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71.
Yasemin Tümer Hümeyra Bati Prof. Dr. Nezihe Çalişkan Çi˘dem Yüksektepe Orhan Büyükgüngör 《无机化学与普通化学杂志》2008,634(3):597-599
The new cyclotriphosphazene derivative N3P3(OC6H3OCH3COH)6 ( 1 ) was synthesized from hexachlorocyclotriphosphazene, N3P3Cl6, and 4‐hydroxy‐3‐methoxybenzaldehyde in acetonitrile in the presence of K2CO3. The structure of 1 was verified by means of elemental analysis, IR, 1H NMR, 13C NMR, 31P NMR spectra, thermal analysis and X‐ray diffraction. 相似文献
72.
Dr. Elif Akhuseyin Yildiz Dr. Ebru Yabaş Prof. Fazlı Sözmen Dr. Yasemin Bozkurt Dr. Ahmet Karatay Prof. Bahadir Boyacioglu Prof. Hüseyin Ünver Dr. Ayhan Elmali 《Chemphyschem》2023,24(5):e202200735
Borondipyrromethene (BODIPY) chromophores are composed of a functional-COOH group at meso position with or without a biphenyl ring, and their compounds with heavy iodine atoms at −2, −6 positions of the BODIPY indacene core were synthesized. The photophysical properties of the compounds were studied with steady-state absorption and fluorescence measurements. It was observed that the absorption band is significantly red-shifted, and fluorescence signals are quenched in the presence of iodine atoms. In addition to that, it was indicated that the biphenyl ring does not affect the spectral shifting in the absorption as well as fluorescence spectra. In an attempt to investigate the effect of π-expanded biphenyl moieties and heavy iodine atoms on charge transfer dynamics, femtosecond transient absorption spectroscopy measurements were carried out in the environment of the tetrahydrofuran (THF) solution. Based on the performed ultrafast pump-probe spectroscopy, BODIPY compounds with iodine atoms lead to intersystem crossing (ISC) and ISC rates were determined as 150 ps and 180 ps for iodine BODIPY compounds with and without π-expanded biphenyl moieties, respectively. According to the theoretical results, the charge transfer in the investigated compounds mostly appears to be intrinsic local excitations, corresponding to high photoluminescence efficiency. These experimental findings are useful for the design and study of the fundamental photochemistry of organic triplet photosensitizers. 相似文献
73.
Yasemin Yahsi Elif Gungor M. Burak Coban Hulya Kara 《Molecular Crystals and Liquid Crystals》2016,637(1):67-75
A new linear trinuclear MnIII-MnII-MnIII complex 1 has been synthesized and characterized by elemental, spectral, X-ray and magnetic analysis. X-ray diffraction studies show that the central MnII ion is located at a crystallographic inversion center and is triply bridged to the terminal MnIII ions through one methoxide, one syn-syn carboxylate and one hydroxyl oxygen bridges with the short MnIII…MnII distance that is 3.047 Å. The intermolecular C-H…O, C-H…π and ring-metal interactions are observed in the hydrogen-bonded assembly of 1. Magnetic studies reveal that the mixed-valence complex 1 has S = 3/2 ground state with antiferromagnetic exchange interactions between MnII and MnIII ions. 相似文献
74.
Dal H Süzen Y Sahin E 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,67(3-4):808-814
Schiff bases derived from different meta-substituted salicylaldehyde and 5-methylaminopyridine have been synthesized and characterized by elemental analysis, FT-IR, NMR and UV-vis techniques. NMR assignments were made using (1)H, (13)C NMR and aided by 2D HETCOR and HMBC heteronuclear correlation techniques. The UV-vis spectra of the compounds were found useful in understanding the existence of tautomeric equilibria [phenol-imine (O-H...N) and keto-amine (O...H-N) forms] in polar and non-polar solvents. In order to rationalize the stabilization of tautomer in solid state, X-ray structure of 2-[(1E)-2-aza-2-(5-methyl(2-pyridyl)ethenyl)]-4-bromobenzen-1-ol (6) was determined. According to our crystallographic result, it has enol-imine tautomeric form. 相似文献
75.
Dal H Süzen Y 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,67(5):1392-1397
The condensation reaction of {N-[(2-hydroxyphenylmethyl)amino]-4,6-dimethylpyridine} (2), which is a reduction product of 1, with trimer N(3)P(3)Cl(6) affords partially a substituted spiro-cyclic phosphazene derivative (3). The fully substituted phosphazenes (4 and 5) have also been obtained from the reactions of 3 with the excess of pyrrolidine and morpholine. The characterizations and spectral investigations of these compounds have been made by elemental analyses, FTIR, 1H-, 13C-, 31P NMR, correlation spectroscopy (COSY), heteronuclear chemical shift correlation (HETCOR), heteronuclear multiple-bond correlation (HMBC) and mass spectroscopy (MS). The salient features of spectral data of these compounds have been discussed. 相似文献
76.
