanics. Commun. Math. Phys. in press.] where we have proven the Green-Kubo formula and the Onsager reciprocity relations for heat fluxes in thermally driven quantum open systems. In this note we extend the derivation of the Green-Kubo formula to heat and charge fluxes and discuss some other generalizations of the model and results of [V. Jakšić Y. Ogata and C.-A. Pillet, The Green-Kubo formula and Onsager reciprocity relations in quantum statistical mechanics. Commun. Math. Phys. in press.]. 相似文献
67.
Space-Time Point-Process Models for Earthquake Occurrences 总被引:5,自引:0,他引:5
Yosihiko Ogata 《Annals of the Institute of Statistical Mathematics》1998,50(2):379-402
Several space-time statistical models are constructed based on both classical empirical studies of clustering and some more speculative hypotheses. Then we discuss the discrimination between models incorporating contrasting assumptions concerning the form of the space-time clusters. We also examine further practical extensions of the model to situations where the background seismicity is spatially non-homogeneous, and the clusters are non-isotropic. The goodness-of-fit of the models, as measured by AIC values, is discussed for two high quality data sets, in different tectonic regions. AIC also allows the details of the clustering structure in space to be clarified. A simulation algorithm for the models is provided, and used to confirm the numerical accuracy of the likelihood calculations. The simulated data sets show the similar spatial distributions to the real ones, but differ from them in some features of space-time clustering. These differences may provide useful indicators of directions for further study. 相似文献
68.
Hidekatsu Yokoyama Toshiyuki Sato Tateaki Ogata Hiroaki Ohya-Nishiguchi Hitoshi Kamada 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1997,129(2):201-206
A signal detector of longitudinally detected ESR (LODESR) is independent of the resonant frequency. We developed anin vivoLODESR spectrometer operating in the regions of 300, 700, and 900 MHz. Using this apparatus, we estimated signal intensities at different operating frequencies obtained from non- or high-dielectric loss phantoms that contained nitroxide radical solutions and from live rats that had received a nitroxide radical. Our result, higher signal intensities in the high-dielectric loss samples (such as physiological saline solution and animals) at a lower frequency, shows that the influence of a decrease in dielectric loss dominates over the signal reduction caused by smaller Zeeman splitting. We believe that this finding strongly supports anin vivoESR resonant frequency that tends to be low. 相似文献
69.
Motivated by recent Hall-effect experiment in YbRh(2)Si(2), we study ground state properties of a Kondo lattice model in a two-dimensional square lattice using variational Monte Carlo method. We show that there are two types of phase transition, an antiferromagnetic transition and a topological one (Fermi-surface reconstruction). In a wide region of parameters, these two transitions occur simultaneously without the breakdown of Kondo screening, accompanied by a discontinuous change of the Hall coefficient. This result is consistent with the experiment and gives a novel theoretical picture for the quantum critical point in heavy-fermion systems. 相似文献
70.
Circular autocorrelation of stationary circular Markov processes 总被引:1,自引:0,他引:1
Toshihiro Abe Hiroaki Ogata Takayuki Shiohama Hiroyuki Taniai 《Statistical Inference for Stochastic Processes》2017,20(3):275-290
The stationary Markov process is considered and its circular autocorrelation function is investigated. More specifically, the transition density of the stationary Markov circular process is defined by two circular distributions, and we elucidate the structure of the circular autocorrelation when one of these distributions is uniform and the other is arbitrary. The asymptotic properties of the natural estimator of the circular autocorrelation function are derived. Furthermore, we consider the bivariate process of trigonometric functions and provide the explicit form of its spectral density matrix. The validity of the model was assessed by applying it to a series of wind direction data. 相似文献