Onium salts, namely sulfonium, phosphonium, ammonium, and pyridinium salts containing phenacyl group are photoinitiators appropriate for the polymerization of monomers such as oxiranes and vinyl ethers, which are not polymerizable by a free-radical mechanism. The initiation is accomplished by direct or indirect (sensitized) photolysis of the salts. Depending on the type of the salt, the direct photoinitiation of cationic polymerization involves reversible or irreversible processes. The photolysis of phenacylsulfonium compounds proceeds by a reversible process, while the other types undergo irreversible photolysis leading to complete fragmentation of the photoinitiator. An additionally useful tool, namely photosensitized generation of initiating species enlarges the versatility of these salts as photoinitiators. Photoinitiated free-radical and zwitterionic polymerizations by using phenacyl-type salts are also addressed. Keto-enol tautomerization of phenacyl pyridinium salts is discussed. Moreover, an interesting application concerning in situ synthesis of clay-poly(methyl methacrylate) nanocomposites with the aid of the phenacyl anilinium salt-based photopolymerization technique is noted. 相似文献
77.
Erdal Aras Ozgul Karatas Yasemin Meric Hind Kh Abbass Mehmet Birey Ahmet Kilic 《辐射效应与固体损伤》2013,168(9):754-758
The single crystals of triphenylphosphinselenid [C18H15PSe] were produced by slow evaporation of concentrated ethyl acetate solutions. These single crystals were exposed to 60Co gamma (γ) rays with a dose speed of 0.980 kGy/h at the room temperature for 72 h. The free radical over the sample was observed using electron paramagnetic resonance (EPR)–X band spectrometer. The EPR spectra were recorded between 120 and 400 K. Furthermore, the sample irradiated was rotated in steps of 10° and analyzed for different orientations of the crystal in the magnetic field. Only one radical structure was determined on the molecule. The hyperfine constants of the sample were found to be anisotropic. The average values of these constants and value of g were calculated as following: g=2.007656, aSe=37.47 G, aP=27.44 G, aHa=17.28 G, and aHb=18.16 G. 相似文献
78.
Almira Ramanaviciene Asta Kausaite-Minkstimiene Yasemin Oztekin Geta Carac Jaroslav Voronovic Natalija German Arunas Ramanavicius 《Mikrochimica acta》2011,175(1-2):79-86
We describe a new method for the visualization of the activity of red-ox proteins on a gold interface. Glucose oxidase was selected as a model system. Surfaces were modified by adhesion of glucose oxidase on (a) electrochemically cleaned gold; (b) gold films modified with gold nanoparticles, (c) a gold surface modified with self-assembled monolayer, and (d) covalent immobilization of protein on the gold surface modified with a self-assembled monolayer. The simple optical method for the visualization of enzyme on the surfaces is based on the enzymatic formation of polypyrrole. The activity of the enzyme was quantified via enzymatic formation of polypyrrole, which was detected and investigated by quartz microbalance and amperometric techniques. The experimental data suggest that the enzymatic formation of the polymer may serve as a method to indicate the adhesion of active redox enzyme on such surfaces. Figure
An optical method for the evaluation of activity and distribution of glucose oxidase on the different surfaces was described. The enzymatic synthesis of polypyrrole (black colour) was successfully applied for the visualization of active enzyme on the surfaces. 相似文献
79.
Laser‐ablated Th atoms are reacted with different F2 concentrations to produce ThFx (x = 1, 2, 3, 4), ThF3(F2) and ThF5‐. 相似文献
80.
This paper develops exact and heuristic algorithms for a stochastic knapsack problem where items with random sizes may be assigned to a knapsack. An item’s value is given by the realization of the product of a random unit revenue and the random item size. When the realization of the sum of selected item sizes exceeds the knapsack capacity, a penalty cost is incurred for each unit of overflow, while our model allows for a salvage value for each unit of capacity that remains unused. We seek to maximize the expected net profit resulting from the assignment of items to the knapsack. Although the capacity is fixed in our core model, we show that problems with random capacity, as well as problems in which capacity is a decision variable subject to unit costs, fall within this class of problems as well. We focus on the case where item sizes are independent and normally distributed random variables, and provide an exact solution method for a continuous relaxation of the problem. We show that an optimal solution to this relaxation exists containing no more than two fractionally selected items, and develop a customized branch-and-bound algorithm for obtaining an optimal binary solution. In addition, we present an efficient heuristic solution method based on our algorithm for solving the relaxation and empirically show that it provides high-quality solutions. 相似文献